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A “half” core-shell magnetic nanohybrid composed of zeolitic imidazolate framework and graphitic carbon nitride for magnetic solid-phase extraction of sulfonylurea herbicides from water samples followed by LC-MS/MS detection

A “half” core-shell g-C 3 N 4 /Fe 3 O 4 @ZIF-8 nanohybrid, in which Fe 3 O 4 and zeolite imidazolate framework-8 (ZIF-8) constructed the core-shell structure, was successfully fabricated via a versatile in situ growth strategy. This nanohybrid was employed for simultaneous magnetic solid-phase extra... Full description

Journal Title: Mikrochimica acta (1966) 2020, Vol.187 (5), p.279-279
Main Author: Qi, Yan
Other Authors: Wan, Mengfei , Abd El-Aty, A. M , Li, Hui , Cao, Liping , She, Yongxin , Shao, Yong , Jin, Fen , Wang, Shanshan , Wang, Jing
Format: Electronic Article Electronic Article
Language: English
Subjects:
Adsorbents
Analytical Chemistry
Anchoring
Carbon nitride
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Core-shell structure
Correlation coefficients
Herbicides
Iron oxides
Linearity
Magnetic cores
Metal-organic frameworks
Microengineering
Nanochemistry
Nanoparticles
Nanostructure
Nanotechnology
Original Paper
Solid phases
Synergistic effect
Zeolites
Publisher: Vienna: Springer Vienna
ID: ISSN: 0026-3672
Link: https://www.ncbi.nlm.nih.gov/pubmed/32314246
Zum Text:
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title: A “half” core-shell magnetic nanohybrid composed of zeolitic imidazolate framework and graphitic carbon nitride for magnetic solid-phase extraction of sulfonylurea herbicides from water samples followed by LC-MS/MS detection
format: Article
creator:
  • Qi, Yan
  • Wan, Mengfei
  • Abd El-Aty, A. M
  • Li, Hui
  • Cao, Liping
  • She, Yongxin
  • Shao, Yong
  • Jin, Fen
  • Wang, Shanshan
  • Wang, Jing
subjects:
  • Adsorbents
  • Analytical Chemistry
  • Anchoring
  • Carbon nitride
  • Characterization and Evaluation of Materials
  • Chemistry
  • Chemistry and Materials Science
  • Core-shell structure
  • Correlation coefficients
  • Herbicides
  • Iron oxides
  • Linearity
  • Magnetic cores
  • Metal-organic frameworks
  • Microengineering
  • Nanochemistry
  • Nanoparticles
  • Nanostructure
  • Nanotechnology
  • Original Paper
  • Solid phases
  • Synergistic effect
  • Zeolites
ispartof: Mikrochimica acta (1966), 2020, Vol.187 (5), p.279-279
description: A “half” core-shell g-C 3 N 4 /Fe 3 O 4 @ZIF-8 nanohybrid, in which Fe 3 O 4 and zeolite imidazolate framework-8 (ZIF-8) constructed the core-shell structure, was successfully fabricated via a versatile in situ growth strategy. This nanohybrid was employed for simultaneous magnetic solid-phase extraction (MSPE) of trace levels of fifteen target sulfonylurea herbicides (SUHs) in environmental water samples followed by LC-MS/MS detection. C 3 N 4 nanosheets were first prepared by liquid exfoliation of bulk g-C 3 N 4 , after which Fe 3 O 4 nanoparticles were uniformly deposited onto the surface of C 3 N 4 nanosheets, and ZIF-8 nanoparticles were grown on the surface of g-C 3 N 4 /Fe 3 O 4 by anchoring Zn 2+ on g-C 3 N 4 /Fe 3 O 4 . Owing to the synergistic effect, the hybridization of C 3 N 4 and ZIF-8 endowed the nanohybrid with higher multi-target adsorption ability for SUHs compared to pure C 3 N 4 or ZIF-8. The separation as well as the enrichment processes were facilitated using Fe 3 O 4 as a magnetic core. The influence of various parameters on MSPE efficiency, including adsorbent dosage, extraction time, solution pH, and desorption solvent and its volume, was investigated in detail. Under optimal conditions, the MSPE coupled with LC-MS/MS exhibited good linearity ranging from 0.5 to 100 μg L −1 with correlation coefficients ( R 2 ) ≥ 0.9919, high sensitivity with low limits of detection (LODs) of 0.005–0.141 μg L −1 and satisfactory recoveries of 67.4–105.5% with relative standard deviations (RSDs)
language: eng
source:
identifier: ISSN: 0026-3672
fulltext: no_fulltext
issn:
  • 0026-3672
  • 1436-5073
url: Link


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titleA “half” core-shell magnetic nanohybrid composed of zeolitic imidazolate framework and graphitic carbon nitride for magnetic solid-phase extraction of sulfonylurea herbicides from water samples followed by LC-MS/MS detection
creatorQi, Yan ; Wan, Mengfei ; Abd El-Aty, A. M ; Li, Hui ; Cao, Liping ; She, Yongxin ; Shao, Yong ; Jin, Fen ; Wang, Shanshan ; Wang, Jing
creatorcontribQi, Yan ; Wan, Mengfei ; Abd El-Aty, A. M ; Li, Hui ; Cao, Liping ; She, Yongxin ; Shao, Yong ; Jin, Fen ; Wang, Shanshan ; Wang, Jing
descriptionA “half” core-shell g-C 3 N 4 /Fe 3 O 4 @ZIF-8 nanohybrid, in which Fe 3 O 4 and zeolite imidazolate framework-8 (ZIF-8) constructed the core-shell structure, was successfully fabricated via a versatile in situ growth strategy. This nanohybrid was employed for simultaneous magnetic solid-phase extraction (MSPE) of trace levels of fifteen target sulfonylurea herbicides (SUHs) in environmental water samples followed by LC-MS/MS detection. C 3 N 4 nanosheets were first prepared by liquid exfoliation of bulk g-C 3 N 4 , after which Fe 3 O 4 nanoparticles were uniformly deposited onto the surface of C 3 N 4 nanosheets, and ZIF-8 nanoparticles were grown on the surface of g-C 3 N 4 /Fe 3 O 4 by anchoring Zn 2+ on g-C 3 N 4 /Fe 3 O 4 . Owing to the synergistic effect, the hybridization of C 3 N 4 and ZIF-8 endowed the nanohybrid with higher multi-target adsorption ability for SUHs compared to pure C 3 N 4 or ZIF-8. The separation as well as the enrichment processes were facilitated using Fe 3 O 4 as a magnetic core. The influence of various parameters on MSPE efficiency, including adsorbent dosage, extraction time, solution pH, and desorption solvent and its volume, was investigated in detail. Under optimal conditions, the MSPE coupled with LC-MS/MS exhibited good linearity ranging from 0.5 to 100 μg L −1 with correlation coefficients ( R 2 ) ≥ 0.9919, high sensitivity with low limits of detection (LODs) of 0.005–0.141 μg L −1 and satisfactory recoveries of 67.4–105.5% with relative standard deviations (RSDs) < 9.8%. These results indicate that this method is reliable for the determination of SUHs in different matrices and the in situ growth strategy is a promising approach for constructing effective adsorbents. Graphical abstract Schematic representation of a “half” core-shell magnetic nanohybrid composed of zeolitic imidazolate framework (ZIF-8) and graphitic carbon nitride (g-C 3 N 4 ) for magnetic solid-phase extraction (MSPE) of trace level determination of fifteen sulfonylurea herbicides (SUHs) in environmental water samples using LC-MS/MS detection.
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subjectAdsorbents ; Analytical Chemistry ; Anchoring ; Carbon nitride ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Core-shell structure ; Correlation coefficients ; Herbicides ; Iron oxides ; Linearity ; Magnetic cores ; Metal-organic frameworks ; Microengineering ; Nanochemistry ; Nanoparticles ; Nanostructure ; Nanotechnology ; Original Paper ; Solid phases ; Synergistic effect ; Zeolites
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7Jin, Fen
8Wang, Shanshan
9Wang, Jing
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descriptionA “half” core-shell g-C 3 N 4 /Fe 3 O 4 @ZIF-8 nanohybrid, in which Fe 3 O 4 and zeolite imidazolate framework-8 (ZIF-8) constructed the core-shell structure, was successfully fabricated via a versatile in situ growth strategy. This nanohybrid was employed for simultaneous magnetic solid-phase extraction (MSPE) of trace levels of fifteen target sulfonylurea herbicides (SUHs) in environmental water samples followed by LC-MS/MS detection. C 3 N 4 nanosheets were first prepared by liquid exfoliation of bulk g-C 3 N 4 , after which Fe 3 O 4 nanoparticles were uniformly deposited onto the surface of C 3 N 4 nanosheets, and ZIF-8 nanoparticles were grown on the surface of g-C 3 N 4 /Fe 3 O 4 by anchoring Zn 2+ on g-C 3 N 4 /Fe 3 O 4 . Owing to the synergistic effect, the hybridization of C 3 N 4 and ZIF-8 endowed the nanohybrid with higher multi-target adsorption ability for SUHs compared to pure C 3 N 4 or ZIF-8. The separation as well as the enrichment processes were facilitated using Fe 3 O 4 as a magnetic core. The influence of various parameters on MSPE efficiency, including adsorbent dosage, extraction time, solution pH, and desorption solvent and its volume, was investigated in detail. Under optimal conditions, the MSPE coupled with LC-MS/MS exhibited good linearity ranging from 0.5 to 100 μg L −1 with correlation coefficients ( R 2 ) ≥ 0.9919, high sensitivity with low limits of detection (LODs) of 0.005–0.141 μg L −1 and satisfactory recoveries of 67.4–105.5% with relative standard deviations (RSDs) < 9.8%. These results indicate that this method is reliable for the determination of SUHs in different matrices and the in situ growth strategy is a promising approach for constructing effective adsorbents. Graphical abstract Schematic representation of a “half” core-shell magnetic nanohybrid composed of zeolitic imidazolate framework (ZIF-8) and graphitic carbon nitride (g-C 3 N 4 ) for magnetic solid-phase extraction (MSPE) of trace level determination of fifteen sulfonylurea herbicides (SUHs) in environmental water samples using LC-MS/MS detection.
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10Iron oxides
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14Microengineering
15Nanochemistry
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21Synergistic effect
22Zeolites
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titleA “half” core-shell magnetic nanohybrid composed of zeolitic imidazolate framework and graphitic carbon nitride for magnetic solid-phase extraction of sulfonylurea herbicides from water samples followed by LC-MS/MS detection
authorQi, Yan ; Wan, Mengfei ; Abd El-Aty, A. M ; Li, Hui ; Cao, Liping ; She, Yongxin ; Shao, Yong ; Jin, Fen ; Wang, Shanshan ; Wang, Jing
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atitleA “half” core-shell magnetic nanohybrid composed of zeolitic imidazolate framework and graphitic carbon nitride for magnetic solid-phase extraction of sulfonylurea herbicides from water samples followed by LC-MS/MS detection
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abstractA “half” core-shell g-C 3 N 4 /Fe 3 O 4 @ZIF-8 nanohybrid, in which Fe 3 O 4 and zeolite imidazolate framework-8 (ZIF-8) constructed the core-shell structure, was successfully fabricated via a versatile in situ growth strategy. This nanohybrid was employed for simultaneous magnetic solid-phase extraction (MSPE) of trace levels of fifteen target sulfonylurea herbicides (SUHs) in environmental water samples followed by LC-MS/MS detection. C 3 N 4 nanosheets were first prepared by liquid exfoliation of bulk g-C 3 N 4 , after which Fe 3 O 4 nanoparticles were uniformly deposited onto the surface of C 3 N 4 nanosheets, and ZIF-8 nanoparticles were grown on the surface of g-C 3 N 4 /Fe 3 O 4 by anchoring Zn 2+ on g-C 3 N 4 /Fe 3 O 4 . Owing to the synergistic effect, the hybridization of C 3 N 4 and ZIF-8 endowed the nanohybrid with higher multi-target adsorption ability for SUHs compared to pure C 3 N 4 or ZIF-8. The separation as well as the enrichment processes were facilitated using Fe 3 O 4 as a magnetic core. The influence of various parameters on MSPE efficiency, including adsorbent dosage, extraction time, solution pH, and desorption solvent and its volume, was investigated in detail. Under optimal conditions, the MSPE coupled with LC-MS/MS exhibited good linearity ranging from 0.5 to 100 μg L −1 with correlation coefficients ( R 2 ) ≥ 0.9919, high sensitivity with low limits of detection (LODs) of 0.005–0.141 μg L −1 and satisfactory recoveries of 67.4–105.5% with relative standard deviations (RSDs) < 9.8%. These results indicate that this method is reliable for the determination of SUHs in different matrices and the in situ growth strategy is a promising approach for constructing effective adsorbents. Graphical abstract Schematic representation of a “half” core-shell magnetic nanohybrid composed of zeolitic imidazolate framework (ZIF-8) and graphitic carbon nitride (g-C 3 N 4 ) for magnetic solid-phase extraction (MSPE) of trace level determination of fifteen sulfonylurea herbicides (SUHs) in environmental water samples using LC-MS/MS detection.
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doi10.1007/s00604-020-04243-5
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