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Construction of barium (II) PVC membrane electrochemical sensor based on 3-deoxy-d-erythro-hexos-2-ulose bis (thiosemicarbazone) as a novel ionophore

In this study, a new ion-selective electrode for Ba is described, illustrating 3-deoxy- -erythro-hexos-2-ulose bis (thiosemicarbazone) (DHUT) in a poly(vinylchloride) (PVC) membrane with benzyl acetate (BA) as a plasticizer and sodium tetraphenyl borate (NaTPB) as an anionic additive. This sensor pr... Full description

Journal Title: Desalination 01 January 2010, Vol.250(1), pp.56-61
Main Author: Zamani, Hassan Ali
Other Authors: Hamed-Mosavian, Mohammad Taghi , Aminzadeh, Elham , Ganjali, Mohammad Reza , Ghaemy, Mousa , Behmadi, Hossien , Faridbod, Farnoush
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 0011-9164 ; E-ISSN: 1873-4464 ; DOI: 10.1016/j.desal.2009.09.014
Link: https://www.sciencedirect.com/science/article/pii/S0011916409009643
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recordid: elsevier_sdoi_10_1016_j_desal_2009_09_014
title: Construction of barium (II) PVC membrane electrochemical sensor based on 3-deoxy-d-erythro-hexos-2-ulose bis (thiosemicarbazone) as a novel ionophore
format: Article
creator:
  • Zamani, Hassan Ali
  • Hamed-Mosavian, Mohammad Taghi
  • Aminzadeh, Elham
  • Ganjali, Mohammad Reza
  • Ghaemy, Mousa
  • Behmadi, Hossien
  • Faridbod, Farnoush
subjects:
  • Pvc Membrane
  • Ion-Selective Electrode
  • Sensor
  • Potentiometry
  • 3-Deoxy-D-Erythro-Hexos-2-Ulose Bis (Thiosemicarbazone)
  • Engineering
ispartof: Desalination, 01 January 2010, Vol.250(1), pp.56-61
description: In this study, a new ion-selective electrode for Ba is described, illustrating 3-deoxy- -erythro-hexos-2-ulose bis (thiosemicarbazone) (DHUT) in a poly(vinylchloride) (PVC) membrane with benzyl acetate (BA) as a plasticizer and sodium tetraphenyl borate (NaTPB) as an anionic additive. This sensor presented very good selectivity and sensitivity towards the Ba ions over a wide variety of cations, including alkali, alkaline earth, transition and heavy metal ions. The electrode revealed a great improvement in the selectivity coefficients for the Ba ions in comparison with the formerly reported Ba sensors. The proposed electrode exhibited a significantly enhanced response towards the Ba ions across the concentration range of 1.0 × 10 –1.0 × 10 M for the...
language: eng
source:
identifier: ISSN: 0011-9164 ; E-ISSN: 1873-4464 ; DOI: 10.1016/j.desal.2009.09.014
fulltext: fulltext
issn:
  • 0011-9164
  • 00119164
  • 1873-4464
  • 18734464
url: Link


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titleConstruction of barium (II) PVC membrane electrochemical sensor based on 3-deoxy-d-erythro-hexos-2-ulose bis (thiosemicarbazone) as a novel ionophore
creatorZamani, Hassan Ali ; Hamed-Mosavian, Mohammad Taghi ; Aminzadeh, Elham ; Ganjali, Mohammad Reza ; Ghaemy, Mousa ; Behmadi, Hossien ; Faridbod, Farnoush
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subjectPvc Membrane ; Ion-Selective Electrode ; Sensor ; Potentiometry ; 3-Deoxy-D-Erythro-Hexos-2-Ulose Bis (Thiosemicarbazone) ; Engineering
descriptionIn this study, a new ion-selective electrode for Ba is described, illustrating 3-deoxy- -erythro-hexos-2-ulose bis (thiosemicarbazone) (DHUT) in a poly(vinylchloride) (PVC) membrane with benzyl acetate (BA) as a plasticizer and sodium tetraphenyl borate (NaTPB) as an anionic additive. This sensor presented very good selectivity and sensitivity towards the Ba ions over a wide variety of cations, including alkali, alkaline earth, transition and heavy metal ions. The electrode revealed a great improvement in the selectivity coefficients for the Ba ions in comparison with the formerly reported Ba sensors. The proposed electrode exhibited a significantly enhanced response towards the Ba ions across the concentration range of 1.0 × 10 –1.0 × 10 M for the...
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