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Mononuclear [Ni.sup.III]-alkyl complexes (Alkyl = Me and Et): relevance to the acetyl-CoA synthase and methyl-CoM reductase.(Report)

Individual reactions of [PPN][[Ni.sup.III]Cl(P[([C.sub.6][H.sub.3]-3-Si[Me.sub.3]-2-S).sub.3])] and C[H.sub.3]MgCl/[C.sub.2][H.sub.5]MgCl are used to synthesize mononuclear, distorted trigonal bipyramidal [PPN][[Ni.sup.III](R)(P[([C.sub.6][H.sub.3]-3-Si[Me.sub.3]-2-S).sub.3])] (R = Me ; R = Et ). Th... Full description

Journal Title: Journal of the American Chemical Society July 14, 2010, Vol.132(27), p.9256-9258
Main Author: Chien - Ming Lee
Other Authors: Chien - Hong Chen , Fu - Xing Liao , Ching - Han Hu , Gene - Hsiang Lee
Format: Electronic Article Electronic Article
Language: English
Subjects:
Quelle: Cengage Learning, Inc.
ID: ISSN: 0002-7863
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recordid: gale_ofa234971460
title: Mononuclear [Ni.sup.III]-alkyl complexes (Alkyl = Me and Et): relevance to the acetyl-CoA synthase and methyl-CoM reductase.(Report)
format: Article
creator:
  • Chien - Ming Lee
  • Chien - Hong Chen
  • Fu - Xing Liao
  • Ching - Han Hu
  • Gene - Hsiang Lee
subjects:
  • Cobalt Compounds -- Chemical Properties
  • Chemical Synthesis -- Analysis
  • Silicon Compounds -- Chemical Properties
  • Nickel Compounds -- Chemical Properties
ispartof: Journal of the American Chemical Society, July 14, 2010, Vol.132(27), p.9256-9258
description: Individual reactions of [PPN][[Ni.sup.III]Cl(P[([C.sub.6][H.sub.3]-3-Si[Me.sub.3]-2-S).sub.3])] and C[H.sub.3]MgCl/[C.sub.2][H.sub.5]MgCl are used to synthesize mononuclear, distorted trigonal bipyramidal [PPN][[Ni.sup.III](R)(P[([C.sub.6][H.sub.3]-3-Si[Me.sub.3]-2-S).sub.3])] (R = Me ; R = Et ). The results offer insight into the low-spin [d.sup.7] electronic configuration in a distorted trigonal bipyramidal ligand field of the [Ni.sup.III].
language: English
source: Cengage Learning, Inc.
identifier: ISSN: 0002-7863
fulltext: fulltext
issn:
  • 0002-7863
  • 00027863
url: Link


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titleMononuclear [Ni.sup.III]-alkyl complexes (Alkyl = Me and Et): relevance to the acetyl-CoA synthase and methyl-CoM reductase.(Report)
creatorChien - Ming Lee ; Chien - Hong Chen ; Fu - Xing Liao ; Ching - Han Hu ; Gene - Hsiang Lee
ispartofJournal of the American Chemical Society, July 14, 2010, Vol.132(27), p.9256-9258
identifierISSN: 0002-7863
subjectCobalt Compounds -- Chemical Properties ; Chemical Synthesis -- Analysis ; Silicon Compounds -- Chemical Properties ; Nickel Compounds -- Chemical Properties
descriptionIndividual reactions of [PPN][[Ni.sup.III]Cl(P[([C.sub.6][H.sub.3]-3-Si[Me.sub.3]-2-S).sub.3])] and C[H.sub.3]MgCl/[C.sub.2][H.sub.5]MgCl are used to synthesize mononuclear, distorted trigonal bipyramidal [PPN][[Ni.sup.III](R)(P[([C.sub.6][H.sub.3]-3-Si[Me.sub.3]-2-S).sub.3])] (R = Me ; R = Et ). The results offer insight into the low-spin [d.sup.7] electronic configuration in a distorted trigonal bipyramidal ligand field of the [Ni.sup.III].
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descriptionIndividual reactions of [PPN][[Ni.sup.III]Cl(P[([C.sub.6][H.sub.3]-3-Si[Me.sub.3]-2-S).sub.3])] and C[H.sub.3]MgCl/[C.sub.2][H.sub.5]MgCl are used to synthesize mononuclear, distorted trigonal bipyramidal [PPN][[Ni.sup.III](R)(P[([C.sub.6][H.sub.3]-3-Si[Me.sub.3]-2-S).sub.3])] (R = Me ; R = Et ). The results offer insight into the low-spin [d.sup.7] electronic configuration in a distorted trigonal bipyramidal ligand field of the [Ni.sup.III].
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abstractIndividual reactions of [PPN][[Ni.sup.III]Cl(P[([C.sub.6][H.sub.3]-3-Si[Me.sub.3]-2-S).sub.3])] and C[H.sub.3]MgCl/[C.sub.2][H.sub.5]MgCl are used to synthesize mononuclear, distorted trigonal bipyramidal [PPN][[Ni.sup.III](R)(P[([C.sub.6][H.sub.3]-3-Si[Me.sub.3]-2-S).sub.3])] (R = Me ; R = Et ). The results offer insight into the low-spin [d.sup.7] electronic configuration in a distorted trigonal bipyramidal ligand field of the [Ni.sup.III].
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