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Efficient synthesis of oxygenated terphenyls and other oligomers: sequential arylation reactions through phenol oxidation-rearomatization.

: Starting from simple phenols, a diverse series of oxygenated terphenyl compounds can be prepared in a concise and practical manner using sequential arylation reactions involving phenol oxidation/rearomatization and quinone monoacetal intermediates (see scheme). Many of the terphenyl products can b... Full description

Journal Title: Chemistry (Weinheim an der Bergstrasse Germany), October 22, 2012, Vol.18(43), pp.13614-13618
Main Author: Dohi, Toshifumi
Other Authors: Kamitanaka, Tohru , Watanabe, Shohei , Hu, Yinjun , Washimi, Naohiko , Kita, Yasuyuki
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1521-3765 ; DOI: 1521-3765 ; DOI: 10.1002/chem.201202086
Link: http://search.proquest.com/docview/1112677009/?pq-origsite=primo
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title: Efficient synthesis of oxygenated terphenyls and other oligomers: sequential arylation reactions through phenol oxidation-rearomatization.
format: Article
creator:
  • Dohi, Toshifumi
  • Kamitanaka, Tohru
  • Watanabe, Shohei
  • Hu, Yinjun
  • Washimi, Naohiko
  • Kita, Yasuyuki
subjects:
  • Benzoquinones–Chemistry
  • Oxidation-Reduction–Chemistry
  • Oxygen–Chemistry
  • Phenols–Chemistry
  • Terphenyl Compounds–Chemistry
  • Benzoquinones
  • Phenols
  • Terphenyl Compounds
  • Quinone
  • Oxygen
ispartof: Chemistry (Weinheim an der Bergstrasse, Germany), October 22, 2012, Vol.18(43), pp.13614-13618
description: : Starting from simple phenols, a diverse series of oxygenated terphenyl compounds can be prepared in a concise and practical manner using sequential arylation reactions involving phenol oxidation/rearomatization and quinone monoacetal intermediates (see scheme). Many of the terphenyl products can be used for preparing well‐defined oligomers and, furthermore, contain valuable functional groups that can be transformed for further diversification.
language: eng
source:
identifier: E-ISSN: 1521-3765 ; DOI: 1521-3765 ; DOI: 10.1002/chem.201202086
fulltext: fulltext
issn:
  • 15213765
  • 1521-3765
url: Link


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titleEfficient synthesis of oxygenated terphenyls and other oligomers: sequential arylation reactions through phenol oxidation-rearomatization.
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description: Starting from simple phenols, a diverse series of oxygenated terphenyl compounds can be prepared in a concise and practical manner using sequential arylation reactions involving phenol oxidation/rearomatization and quinone monoacetal intermediates (see scheme). Many of the terphenyl products can be used for preparing well‐defined oligomers and, furthermore, contain valuable functional groups that can be transformed for further diversification.
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