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Inverse-micelle-encapsulated water-enabled bond breaking of dialkyl diselenide/disulfide: a critical step for synthesizing high-quality gold nanoparticles.

Inverse-micelle-encapsulated water formed in the two-phase Brust-Schiffrin method (BSM) is applied to fabricate high-quality gold nanoparticles (NPs). The reaction of dialkyl diselenide/disulfide with the Au(III) complex is found to be essential for Se-Se/S-S bond breaking leading to formation of hi... Full description

Journal Title: Journal of the American Chemical Society October 31, 2012, Vol.134(43), pp.17991-17996
Main Author: Zaluzhna, Oksana
Other Authors: Li, Ying , Allison, Thomas C , Tong, Yuye J
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1520-5126 ; DOI: 1520-5126 ; DOI: 10.1021/ja3068758
Link: http://search.proquest.com/docview/1125249829/?pq-origsite=primo
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title: Inverse-micelle-encapsulated water-enabled bond breaking of dialkyl diselenide/disulfide: a critical step for synthesizing high-quality gold nanoparticles.
format: Article
creator:
  • Zaluzhna, Oksana
  • Li, Ying
  • Allison, Thomas C
  • Tong, Yuye J
subjects:
  • Disulfides–Chemistry
  • Gold–Chemistry
  • Metal Nanoparticles–Chemistry
  • Micelles–Chemistry
  • Organoselenium Compounds–Chemistry
  • Particle Size–Chemistry
  • Surface Properties–Chemistry
  • Water–Chemistry
  • Disulfides
  • Micelles
  • Organoselenium Compounds
  • Water
  • Gold
ispartof: Journal of the American Chemical Society, October 31, 2012, Vol.134(43), pp.17991-17996
description: Inverse-micelle-encapsulated water formed in the two-phase Brust-Schiffrin method (BSM) is applied to fabricate high-quality gold nanoparticles (NPs). The reaction of dialkyl diselenide/disulfide with the Au(III) complex is found to be essential for Se-Se/S-S bond breaking leading to formation of higher-quality Au NPs.
language: eng
source:
identifier: E-ISSN: 1520-5126 ; DOI: 1520-5126 ; DOI: 10.1021/ja3068758
fulltext: no_fulltext
issn:
  • 15205126
  • 1520-5126
url: Link


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titleInverse-micelle-encapsulated water-enabled bond breaking of dialkyl diselenide/disulfide: a critical step for synthesizing high-quality gold nanoparticles.
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descriptionInverse-micelle-encapsulated water formed in the two-phase Brust-Schiffrin method (BSM) is applied to fabricate high-quality gold nanoparticles (NPs). The reaction of dialkyl diselenide/disulfide with the Au(III) complex is found to be essential for Se-Se/S-S bond breaking leading to formation of higher-quality Au NPs.
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