schliessen

Filtern

 

Bibliotheken

Octamolybdate-based metal-organic framework with unsaturated coordinated metal center as electrocatalyst for generating hydrogen from water

Two octamolybdate-based MOFs with unsaturated coordinated metal centers formulated as Cu(3)(Mo(8)O(26))(H(2)O)(2)(OH)(2)(L1)(4) (L1 = 4H-4-amino-1,2,4-triazole) (1) and Ag(4)(Mo(8)O(26))(L2)(2.5)(H(2)O) (L2 = 3,5-dimethyl-4-amino-4H-1,2,4-triazole) (2) were synthesized and structurally characterized... Full description

Journal Title: Inorganic chemistry 18 January 2013, Vol.52(2), pp.777-84
Main Author: Gong, Yun
Other Authors: Wu, Tao , Jiang, Peng Gang , Lin, Jian Hua , Yang, Yong Xi
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1520-510X ; PMID: 23276292 Version:1 ; DOI: 10.1021/ic3018858
Link: http://pubmed.gov/23276292
Zum Text:
SendSend as email Add to Book BagAdd to Book Bag
Staff View
recordid: medline23276292
title: Octamolybdate-based metal-organic framework with unsaturated coordinated metal center as electrocatalyst for generating hydrogen from water
format: Article
creator:
  • Gong, Yun
  • Wu, Tao
  • Jiang, Peng Gang
  • Lin, Jian Hua
  • Yang, Yong Xi
subjects:
  • Hydrogen -- Chemical Properties
  • Water Chemistry -- Analysis
ispartof: Inorganic chemistry, 18 January 2013, Vol.52(2), pp.777-84
description: Two octamolybdate-based MOFs with unsaturated coordinated metal centers formulated as Cu(3)(Mo(8)O(26))(H(2)O)(2)(OH)(2)(L1)(4) (L1 = 4H-4-amino-1,2,4-triazole) (1) and Ag(4)(Mo(8)O(26))(L2)(2.5)(H(2)O) (L2 = 3,5-dimethyl-4-amino-4H-1,2,4-triazole) (2) were synthesized and structurally characterized by single-crystal X-ray diffractions. Complex 1 exhibits a 1D chain-like structure. In complex 2, 1D Ag-octamolybdate chains in the ac plane are covalently embedded into the 2D Ag-L2 layer, and the Ag-octamolybdate chains in the bc plane covalently link the 2D layers into 3D architecture. The two complexes both exhibit electrocatalytic activities toward generating H(2) from water with lowered overpotentials and enhanced currents, and the Cu complex exhibits better electrocatalytic activity toward generating H(2) from water than the Ag complex.
language: eng
source:
identifier: E-ISSN: 1520-510X ; PMID: 23276292 Version:1 ; DOI: 10.1021/ic3018858
fulltext: fulltext
issn:
  • 1520510X
  • 1520-510X
url: Link


@attributes
ID172616117
RANK0.07
NO1
SEARCH_ENGINEprimo_central_multiple_fe
SEARCH_ENGINE_TYPEPrimo Central Search Engine
LOCALfalse
PrimoNMBib
record
control
sourcerecordid23276292
sourceidmedline
recordidTN_medline23276292
sourceformatXML
sourcesystemPC
pqid1273664582
galeid360335128
display
typearticle
titleOctamolybdate-based metal-organic framework with unsaturated coordinated metal center as electrocatalyst for generating hydrogen from water
creatorGong, Yun ; Wu, Tao ; Jiang, Peng Gang ; Lin, Jian Hua ; Yang, Yong Xi
ispartofInorganic chemistry, 18 January 2013, Vol.52(2), pp.777-84
identifier
descriptionTwo octamolybdate-based MOFs with unsaturated coordinated metal centers formulated as Cu(3)(Mo(8)O(26))(H(2)O)(2)(OH)(2)(L1)(4) (L1 = 4H-4-amino-1,2,4-triazole) (1) and Ag(4)(Mo(8)O(26))(L2)(2.5)(H(2)O) (L2 = 3,5-dimethyl-4-amino-4H-1,2,4-triazole) (2) were synthesized and structurally characterized by single-crystal X-ray diffractions. Complex 1 exhibits a 1D chain-like structure. In complex 2, 1D Ag-octamolybdate chains in the ac plane are covalently embedded into the 2D Ag-L2 layer, and the Ag-octamolybdate chains in the bc plane covalently link the 2D layers into 3D architecture. The two complexes both exhibit electrocatalytic activities toward generating H(2) from water with lowered overpotentials and enhanced currents, and the Cu complex exhibits better electrocatalytic activity toward generating H(2) from water than the Ag complex.
languageeng
source
subjectHydrogen -- Chemical Properties ; Water Chemistry -- Analysis;
version4
lds50peer_reviewed
links
openurl$$Topenurl_article
backlink$$Uhttp://pubmed.gov/23276292$$EView_this_record_in_MEDLINE/PubMed
openurlfulltext$$Topenurlfull_article
addlink$$Uhttp://exlibris-pub.s3.amazonaws.com/aboutMedline.html$$EView_the_MEDLINE/PubMed_Copyright_Statement
search
creatorcontrib
0Gong, Yun
1Wu, Tao
2Jiang, Peng Gang
3Lin, Jian Hua
4Yang, Yong Xi
titleOctamolybdate-based metal-organic framework with unsaturated coordinated metal center as electrocatalyst for generating hydrogen from water
descriptionTwo octamolybdate-based MOFs with unsaturated coordinated metal centers formulated as Cu(3)(Mo(8)O(26))(H(2)O)(2)(OH)(2)(L1)(4) (L1 = 4H-4-amino-1,2,4-triazole) (1) and Ag(4)(Mo(8)O(26))(L2)(2.5)(H(2)O) (L2 = 3,5-dimethyl-4-amino-4H-1,2,4-triazole) (2) were synthesized and structurally characterized by single-crystal X-ray diffractions. Complex 1 exhibits a 1D chain-like structure. In complex 2, 1D Ag-octamolybdate chains in the ac plane are covalently embedded into the 2D Ag-L2 layer, and the Ag-octamolybdate chains in the bc plane covalently link the 2D layers into 3D architecture. The two complexes both exhibit electrocatalytic activities toward generating H(2) from water with lowered overpotentials and enhanced currents, and the Cu complex exhibits better electrocatalytic activity toward generating H(2) from water than the Ag complex.
general
023276292
1English
2MEDLINE/PubMed (U.S. National Library of Medicine)
310.1021/ic3018858
4MEDLINE/PubMed (NLM)
sourceidmedline
recordidmedline23276292
issn
01520510X
11520-510X
rsrctypearticle
creationdate2013
addtitleInorganic chemistry
searchscope
0medline
1nlm_medline
2MEDLINE
scope
0medline
1nlm_medline
2MEDLINE
lsr4120130118
citationpf 777 vol 52 issue 2
startdate20130118
enddate20130118
lsr30VSR-Enriched:[subject, pqid, galeid, issn, pages]
sort
titleOctamolybdate-based metal-organic framework with unsaturated coordinated metal center as electrocatalyst for generating hydrogen from water
authorGong, Yun ; Wu, Tao ; Jiang, Peng Gang ; Lin, Jian Hua ; Yang, Yong Xi
creationdate20130118
lso0120130118
facets
frbrgroupid6221244126854213321
frbrtype5
newrecords20190701
languageeng
creationdate2013
collectionMEDLINE/PubMed (NLM)
prefilterarticles
rsrctypearticles
creatorcontrib
0Gong, Yun
1Wu, Tao
2Jiang, Peng Gang
3Lin, Jian Hua
4Yang, Yong Xi
jtitleInorganic Chemistry
toplevelpeer_reviewed
delivery
delcategoryRemote Search Resource
fulltextfulltext
addata
aulast
0Gong
1Wu
2Jiang
3Lin
4Yang
aufirst
0Yun
1Tao
2Peng Gang
3Jian Hua
4Yong Xi
au
0Gong, Yun
1Wu, Tao
2Jiang, Peng Gang
3Lin, Jian Hua
4Yang, Yong Xi
atitleOctamolybdate-based metal-organic framework with unsaturated coordinated metal center as electrocatalyst for generating hydrogen from water
jtitleInorganic chemistry
risdate20130118
volume52
issue2
spage777
pages777-784
eissn1520-510X
formatjournal
genrearticle
ristypeJOUR
abstractTwo octamolybdate-based MOFs with unsaturated coordinated metal centers formulated as Cu(3)(Mo(8)O(26))(H(2)O)(2)(OH)(2)(L1)(4) (L1 = 4H-4-amino-1,2,4-triazole) (1) and Ag(4)(Mo(8)O(26))(L2)(2.5)(H(2)O) (L2 = 3,5-dimethyl-4-amino-4H-1,2,4-triazole) (2) were synthesized and structurally characterized by single-crystal X-ray diffractions. Complex 1 exhibits a 1D chain-like structure. In complex 2, 1D Ag-octamolybdate chains in the ac plane are covalently embedded into the 2D Ag-L2 layer, and the Ag-octamolybdate chains in the bc plane covalently link the 2D layers into 3D architecture. The two complexes both exhibit electrocatalytic activities toward generating H(2) from water with lowered overpotentials and enhanced currents, and the Cu complex exhibits better electrocatalytic activity toward generating H(2) from water than the Ag complex.
doi10.1021/ic3018858
pmid23276292
issn00201669
date2013-01-18