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Application of Singh-Jha Equation in the Evaluation of b Parameter of Laidler-Landskroener Equation in the Hydrolysis of Vinyl Acetate

Singh-Jha method is applied to calculate b* of Laidler-Landskroener equation, the distance of closed approach of solvent molecules to the activated complexes in alkaline hydrolysis of vinyl acetate. This method is applied to alkaline hydrolysis of vinyl acetate in water enriched ethanol between 30 °... Full description

Journal Title: E-journal of chemistry 01 January 2010, Vol.7(4), pp.1170-1173
Main Author: Sangita Sharma
Other Authors: Bijal Vyas , Falguni Thakkar , Ketan Patel , J. J. Vora
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 0973-4945 ; E-ISSN: 2090-9810 ; DOI: 10.1155/2010/451523
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title: Application of Singh-Jha Equation in the Evaluation of b Parameter of Laidler-Landskroener Equation in the Hydrolysis of Vinyl Acetate
format: Article
creator:
  • Sangita Sharma
  • Bijal Vyas
  • Falguni Thakkar
  • Ketan Patel
  • J. J. Vora
subjects:
  • Chemistry
ispartof: E-journal of chemistry, 01 January 2010, Vol.7(4), pp.1170-1173
description: Singh-Jha method is applied to calculate b* of Laidler-Landskroener equation, the distance of closed approach of solvent molecules to the activated complexes in alkaline hydrolysis of vinyl acetate. This method is applied to alkaline hydrolysis of vinyl acetate in water enriched ethanol between 30 °C and 35 °C. The rate of hydrolysis decreases with the increase of content of organic solvent at both temperatures. The size of transition state was found to be large as compared to the initial state. The b* was found to be 3.7693Å which is in agreement with the values obtained earlier.
language: eng
source:
identifier: ISSN: 0973-4945 ; E-ISSN: 2090-9810 ; DOI: 10.1155/2010/451523
fulltext: fulltext_linktorsrc
issn:
  • 0973-4945
  • 09734945
  • 2090-9810
  • 20909810
url: Link


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titleApplication of Singh-Jha Equation in the Evaluation of b Parameter of Laidler-Landskroener Equation in the Hydrolysis of Vinyl Acetate
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descriptionSingh-Jha method is applied to calculate b* of Laidler-Landskroener equation, the distance of closed approach of solvent molecules to the activated complexes in alkaline hydrolysis of vinyl acetate. This method is applied to alkaline hydrolysis of vinyl acetate in water enriched ethanol between 30 °C and 35 °C. The rate of hydrolysis decreases with the increase of content of organic solvent at both temperatures. The size of transition state was found to be large as compared to the initial state. The b* was found to be 3.7693Å which is in agreement with the values obtained earlier.
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description

Singh-Jha method is applied to calculate b* of Laidler-Landskroener equation, the distance of closed approach of solvent molecules to the activated complexes in alkaline hydrolysis of vinyl acetate. This method is applied to alkaline hydrolysis of vinyl acetate in water enriched ethanol between 30 °C and 35 °C. The rate of hydrolysis decreases with the increase of content of organic solvent at both temperatures. The size of transition state was found to be large as compared to the initial state. The b* was found to be 3.7693Å which is in agreement with the values obtained earlier.

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Singh-Jha method is applied to calculate b* of Laidler-Landskroener equation, the distance of closed approach of solvent molecules to the activated complexes in alkaline hydrolysis of vinyl acetate. This method is applied to alkaline hydrolysis of vinyl acetate in water enriched ethanol between 30 °C and 35 °C. The rate of hydrolysis decreases with the increase of content of organic solvent at both temperatures. The size of transition state was found to be large as compared to the initial state. The b* was found to be 3.7693Å which is in agreement with the values obtained earlier.

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