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Palladium-catalyzed oxidative regio- and diastereoselective diarylating carbocyclization of dienynes.

Transmetallation: A highly regio- and diastereoselective carbocyclization involving a palladium-catalyzed 1,2-addition of two carbon atoms across a conjugated diene has been developed (see scheme). The reaction is performed with dienynes and an oxygen tether containing a terminal or internal triple... Full description

Journal Title: Chemistry (Weinheim an der Bergstrasse Germany), May 17, 2013, Vol.19(21), pp.6571-6575
Main Author: Jiang, Min
Other Authors: Bäckvall, Jan-E
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1521-3765 ; DOI: 10.1002/chem.201204555
Link: http://search.proquest.com/docview/1350891997/?pq-origsite=primo
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recordid: proquest1350891997
title: Palladium-catalyzed oxidative regio- and diastereoselective diarylating carbocyclization of dienynes.
format: Article
creator:
  • Jiang, Min
  • Bäckvall, Jan-E
subjects:
  • Alkadienes–Chemistry
  • Alkynes–Chemistry
  • Boronic Acids–Chemistry
  • Carbon–Chemistry
  • Catalysis–Chemistry
  • Cyclization–Chemistry
  • Molecular Structure–Chemistry
  • Oxidation-Reduction–Chemistry
  • Oxygen–Chemistry
  • Palladium–Chemistry
  • Stereoisomerism–Chemistry
  • Alkadienes
  • Alkynes
  • Boronic Acids
  • Palladium
  • Carbon
  • Benzeneboronic Acid
  • Oxygen
ispartof: Chemistry (Weinheim an der Bergstrasse, Germany), May 17, 2013, Vol.19(21), pp.6571-6575
description: Transmetallation: A highly regio- and diastereoselective carbocyclization involving a palladium-catalyzed 1,2-addition of two carbon atoms across a conjugated diene has been developed (see scheme). The reaction is performed with dienynes and an oxygen tether containing a terminal or internal triple bond.
language: eng
source:
identifier: E-ISSN: 1521-3765 ; DOI: 10.1002/chem.201204555
fulltext: fulltext
issn:
  • 15213765
  • 1521-3765
url: Link


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ispartofChemistry (Weinheim an der Bergstrasse, Germany), May 17, 2013, Vol.19(21), pp.6571-6575
identifierE-ISSN: 1521-3765 ; DOI: 10.1002/chem.201204555
subjectAlkadienes–Chemistry ; Alkynes–Chemistry ; Boronic Acids–Chemistry ; Carbon–Chemistry ; Catalysis–Chemistry ; Cyclization–Chemistry ; Molecular Structure–Chemistry ; Oxidation-Reduction–Chemistry ; Oxygen–Chemistry ; Palladium–Chemistry ; Stereoisomerism–Chemistry ; Alkadienes ; Alkynes ; Boronic Acids ; Palladium ; Carbon ; Benzeneboronic Acid ; Oxygen
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descriptionTransmetallation: A highly regio- and diastereoselective carbocyclization involving a palladium-catalyzed 1,2-addition of two carbon atoms across a conjugated diene has been developed (see scheme). The reaction is performed with dienynes and an oxygen tether containing a terminal or internal triple bond.
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