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A double-stranded dinuclear cadmium(II) helicate that assembles into chains in the solid state

A [4+4] double-stranded cadmium dihelicate was afforded from an easily accessible thiosemicarbazone ligand; its crystal structure reveals the assembly of two enantiomers into dihelicate pairs, these pairs being further connected into infinite linear chains.

Journal Title: Dalton transactions (Cambridge England : 2003), 07 February 2010, Vol.39(5), pp.1191-4
Main Author: Martínez-Calvo, Miguel
Other Authors: González-Noya, Ana M , Pedrido, Rosa , Romero, María J , Fernández, M Isabel , Zaragoza, Guillermo , Bermejo, Manuel R
Format: Electronic Article Electronic Article
Language: English
ID: E-ISSN: 1477-9234 ; PMID: 20104342 Version:1 ; DOI: 10.1039/b915953c
Link: http://pubmed.gov/20104342
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recordid: medline20104342
title: A double-stranded dinuclear cadmium(II) helicate that assembles into chains in the solid state
format: Article
creator:
  • Martínez-Calvo, Miguel
  • González-Noya, Ana M
  • Pedrido, Rosa
  • Romero, María J
  • Fernández, M Isabel
  • Zaragoza, Guillermo
  • Bermejo, Manuel R
ispartof: Dalton transactions (Cambridge, England : 2003), 07 February 2010, Vol.39(5), pp.1191-4
description: A [4+4] double-stranded cadmium dihelicate was afforded from an easily accessible thiosemicarbazone ligand; its crystal structure reveals the assembly of two enantiomers into dihelicate pairs, these pairs being further connected into infinite linear chains.
language: eng
source:
identifier: E-ISSN: 1477-9234 ; PMID: 20104342 Version:1 ; DOI: 10.1039/b915953c
fulltext: fulltext
issn:
  • 14779234
  • 1477-9234
url: Link


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abstractA [4+4] double-stranded cadmium dihelicate was afforded from an easily accessible thiosemicarbazone ligand; its crystal structure reveals the assembly of two enantiomers into dihelicate pairs, these pairs being further connected into infinite linear chains.
doi10.1039/b915953c
pmid20104342
date2010-02-07