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Synthesis and properties of methyl hexahydrophthalic anhydride-cured fluorinated epoxy resin 2,2-bisphenol hexafluoropropane diglycidyl ether

Byline: Miao Yin, Li Yang, Xiu-yun Li, Han-bing Ma Keywords: thermosets; synthesis and processing; dielectric properties; thermal properties; structure-property relations ABSTRACT The fluorinated epoxy resin, 2,2-bisphenol hexafluoropropane diglycidyl ether (DGEBHF) was synthesized through a two-ste... Full description

Journal Title: Journal of Applied Polymer Science Nov, 2013, Vol.130(4), p.2801(9)
Main Author: Yin, Miao
Other Authors: Yang, Li , Li, Xiu - Yun , Ma, Han - Bing
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 0021-8995
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recordid: gale_ofa350157014
title: Synthesis and properties of methyl hexahydrophthalic anhydride-cured fluorinated epoxy resin 2,2-bisphenol hexafluoropropane diglycidyl ether
format: Article
creator:
  • Yin, Miao
  • Yang, Li
  • Li, Xiu - Yun
  • Ma, Han - Bing
subjects:
  • Epoxy Resins -- Analysis
  • Dielectric Materials -- Analysis
ispartof: Journal of Applied Polymer Science, Nov, 2013, Vol.130(4), p.2801(9)
description: Byline: Miao Yin, Li Yang, Xiu-yun Li, Han-bing Ma Keywords: thermosets; synthesis and processing; dielectric properties; thermal properties; structure-property relations ABSTRACT The fluorinated epoxy resin, 2,2-bisphenol hexafluoropropane diglycidyl ether (DGEBHF) was synthesized through a two-step procedure, and the chemical structure was confirmed by .sub.1H nuclear magnetic resonance (NMR), .sub.13C NMR, and Fourier transform infrared (FTIR) spectra. Moreover, DGEBHF was thermally cured with methyl hexahydrophthalic anhydride (MHHPA). The results clearly indicated that the cured DGEBHF/MHHPA exhibited higher glass transition temperature (T.sub.g 147[degrees]C) and thermal decomposition temperature at 5% weight loss (T.sub.5 372[degrees]C) than those (T.sub.g 131.2[degrees]C; T.sub.5 362[degrees]C) of diglycidyl ether of bisphenol A (DGEBA)/MHHPA. In addition, the incorporation of bis-trifluoromethyl groups led to enhanced dielectric properties with lower dielectric constant (D.sub.k 2.93) of DGEBHF/MHHPA compared with cured DGEBA resins (D.sub.k 3.25). The cured fluorinated epoxy resin also gave lower water absorption measured in two methods relative to its nonfluorinated counterparts. [c] 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 2801-2808, 2013
language: English
source:
identifier: ISSN: 0021-8995
fulltext: fulltext
issn:
  • 0021-8995
  • 00218995
url: Link


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titleSynthesis and properties of methyl hexahydrophthalic anhydride-cured fluorinated epoxy resin 2,2-bisphenol hexafluoropropane diglycidyl ether
creatorYin, Miao ; Yang, Li ; Li, Xiu - Yun ; Ma, Han - Bing
ispartofJournal of Applied Polymer Science, Nov, 2013, Vol.130(4), p.2801(9)
identifierISSN: 0021-8995
subjectEpoxy Resins -- Analysis ; Dielectric Materials -- Analysis
descriptionByline: Miao Yin, Li Yang, Xiu-yun Li, Han-bing Ma Keywords: thermosets; synthesis and processing; dielectric properties; thermal properties; structure-property relations ABSTRACT The fluorinated epoxy resin, 2,2-bisphenol hexafluoropropane diglycidyl ether (DGEBHF) was synthesized through a two-step procedure, and the chemical structure was confirmed by .sub.1H nuclear magnetic resonance (NMR), .sub.13C NMR, and Fourier transform infrared (FTIR) spectra. Moreover, DGEBHF was thermally cured with methyl hexahydrophthalic anhydride (MHHPA). The results clearly indicated that the cured DGEBHF/MHHPA exhibited higher glass transition temperature (T.sub.g 147[degrees]C) and thermal decomposition temperature at 5% weight loss (T.sub.5 372[degrees]C) than those (T.sub.g 131.2[degrees]C; T.sub.5 362[degrees]C) of diglycidyl ether of bisphenol A (DGEBA)/MHHPA. In addition, the incorporation of bis-trifluoromethyl groups led to enhanced dielectric properties with lower dielectric constant (D.sub.k 2.93) of DGEBHF/MHHPA compared with cured DGEBA resins (D.sub.k 3.25). The cured fluorinated epoxy resin also gave lower water absorption measured in two methods relative to its nonfluorinated counterparts. [c] 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 2801-2808, 2013
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titleSynthesis and properties of methyl hexahydrophthalic anhydride-cured fluorinated epoxy resin 2,2-bisphenol hexafluoropropane diglycidyl ether.
descriptionByline: Miao Yin, Li Yang, Xiu-yun Li, Han-bing Ma Keywords: thermosets; synthesis and processing; dielectric properties; thermal properties; structure-property relations ABSTRACT The fluorinated epoxy resin, 2,2-bisphenol hexafluoropropane diglycidyl ether (DGEBHF) was synthesized through a two-step procedure, and the chemical structure was confirmed by .sub.1H nuclear magnetic resonance (NMR), .sub.13C NMR, and Fourier transform infrared (FTIR) spectra. Moreover, DGEBHF was thermally cured with methyl hexahydrophthalic anhydride (MHHPA). The results clearly indicated that the cured DGEBHF/MHHPA exhibited higher glass transition temperature (T.sub.g 147[degrees]C) and thermal decomposition temperature at 5% weight loss (T.sub.5 372[degrees]C) than those (T.sub.g 131.2[degrees]C; T.sub.5 362[degrees]C) of diglycidyl ether of bisphenol A (DGEBA)/MHHPA. In addition, the incorporation of bis-trifluoromethyl groups led to enhanced dielectric properties with lower dielectric constant (D.sub.k 2.93) of DGEBHF/MHHPA compared with cured DGEBA resins (D.sub.k 3.25). The cured fluorinated epoxy resin also gave lower water absorption measured in two methods relative to its nonfluorinated counterparts. [c] 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 2801-2808, 2013
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abstractByline: Miao Yin, Li Yang, Xiu-yun Li, Han-bing Ma Keywords: thermosets; synthesis and processing; dielectric properties; thermal properties; structure-property relations ABSTRACT The fluorinated epoxy resin, 2,2-bisphenol hexafluoropropane diglycidyl ether (DGEBHF) was synthesized through a two-step procedure, and the chemical structure was confirmed by .sub.1H nuclear magnetic resonance (NMR), .sub.13C NMR, and Fourier transform infrared (FTIR) spectra. Moreover, DGEBHF was thermally cured with methyl hexahydrophthalic anhydride (MHHPA). The results clearly indicated that the cured DGEBHF/MHHPA exhibited higher glass transition temperature (T.sub.g 147[degrees]C) and thermal decomposition temperature at 5% weight loss (T.sub.5 372[degrees]C) than those (T.sub.g 131.2[degrees]C; T.sub.5 362[degrees]C) of diglycidyl ether of bisphenol A (DGEBA)/MHHPA. In addition, the incorporation of bis-trifluoromethyl groups led to enhanced dielectric properties with lower dielectric constant (D.sub.k 2.93) of DGEBHF/MHHPA compared with cured DGEBA resins (D.sub.k 3.25). The cured fluorinated epoxy resin also gave lower water absorption measured in two methods relative to its nonfluorinated counterparts. [c] 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 2801-2808, 2013
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