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A Solution Study of Complex Formation of Some Diamines with Lanthanones

To study the metal ligand equilibrium in aqueous solution, the well known Irving-Rossotti titration method was used. The temperature selected is 30±0.10C at ionic strength 0.2 M (NaClO4) which was maintained constant through out the work. The binary metal complex (ML2) formation was studied. The met... Full description

Journal Title: E-journal of chemistry 2009, Vol.6 (1), p.270-272
Main Author: Vora, J. J
Other Authors: Patel, D. R , Patel, Asha D , Patel, Kanu , Sharma, Sangita , Bhutadiya, Laxman S , Vasava, Sunil B
Format: Electronic Article Electronic Article
Language: English
Subjects:
Publisher: Hindawi Publishing Corporation
ID: ISSN: 0973-4945
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title: A Solution Study of Complex Formation of Some Diamines with Lanthanones
format: Article
creator:
  • Vora, J. J
  • Patel, D. R
  • Patel, Asha D
  • Patel, Kanu
  • Sharma, Sangita
  • Bhutadiya, Laxman S
  • Vasava, Sunil B
subjects:
  • Chemistry
ispartof: E-journal of chemistry, 2009, Vol.6 (1), p.270-272
description: To study the metal ligand equilibrium in aqueous solution, the well known Irving-Rossotti titration method was used. The temperature selected is 30±0.10C at ionic strength 0.2 M (NaClO4) which was maintained constant through out the work. The binary metal complex (ML2) formation was studied. The metals selected are Sm3+, Gd3+, Dy3+and Yb3+. The diamine ligands taken are ethylenediamine, 1,2 diamino propane, 1,3 diamino propane,N-Ndiethyl ethylenediamine andN-N -dimethyl ethylenediamine. Factors that affected the stability of the complexes are size and ionic potential of lanthanone ions, basicity of ligands, ring size and steric effect of ligands.
language: eng
source:
identifier: ISSN: 0973-4945
fulltext: no_fulltext
issn:
  • 0973-4945
  • 2090-9810
url: Link


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titleA Solution Study of Complex Formation of Some Diamines with Lanthanones
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descriptionTo study the metal ligand equilibrium in aqueous solution, the well known Irving-Rossotti titration method was used. The temperature selected is 30±0.10C at ionic strength 0.2 M (NaClO4) which was maintained constant through out the work. The binary metal complex (ML2) formation was studied. The metals selected are Sm3+, Gd3+, Dy3+and Yb3+. The diamine ligands taken are ethylenediamine, 1,2 diamino propane, 1,3 diamino propane,N-Ndiethyl ethylenediamine andN-N -dimethyl ethylenediamine. Factors that affected the stability of the complexes are size and ionic potential of lanthanone ions, basicity of ligands, ring size and steric effect of ligands.
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issn0973-4945
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abstractTo study the metal ligand equilibrium in aqueous solution, the well known Irving-Rossotti titration method was used. The temperature selected is 30±0.10C at ionic strength 0.2 M (NaClO4) which was maintained constant through out the work. The binary metal complex (ML2) formation was studied. The metals selected are Sm3+, Gd3+, Dy3+and Yb3+. The diamine ligands taken are ethylenediamine, 1,2 diamino propane, 1,3 diamino propane,N-Ndiethyl ethylenediamine andN-N -dimethyl ethylenediamine. Factors that affected the stability of the complexes are size and ionic potential of lanthanone ions, basicity of ligands, ring size and steric effect of ligands.
pubHindawi Publishing Corporation
doi10.1155/2009/205983
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