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Catalytic Oxidation in Supercritical Water

Recently, catalytic oxidation in supercritical water (SCW) has received considerable research attention. The major thrust of this current research effort is attributable to the rapid development of supercritical water oxidation (SCWO) as an innovative wastewater treatment technology. The incentives... Full description

Journal Title: Industrial & Engineering Chemistry Research 01/1996, Vol.35(10), pp.3257-3279
Main Author: Ding, Zhong Yi
Other Authors: Frisch, Michael A. , Li, Lixiong , Gloyna, Earnest F.
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 0888-5885 ; E-ISSN: 1520-5045 ; DOI: http://dx.doi.org/10.1021/ie960022n
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recordid: crossref10.1021/ie960022n
title: Catalytic Oxidation in Supercritical Water
format: Article
creator:
  • Ding, Zhong Yi
  • Frisch, Michael A.
  • Li, Lixiong
  • Gloyna, Earnest F.
subjects:
  • Energy Conservation, Consumption, And Utilization Environmental Sciences Waste Water
  • Water Treatment
  • Organic Compounds
  • Oxidation
  • Catalysts
  • Reviews
  • Supercritical State
  • Hydrolysis
  • Chemical Preparation
  • Catalysis
ispartof: Industrial & Engineering Chemistry Research, 01/1996, Vol.35(10), pp.3257-3279
description: Recently, catalytic oxidation in supercritical water (SCW) has received considerable research attention. The major thrust of this current research effort is attributable to the rapid development of supercritical water oxidation (SCWO) as an innovative wastewater treatment technology. The incentives of catalyst-enhanced processes may include increased reaction rates, reduced residence times and temperatures, and optimized reaction pathways that are otherwise difficult to achieve through noncatalytic processes. However, the databases associated with the use of catalysts in SCWO are limited. The purpose of this paper is to (1) review catalytic enhancement and technology as related to SCWO; (2) analyze effects of SCW on catalysts and catalytic SCWO processes; and (3) present a catalyst development strategy for SCWO-related applications. Catalyst activity and stability (in terms of reaction kinetics, surface phenomena, and phase behavior of catalysts in SCW) are emphasized. The paper presents a useful database, provides guidelines for catalyst selection, and illustrates how effective use of catalyst may enhance SCWO process development. 230 refs. Journal Article.
language: eng
source:
identifier: ISSN: 0888-5885 ; E-ISSN: 1520-5045 ; DOI: http://dx.doi.org/10.1021/ie960022n
fulltext: no_fulltext
issn:
  • 08885885
  • 0888-5885
  • 15205045
  • 1520-5045
url: Link


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descriptionRecently, catalytic oxidation in supercritical water (SCW) has received considerable research attention. The major thrust of this current research effort is attributable to the rapid development of supercritical water oxidation (SCWO) as an innovative wastewater treatment technology. The incentives of catalyst-enhanced processes may include increased reaction rates, reduced residence times and temperatures, and optimized reaction pathways that are otherwise difficult to achieve through noncatalytic processes. However, the databases associated with the use of catalysts in SCWO are limited. The purpose of this paper is to (1) review catalytic enhancement and technology as related to SCWO; (2) analyze effects of SCW on catalysts and catalytic SCWO processes; and (3) present a catalyst development strategy for SCWO-related applications. Catalyst activity and stability (in terms of reaction kinetics, surface phenomena, and phase behavior of catalysts in SCW) are emphasized. The paper presents a useful database, provides guidelines for catalyst selection, and illustrates how effective use of catalyst may enhance SCWO process development. 230 refs. Journal Article.
subjectEnergy Conservation, Consumption, And Utilization Environmental Sciences Waste Water ; Water Treatment ; Organic Compounds ; Oxidation ; Catalysts ; Reviews ; Supercritical State ; Hydrolysis ; Chemical Preparation ; Catalysis;
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