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Total synthesis and absolute stereochemical assignment of kibdelone C.(Report)

The synthesis of a chiral, nonracemic iodocyclohexene carboxylate EF ring fragment of the kibdelones by using an intramolecular iodo halo-Michael aldol reaction and its merger with an ABCD ring fragment to produce the congener kibdelone C is described.

Journal Title: Journal of the American Chemical Society July 6, 2011, Vol.133(26), p.9952-9955
Main Author: Sloman, David L.
Other Authors: Bacon, Jeffrey W. , Porco, John A. , Jr.
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 0002-7863
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title: Total synthesis and absolute stereochemical assignment of kibdelone C.(Report)
format: Article
creator:
  • Sloman, David L.
  • Bacon, Jeffrey W.
  • Porco, John A. , Jr.
subjects:
  • Hexene -- Chemical Properties
  • Antineoplastic Agents -- Chemical Properties
  • Antineoplastic Agents -- Structure
  • Carboxyl Compounds -- Chemical Properties
  • Molecular Structure -- Analysis
ispartof: Journal of the American Chemical Society, July 6, 2011, Vol.133(26), p.9952-9955
description: The synthesis of a chiral, nonracemic iodocyclohexene carboxylate EF ring fragment of the kibdelones by using an intramolecular iodo halo-Michael aldol reaction and its merger with an ABCD ring fragment to produce the congener kibdelone C is described.
language: English
source:
identifier: ISSN: 0002-7863
fulltext: no_fulltext
issn:
  • 0002-7863
  • 00027863
url: Link


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titleTotal synthesis and absolute stereochemical assignment of kibdelone C.(Report)
creatorSloman, David L. ; Bacon, Jeffrey W. ; Porco, John A. , Jr.
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identifierISSN: 0002-7863
subjectHexene -- Chemical Properties ; Antineoplastic Agents -- Chemical Properties ; Antineoplastic Agents -- Structure ; Carboxyl Compounds -- Chemical Properties ; Molecular Structure -- Analysis
descriptionThe synthesis of a chiral, nonracemic iodocyclohexene carboxylate EF ring fragment of the kibdelones by using an intramolecular iodo halo-Michael aldol reaction and its merger with an ABCD ring fragment to produce the congener kibdelone C is described.
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titleTotal synthesis and absolute stereochemical assignment of kibdelone C.(Report)
descriptionThe synthesis of a chiral, nonracemic iodocyclohexene carboxylate EF ring fragment of the kibdelones by using an intramolecular iodo halo-Michael aldol reaction and its merger with an ABCD ring fragment to produce the congener kibdelone C is described.
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abstractThe synthesis of a chiral, nonracemic iodocyclohexene carboxylate EF ring fragment of the kibdelones by using an intramolecular iodo halo-Michael aldol reaction and its merger with an ABCD ring fragment to produce the congener kibdelone C is described.
pubAmerican Chemical Society
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doi10.1021/ja203642n
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date2011-07-06