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Metal-catalyzed [6 + 3] cycloaddition of tropone with azomethine ylides: a practical access to piperidine-fused bicyclic heterocycles.(Report)

The article describes the metal-catalyzed [6 + 3] cycloaddition of tropone with azomethine ylides. A chiral ferrocenylphosphine-copper(I) complex was used as the catalyst in this reaction which afforded piperidine-fused bicyclic heterocycles in moderate to high yields with good to excellent diastere... Full description

Journal Title: Journal of the American Chemical Society Feb 12, 2014, Vol.136(6), p.2625-2629
Main Author: Honglei Liu
Other Authors: Chengfeng Jing , Hui Jiang , Wenjun Yang , Lei Zhang , Zhen Li , Yan Zhao , Yang Wu , Hao Yu , Bo Wang , Yumei Xiao , Hongchao Guo
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 0002-7863
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recordid: gale_ofg362791142
title: Metal-catalyzed [6 + 3] cycloaddition of tropone with azomethine ylides: a practical access to piperidine-fused bicyclic heterocycles.(Report)
format: Article
creator:
  • Honglei Liu
  • Chengfeng Jing
  • Hui Jiang
  • Wenjun Yang
  • Lei Zhang
  • Zhen Li
  • Yan Zhao
  • Yang Wu
  • Hao Yu
  • Bo Wang
  • Yumei Xiao
  • Hongchao Guo
subjects:
  • Catalysts -- Usage
  • Cyclization (Chemistry) -- Analysis
  • Schiff Bases -- Research
ispartof: Journal of the American Chemical Society, Feb 12, 2014, Vol.136(6), p.2625-2629
description: The article describes the metal-catalyzed [6 + 3] cycloaddition of tropone with azomethine ylides. A chiral ferrocenylphosphine-copper(I) complex was used as the catalyst in this reaction which afforded piperidine-fused bicyclic heterocycles in moderate to high yields with good to excellent diastereo- and enantioselectivies.
language: English
source:
identifier: ISSN: 0002-7863
fulltext: fulltext
issn:
  • 0002-7863
  • 00027863
url: Link


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titleMetal-catalyzed [6 + 3] cycloaddition of tropone with azomethine ylides: a practical access to piperidine-fused bicyclic heterocycles.(Report)
creatorHonglei Liu ; Chengfeng Jing ; Hui Jiang ; Wenjun Yang ; Lei Zhang ; Zhen Li ; Yan Zhao ; Yang Wu ; Hao Yu ; Bo Wang ; Yumei Xiao ; Hongchao Guo
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subjectCatalysts -- Usage ; Cyclization (Chemistry) -- Analysis ; Schiff Bases -- Research
descriptionThe article describes the metal-catalyzed [6 + 3] cycloaddition of tropone with azomethine ylides. A chiral ferrocenylphosphine-copper(I) complex was used as the catalyst in this reaction which afforded piperidine-fused bicyclic heterocycles in moderate to high yields with good to excellent diastereo- and enantioselectivies.
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titleMetal-catalyzed [6 + 3] cycloaddition of tropone with azomethine ylides: a practical access to piperidine-fused bicyclic heterocycles.(Report)
descriptionThe article describes the metal-catalyzed [6 + 3] cycloaddition of tropone with azomethine ylides. A chiral ferrocenylphosphine-copper(I) complex was used as the catalyst in this reaction which afforded piperidine-fused bicyclic heterocycles in moderate to high yields with good to excellent diastereo- and enantioselectivies.
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titleMetal-catalyzed [6 + 3] cycloaddition of tropone with azomethine ylides: a practical access to piperidine-fused bicyclic heterocycles.(Report)
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atitleMetal-catalyzed [6 + 3] cycloaddition of tropone with azomethine ylides: a practical access to piperidine-fused bicyclic heterocycles.(Report)
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abstractThe article describes the metal-catalyzed [6 + 3] cycloaddition of tropone with azomethine ylides. A chiral ferrocenylphosphine-copper(I) complex was used as the catalyst in this reaction which afforded piperidine-fused bicyclic heterocycles in moderate to high yields with good to excellent diastereo- and enantioselectivies.
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date2014-02-12