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Determination of terbium in phosphate rock by Tb 3+-selective fluorimetric optode based on dansyl derivative as a neutral fluorogenic ionophore

For the first time a highly sensitive and selective fluorimetric optode membrane was prepared for determination of trace amounts of Tb(III) ions in phosphate rock samples. The Tb(III) sensing system was constructed by incorporating 5-(dimethylamino)-N′-(2-hydroxy-1-naphthoyl) naphthalene-1-sulfonohy... Full description

Journal Title: Analytica Chimica Acta 2010, Vol.664(2), pp.172-177
Main Author: Hosseini, Morteza
Other Authors: Ganjali, Mohammad Reza , Veismohammadi, Bahareh , Faridbod, Farnoush , Abkenar, Shiva Dehghan , Norouzi, Parviz
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 0003-2670 ; E-ISSN: 1873-4324 ; DOI: 10.1016/j.aca.2010.02.016
Link: https://www.sciencedirect.com/science/article/pii/S0003267010002576
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recordid: elsevier_sdoi_10_1016_j_aca_2010_02_016
title: Determination of terbium in phosphate rock by Tb 3+-selective fluorimetric optode based on dansyl derivative as a neutral fluorogenic ionophore
format: Article
creator:
  • Hosseini, Morteza
  • Ganjali, Mohammad Reza
  • Veismohammadi, Bahareh
  • Faridbod, Farnoush
  • Abkenar, Shiva Dehghan
  • Norouzi, Parviz
subjects:
  • Sensor
  • Optode
  • Terbium
  • Fluorescence
  • Chemistry
ispartof: Analytica Chimica Acta, 2010, Vol.664(2), pp.172-177
description: For the first time a highly sensitive and selective fluorimetric optode membrane was prepared for determination of trace amounts of Tb(III) ions in phosphate rock samples. The Tb(III) sensing system was constructed by incorporating 5-(dimethylamino)-N′-(2-hydroxy-1-naphthoyl) naphthalene-1-sulfonohydrazine (L) as a neutral Tb(III)-selective fluoroionophore, in the plasticized PVC membrane containing sodium tetraphenyl borate as a liphophilic anionic additive. The response of the optode is based on the strong fluorescence quenching of L by Tb ions. At a pH value of 5.0, the optode displays a wide concentration range of 1.0 × 10 to 1.0 × 10 M, with a relatively fast response time of less than 45 s. In addition, to high stability and reproducibility, the sensor shows a unique...
language: eng
source:
identifier: ISSN: 0003-2670 ; E-ISSN: 1873-4324 ; DOI: 10.1016/j.aca.2010.02.016
fulltext: fulltext
issn:
  • 0003-2670
  • 00032670
  • 1873-4324
  • 18734324
url: Link


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titleDetermination of terbium in phosphate rock by Tb 3+-selective fluorimetric optode based on dansyl derivative as a neutral fluorogenic ionophore
creatorHosseini, Morteza ; Ganjali, Mohammad Reza ; Veismohammadi, Bahareh ; Faridbod, Farnoush ; Abkenar, Shiva Dehghan ; Norouzi, Parviz
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descriptionFor the first time a highly sensitive and selective fluorimetric optode membrane was prepared for determination of trace amounts of Tb(III) ions in phosphate rock samples. The Tb(III) sensing system was constructed by incorporating 5-(dimethylamino)-N′-(2-hydroxy-1-naphthoyl) naphthalene-1-sulfonohydrazine (L) as a neutral Tb(III)-selective fluoroionophore, in the plasticized PVC membrane containing sodium tetraphenyl borate as a liphophilic anionic additive. The response of the optode is based on the strong fluorescence quenching of L by Tb ions. At a pH value of 5.0, the optode displays a wide concentration range of 1.0 × 10 to 1.0 × 10 M, with a relatively fast response time of less than 45 s. In addition, to high stability and reproducibility, the sensor shows a unique...
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