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Reductive cleavage of the Csp2-Csp3 bond of secondary benzyl alcohols: rhodium catalysis directed by N-containing groups.

Cutting loose: 1,1-Biarylmethanol substrates undergo reductive cleavage of the C--C bond in the presence of a cationic Rh super(III) catalyst and H sub(2) (see scheme; DG=directing group). Various functional groups are tolerated in the reaction system. Preliminary studies indicate that a five-member... Full description

Journal Title: Angewandte Chemie (International ed. in English) September 24, 2012, Vol.51(39), pp.9851-9855
Main Author: Chen, Kang
Other Authors: Li, Hu , Lei, Zhi-Quan , Li, Yang , Ye, Wen-He , Zhang, Li-Sheng , Sun, Jian , Shi, Zhang-Jie
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1521-3773 ; DOI: 1521-3773 ; DOI: 10.1002/anie.201204338
Link: http://search.proquest.com/docview/1041324890/?pq-origsite=primo
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title: Reductive cleavage of the Csp2-Csp3 bond of secondary benzyl alcohols: rhodium catalysis directed by N-containing groups.
format: Article
creator:
  • Chen, Kang
  • Li, Hu
  • Lei, Zhi-Quan
  • Li, Yang
  • Ye, Wen-He
  • Zhang, Li-Sheng
  • Sun, Jian
  • Shi, Zhang-Jie
subjects:
  • Benzyl Alcohols–Chemistry
  • Catalysis–Analogs & Derivatives
  • Hydrogenation–Chemistry
  • Methanol–Chemistry
  • Oxidation-Reduction–Chemistry
  • Rhodium–Chemistry
  • Benzyl Alcohols
  • Rhodium
  • Methanol
ispartof: Angewandte Chemie (International ed. in English), September 24, 2012, Vol.51(39), pp.9851-9855
description: Cutting loose: 1,1-Biarylmethanol substrates undergo reductive cleavage of the C--C bond in the presence of a cationic Rh super(III) catalyst and H sub(2) (see scheme; DG=directing group). Various functional groups are tolerated in the reaction system. Preliminary studies indicate that a five-membered rhodacycle intermediate, which then converts into a Rh super(III) hydride species for the reduction, is involved in the catalytic cycle.
language: eng
source:
identifier: E-ISSN: 1521-3773 ; DOI: 1521-3773 ; DOI: 10.1002/anie.201204338
fulltext: fulltext
issn:
  • 15213773
  • 1521-3773
url: Link


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titleReductive cleavage of the Csp2-Csp3 bond of secondary benzyl alcohols: rhodium catalysis directed by N-containing groups.
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descriptionCutting loose: 1,1-Biarylmethanol substrates undergo reductive cleavage of the C--C bond in the presence of a cationic Rh super(III) catalyst and H sub(2) (see scheme; DG=directing group). Various functional groups are tolerated in the reaction system. Preliminary studies indicate that a five-membered rhodacycle intermediate, which then converts into a Rh super(III) hydride species for the reduction, is involved in the catalytic cycle.
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titleReductive cleavage of the Csp2-Csp3 bond of secondary benzyl alcohols: rhodium catalysis directed by N-containing groups.
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