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Catalytic enantioselective alkylative dearomatization-annulation: total synthesis and absolute configuration assignment of hyperibone K

The asymmetric total synthesis of the polyprenylated acylphloroglucinol hyperibone K has been achieved using an enantioselective alkylative dearomatization-annulation process. NMR and computational studies were employed to probe the mode of action of a chiral phase-transfer (ion pair) catalyst.

Journal Title: Journal of the American Chemical Society 06 October 2010, Vol.132(39), pp.13642-4
Main Author: Qi, Ji
Other Authors: Beeler, Aaron B , Zhang, Qiang , Porco, John A
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1520-5126 ; PMID: 20831187 Version:1 ; DOI: 10.1021/ja1057828
Link: http://pubmed.gov/20831187
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recordid: medline20831187
title: Catalytic enantioselective alkylative dearomatization-annulation: total synthesis and absolute configuration assignment of hyperibone K
format: Article
creator:
  • Qi, Ji
  • Beeler, Aaron B
  • Zhang, Qiang
  • Porco, John A
subjects:
  • Adamantane -- Analogs & Derivatives
  • Hemiterpenes -- Chemical Synthesis
  • Phloroglucinol -- Analogs & Derivatives
ispartof: Journal of the American Chemical Society, 06 October 2010, Vol.132(39), pp.13642-4
description: The asymmetric total synthesis of the polyprenylated acylphloroglucinol hyperibone K has been achieved using an enantioselective alkylative dearomatization-annulation process. NMR and computational studies were employed to probe the mode of action of a chiral phase-transfer (ion pair) catalyst.
language: eng
source:
identifier: E-ISSN: 1520-5126 ; PMID: 20831187 Version:1 ; DOI: 10.1021/ja1057828
fulltext: no_fulltext
issn:
  • 15205126
  • 1520-5126
url: Link


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subjectAdamantane -- Analogs & Derivatives ; Hemiterpenes -- Chemical Synthesis ; Phloroglucinol -- Analogs & Derivatives
descriptionThe asymmetric total synthesis of the polyprenylated acylphloroglucinol hyperibone K has been achieved using an enantioselective alkylative dearomatization-annulation process. NMR and computational studies were employed to probe the mode of action of a chiral phase-transfer (ion pair) catalyst.
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titleCatalytic enantioselective alkylative dearomatization-annulation: total synthesis and absolute configuration assignment of hyperibone K
descriptionThe asymmetric total synthesis of the polyprenylated acylphloroglucinol hyperibone K has been achieved using an enantioselective alkylative dearomatization-annulation process. NMR and computational studies were employed to probe the mode of action of a chiral phase-transfer (ion pair) catalyst.
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abstractThe asymmetric total synthesis of the polyprenylated acylphloroglucinol hyperibone K has been achieved using an enantioselective alkylative dearomatization-annulation process. NMR and computational studies were employed to probe the mode of action of a chiral phase-transfer (ion pair) catalyst.
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date2010-10-06