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Oxidation of chloride and subsequent chlorination of organic compounds by oxoiron(IV) porphyrin π-cation radicals.

Ironing it out: Oxoiron(IV) porphyrin π‐cation radical complexes (see figure) serve as models for the oxidation of Cl− into an active chlorinating reagent that chlorinates various organic compounds. Evidence suggests that Cl− is oxidized to Cl2 via Cl.. The mechanism involving either direct electron... Full description

Journal Title: Angewandte Chemie (International ed. in English) October 10, 2011, Vol.50(42), pp.9935-9939
Main Author: Cong, Zhiqi
Other Authors: Kurahashi, Takuya , Fujii, Hiroshi
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1521-3773 ; DOI: 10.1002/anie.201104461
Link: http://search.proquest.com/docview/1093498088/?pq-origsite=primo
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title: Oxidation of chloride and subsequent chlorination of organic compounds by oxoiron(IV) porphyrin π-cation radicals.
format: Article
creator:
  • Cong, Zhiqi
  • Kurahashi, Takuya
  • Fujii, Hiroshi
subjects:
  • Cations–Chemistry
  • Chlorides–Chemistry
  • Free Radicals–Chemistry
  • Hydrocarbons, Chlorinated–Chemical Synthesis
  • Iron–Chemistry
  • Metalloporphyrins–Chemistry
  • Molecular Structure–Chemical Synthesis
  • Oxidation-Reduction–Chemistry
  • Cations
  • Chlorides
  • Free Radicals
  • Hydrocarbons, Chlorinated
  • Metalloporphyrins
  • Iron
ispartof: Angewandte Chemie (International ed. in English), October 10, 2011, Vol.50(42), pp.9935-9939
description: Ironing it out: Oxoiron(IV) porphyrin π‐cation radical complexes (see figure) serve as models for the oxidation of Cl− into an active chlorinating reagent that chlorinates various organic compounds. Evidence suggests that Cl− is oxidized to Cl2 via Cl.. The mechanism involving either direct electron transfer or iron(III) hypochlorite formation, and then homolysis of the ClO bond is discussed.
language: eng
source:
identifier: E-ISSN: 1521-3773 ; DOI: 10.1002/anie.201104461
fulltext: fulltext
issn:
  • 15213773
  • 1521-3773
url: Link


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titleOxidation of chloride and subsequent chlorination of organic compounds by oxoiron(IV) porphyrin π-cation radicals.
creatorCong, Zhiqi ; Kurahashi, Takuya ; Fujii, Hiroshi
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identifierE-ISSN: 1521-3773 ; DOI: 10.1002/anie.201104461
subjectCations–Chemistry ; Chlorides–Chemistry ; Free Radicals–Chemistry ; Hydrocarbons, Chlorinated–Chemical Synthesis ; Iron–Chemistry ; Metalloporphyrins–Chemistry ; Molecular Structure–Chemical Synthesis ; Oxidation-Reduction–Chemistry ; Cations ; Chlorides ; Free Radicals ; Hydrocarbons, Chlorinated ; Metalloporphyrins ; Iron
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descriptionIroning it out: Oxoiron(IV) porphyrin π‐cation radical complexes (see figure) serve as models for the oxidation of Cl− into an active chlorinating reagent that chlorinates various organic compounds. Evidence suggests that Cl− is oxidized to Cl2 via Cl.. The mechanism involving either direct electron transfer or iron(III) hypochlorite formation, and then homolysis of the ClO bond is discussed.
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