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Self-assembly and self-metallization of porphyrin nanosheets

Square porphyrin nanosheets with uniform thickness (7−12 nm) and aspect ratios up to 100 have been synthesized for the first time using a reprecipitation method. They retain the photocatalytic activity of the precursor molecules and can be self-metallized with Pt, Pd, and Au. Their unique morphology... Full description

Journal Title: Journal of the American Chemical Society 07 March 2007, Vol.129(9), pp.2440-1
Main Author: Wang, Zhongchun
Other Authors: Li, Zhiyong , Medforth, Craig J , Shelnutt, John A
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 0002-7863 ; PMID: 17290997 Version:1
Link: http://pubmed.gov/17290997
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recordid: medline17290997
title: Self-assembly and self-metallization of porphyrin nanosheets
format: Article
creator:
  • Wang, Zhongchun
  • Li, Zhiyong
  • Medforth, Craig J
  • Shelnutt, John A
subjects:
  • Chemistry
ispartof: Journal of the American Chemical Society, 07 March 2007, Vol.129(9), pp.2440-1
description: Square porphyrin nanosheets with uniform thickness (7−12 nm) and aspect ratios up to 100 have been synthesized for the first time using a reprecipitation method. They retain the photocatalytic activity of the precursor molecules and can be self-metallized with Pt, Pd, and Au. Their unique morphology, photocatalytic properties, and large surface areas suggest potential applications in photo- and electrocatalysis, sensing, as components for optoelectronic nanodevices, and solar energy capture and conversion.
language: eng
source:
identifier: ISSN: 0002-7863 ; PMID: 17290997 Version:1
fulltext: no_fulltext
issn:
  • 00027863
  • 0002-7863
url: Link


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descriptionSquare porphyrin nanosheets with uniform thickness (7−12 nm) and aspect ratios up to 100 have been synthesized for the first time using a reprecipitation method. They retain the photocatalytic activity of the precursor molecules and can be self-metallized with Pt, Pd, and Au. Their unique morphology, photocatalytic properties, and large surface areas suggest potential applications in photo- and electrocatalysis, sensing, as components for optoelectronic nanodevices, and solar energy capture and conversion.
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