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Application of chiral N-tert-butylsulfinyl vinyl aziridines in Rh(I) catalyzed 1,4-addition of aryl boronic acids to cyclic enones

Chiral N-tert-butylsulfinyl vinyl aziridine ligands prepared from a readily available (R)-tert-butanesulfinamide have been applied in the rhodium-catalyzed asymmetric 1,4-addition of aryl boronic acids to cyclic enones, which gives high yields and excellent enantioselectivities.

Journal Title: Chemical communications (Cambridge England), 21 July 2013, Vol.49(57), pp.6433-5
Main Author: Chen, Qian
Other Authors: Chen, Chao , Guo, Fang , Xia, Wujiong
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1364-548X ; PMID: 23756467 Version:1 ; DOI: 10.1039/c3cc42673d
Link: http://pubmed.gov/23756467
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recordid: medline23756467
title: Application of chiral N-tert-butylsulfinyl vinyl aziridines in Rh(I) catalyzed 1,4-addition of aryl boronic acids to cyclic enones
format: Article
creator:
  • Chen, Qian
  • Chen, Chao
  • Guo, Fang
  • Xia, Wujiong
subjects:
  • Aziridines -- Chemistry
  • Rhodium -- Chemistry
ispartof: Chemical communications (Cambridge, England), 21 July 2013, Vol.49(57), pp.6433-5
description: Chiral N-tert-butylsulfinyl vinyl aziridine ligands prepared from a readily available (R)-tert-butanesulfinamide have been applied in the rhodium-catalyzed asymmetric 1,4-addition of aryl boronic acids to cyclic enones, which gives high yields and excellent enantioselectivities.
language: eng
source:
identifier: E-ISSN: 1364-548X ; PMID: 23756467 Version:1 ; DOI: 10.1039/c3cc42673d
fulltext: fulltext
issn:
  • 1364548X
  • 1364-548X
url: Link


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descriptionChiral N-tert-butylsulfinyl vinyl aziridine ligands prepared from a readily available (R)-tert-butanesulfinamide have been applied in the rhodium-catalyzed asymmetric 1,4-addition of aryl boronic acids to cyclic enones, which gives high yields and excellent enantioselectivities.
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abstractChiral N-tert-butylsulfinyl vinyl aziridine ligands prepared from a readily available (R)-tert-butanesulfinamide have been applied in the rhodium-catalyzed asymmetric 1,4-addition of aryl boronic acids to cyclic enones, which gives high yields and excellent enantioselectivities.
doi10.1039/c3cc42673d
pmid23756467
date2013-07-21