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Organic chemistry: Directors extend their reach

The root of the regioselectivity problem is taught to chemistry students in their first organic chemistry course at university, in studies of classical electrophilic aromatic-substitution reactions - the most widely used reactions for attaching groups to benzene rings. In a benzene ring, the carbon... Full description

Journal Title: Nature 27 June 2012, Vol.486(7404), pp.478-9
Main Author: Kitching, Matthew O
Other Authors: Snieckus, Victor
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1476-4687 ; PMID: 22739310 Version:1 ; DOI: 10.1038/486478a
Link: http://pubmed.gov/22739310
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recordid: medline22739310
title: Organic chemistry: Directors extend their reach
format: Article
creator:
  • Kitching, Matthew O
  • Snieckus, Victor
subjects:
  • Carbon -- Chemistry
  • Chemistry Techniques, Synthetic -- Methods
  • Hydrogen -- Chemistry
ispartof: Nature, 27 June 2012, Vol.486(7404), pp.478-9
description: The root of the regioselectivity problem is taught to chemistry students in their first organic chemistry course at university, in studies of classical electrophilic aromatic-substitution reactions - the most widely used reactions for attaching groups to benzene rings. In a benzene ring, the carbon atoms on either side of the point of attachment of a chemical group are said to be in the ortho-positions; the next two around the ring are in the meta-positions; and the carbon atom on the other side of the ring from the attached group is in the para-position (Fig. 1a).
language: eng
source:
identifier: E-ISSN: 1476-4687 ; PMID: 22739310 Version:1 ; DOI: 10.1038/486478a
fulltext: fulltext
issn:
  • 14764687
  • 1476-4687
url: Link


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descriptionThe root of the regioselectivity problem is taught to chemistry students in their first organic chemistry course at university, in studies of classical electrophilic aromatic-substitution reactions - the most widely used reactions for attaching groups to benzene rings. In a benzene ring, the carbon atoms on either side of the point of attachment of a chemical group are said to be in the ortho-positions; the next two around the ring are in the meta-positions; and the carbon atom on the other side of the ring from the attached group is in the para-position (Fig. 1a).
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