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Tuning the oxidation states of copper ions (+I/+II) to construct different Keggin-based topology structures

Through tuning the oxidation states of CuI/II, two Keggin-based compounds with different topologies, [ [Formula omitted.] (btx)4(P [Formula omitted.] O40)] (1) and [ [Formula omitted.] (btx)4(SiW12O40)] (2) (btx = 1,6-bis(1,2,4-triazol-1-y1)hexane), were synthesized and structurally characterized. I... Full description

Journal Title: Journal of Coordination Chemistry Jun 2012, Vol.65(12), pp.2147-2158
Main Author: Tian, Ai-Xiang
Other Authors: Lin, Xiao-Ling , Liu, Yu-Jing , Liu, Gui-Ying , Ying, Jun , Wang, Xiu-Li , Lin, Hong-Yan
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 00958972 ; E-ISSN: 10290389 ; DOI: 10.1080/00958972.2012.688962
Link: http://search.proquest.com/docview/1240567648/?pq-origsite=primo
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title: Tuning the oxidation states of copper ions (+I/+II) to construct different Keggin-based topology structures
format: Article
creator:
  • Tian, Ai-Xiang
  • Lin, Xiao-Ling
  • Liu, Yu-Jing
  • Liu, Gui-Ying
  • Ying, Jun
  • Wang, Xiu-Li
  • Lin, Hong-Yan
subjects:
  • Chemistry
  • Aquatic Plants
  • Oxidation
  • Topology
  • Polyoxometalate
  • Topology
  • Oxidation States
  • Hydrothermal Synthesis
  • Electrochemical Properties
ispartof: Journal of Coordination Chemistry, Jun 2012, Vol.65(12), pp.2147-2158
description: Through tuning the oxidation states of CuI/II, two Keggin-based compounds with different topologies, [ [Formula omitted.] (btx)4(P [Formula omitted.] O40)] (1) and [ [Formula omitted.] (btx)4(SiW12O40)] (2) (btx = 1,6-bis(1,2,4-triazol-1-y1)hexane), were synthesized and structurally characterized. In 1, there exist decanuclear CuI circuits, which are linked through N1-containing btx ligands to construct a grid-like 2-D layer. Three sets of these layers interpenetrate to build a three-fold interpenetrating framework. The Keggin polyanions connect the adjacent three-fold interpenetrating frameworks to construct a 3-D structure. In 2, the CuII-btx moiety shows a (66) 3-D hexagonal channel-style framework. The Keggin polyanion offering four terminal oxygen atoms incorporates with this metal-organic framework imbedding the channels. The different oxidation states of copper ions (+I/+II) induces distinct coordination modes of btx and Keggin polyanions and affects the whole structural topologies....
language: eng
source:
identifier: ISSN: 00958972 ; E-ISSN: 10290389 ; DOI: 10.1080/00958972.2012.688962
fulltext: fulltext
issn:
  • 00958972
  • 0095-8972
  • 10290389
  • 1029-0389
url: Link


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titleTuning the oxidation states of copper ions (+I/+II) to construct different Keggin-based topology structures
creatorTian, Ai-Xiang ; Lin, Xiao-Ling ; Liu, Yu-Jing ; Liu, Gui-Ying ; Ying, Jun ; Wang, Xiu-Li ; Lin, Hong-Yan
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subjectChemistry ; Aquatic Plants ; Oxidation ; Topology ; Polyoxometalate ; Topology ; Oxidation States ; Hydrothermal Synthesis ; Electrochemical Properties
descriptionThrough tuning the oxidation states of CuI/II, two Keggin-based compounds with different topologies, [ [Formula omitted.] (btx)4(P [Formula omitted.] O40)] (1) and [ [Formula omitted.] (btx)4(SiW12O40)] (2) (btx = 1,6-bis(1,2,4-triazol-1-y1)hexane), were synthesized and structurally characterized. In 1, there exist decanuclear CuI circuits, which are linked through N1-containing btx ligands to construct a grid-like 2-D layer. Three sets of these layers interpenetrate to build a three-fold interpenetrating framework. The Keggin polyanions connect the adjacent three-fold interpenetrating frameworks to construct a 3-D structure. In 2, the CuII-btx moiety shows a (66) 3-D hexagonal channel-style framework. The Keggin polyanion offering four terminal oxygen atoms incorporates with this metal-organic framework imbedding the channels. The different oxidation states of copper ions (+I/+II) induces distinct coordination modes of btx and Keggin polyanions and affects the whole structural topologies....
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titleTuning the oxidation states of copper ions (+I/+II) to construct different Keggin-based topology structures
descriptionThrough tuning the oxidation states of CuI/II, two Keggin-based compounds with different topologies, [ [Formula omitted.] (btx)4(P [Formula omitted.] O40)] (1) and [ [Formula omitted.] (btx)4(SiW12O40)] (2) (btx = 1,6-bis(1,2,4-triazol-1-y1)hexane), were synthesized and structurally characterized. In 1, there exist decanuclear CuI circuits, which are linked through N1-containing btx ligands to construct a grid-like 2-D layer. Three sets of these layers interpenetrate to build a three-fold interpenetrating framework. The Keggin polyanions connect the adjacent three-fold interpenetrating frameworks to construct a 3-D structure. In 2, the CuII-btx moiety shows a (66) 3-D hexagonal channel-style framework. The Keggin polyanion offering four terminal oxygen atoms incorporates with this metal-organic framework imbedding the channels. The different oxidation states of copper ions (+I/+II) induces distinct coordination modes of btx and Keggin polyanions and affects the whole structural topologies....
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abstractThrough tuning the oxidation states of CuI/II, two Keggin-based compounds with different topologies, [ [Formula omitted.] (btx)4(P [Formula omitted.] O40)] (1) and [ [Formula omitted.] (btx)4(SiW12O40)] (2) (btx = 1,6-bis(1,2,4-triazol-1-y1)hexane), were synthesized and structurally characterized. In 1, there exist decanuclear CuI circuits, which are linked through N1-containing btx ligands to construct a grid-like 2-D layer. Three sets of these layers interpenetrate to build a three-fold interpenetrating framework. The Keggin polyanions connect the adjacent three-fold interpenetrating frameworks to construct a 3-D structure. In 2, the CuII-btx moiety shows a (66) 3-D hexagonal channel-style framework. The Keggin polyanion offering four terminal oxygen atoms incorporates with this metal-organic framework imbedding the channels. The different oxidation states of copper ions (+I/+II) induces distinct coordination modes of btx and Keggin polyanions and affects the whole structural topologies....
copAbingdon
pubTaylor & Francis Ltd.
doi10.1080/00958972.2012.688962
urlhttp://search.proquest.com/docview/1240567648/
date2012-06-01