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Oxygen binding to sulfur in nitrosylated iron-thiolate complexes: relevance to the Fe-containing nitrile hydratases

The promotion of sulfur oxygenation of iron-dithiolates by molecular oxygen and the stabilization of the S-bonded monosulfinate iron species due to the binding of one NO molecule to the Fe center is discussed. Iron NO-bound complex [(NO)Fe(S,S-C6H4)2](super -1) and S-bonded monosulfinate [(NO)Fe(S,S... Full description

Journal Title: Journal of the American Chemical Society Sept 24, 2003, Vol.125(38), p.11492-11493
Main Author: Chien - Ming Lee
Other Authors: Chung - Hung Hsieh , Dutta, Amitava , Gene - Hsiang Lee , Wen - Feng Liaw
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 0002-7863
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recordid: gale_ofa123559790
title: Oxygen binding to sulfur in nitrosylated iron-thiolate complexes: relevance to the Fe-containing nitrile hydratases
format: Article
creator:
  • Chien - Ming Lee
  • Chung - Hung Hsieh
  • Dutta, Amitava
  • Gene - Hsiang Lee
  • Wen - Feng Liaw
subjects:
  • Sulfur -- Chemical Properties
  • Iron (Metal) -- Research
  • Photochemistry -- Research
  • Nitriles -- Research
ispartof: Journal of the American Chemical Society, Sept 24, 2003, Vol.125(38), p.11492-11493
description: The promotion of sulfur oxygenation of iron-dithiolates by molecular oxygen and the stabilization of the S-bonded monosulfinate iron species due to the binding of one NO molecule to the Fe center is discussed. Iron NO-bound complex [(NO)Fe(S,S-C6H4)2](super -1) and S-bonded monosulfinate [(NO)Fe(S,SO2-C6H4)(S,S-C6H4)](super -1) are found to be photochemically interconvertible.
language: English
source:
identifier: ISSN: 0002-7863
fulltext: fulltext
issn:
  • 0002-7863
  • 00027863
url: Link


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titleOxygen binding to sulfur in nitrosylated iron-thiolate complexes: relevance to the Fe-containing nitrile hydratases
creatorChien - Ming Lee ; Chung - Hung Hsieh ; Dutta, Amitava ; Gene - Hsiang Lee ; Wen - Feng Liaw
ispartofJournal of the American Chemical Society, Sept 24, 2003, Vol.125(38), p.11492-11493
identifierISSN: 0002-7863
subjectSulfur -- Chemical Properties ; Iron (Metal) -- Research ; Photochemistry -- Research ; Nitriles -- Research
descriptionThe promotion of sulfur oxygenation of iron-dithiolates by molecular oxygen and the stabilization of the S-bonded monosulfinate iron species due to the binding of one NO molecule to the Fe center is discussed. Iron NO-bound complex [(NO)Fe(S,S-C6H4)2](super -1) and S-bonded monosulfinate [(NO)Fe(S,SO2-C6H4)(S,S-C6H4)](super -1) are found to be photochemically interconvertible.
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titleOxygen binding to sulfur in nitrosylated iron-thiolate complexes: relevance to the Fe-containing nitrile hydratases.
descriptionThe promotion of sulfur oxygenation of iron-dithiolates by molecular oxygen and the stabilization of the S-bonded monosulfinate iron species due to the binding of one NO molecule to the Fe center is discussed. Iron NO-bound complex [(NO)Fe(S,S-C6H4)2](super -1) and S-bonded monosulfinate [(NO)Fe(S,SO2-C6H4)(S,S-C6H4)](super -1) are found to be photochemically interconvertible.
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abstractThe promotion of sulfur oxygenation of iron-dithiolates by molecular oxygen and the stabilization of the S-bonded monosulfinate iron species due to the binding of one NO molecule to the Fe center is discussed. Iron NO-bound complex [(NO)Fe(S,S-C6H4)2](super -1) and S-bonded monosulfinate [(NO)Fe(S,SO2-C6H4)(S,S-C6H4)](super -1) are found to be photochemically interconvertible.
pubAmerican Chemical Society
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date2003-09-24