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Selective C(sp2)-C(sp) bond cleavage: the nitrogenation of alkynes to amides.

Breakthrough: A novel catalyzed direct highly selective C sp 2 --C sub(sp) bond functionalization of alkynes to amides has been developed. Nitrogenation is achieved by the highly selective C sp 2 --C sub(sp) bond cleavage of aryl-substituted alkynes. The oxidant-free and mild conditions and wide sub... Full description

Journal Title: Angewandte Chemie (International ed. in English) July 22, 2013, Vol.52(30), pp.7850-7854
Main Author: Qin, Chong
Other Authors: Feng, Peng , Ou, Yang , Shen, Tao , Wang, Teng , Jiao, Ning
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1521-3773 ; DOI: 10.1002/anie.201303376
Link: http://search.proquest.com/docview/1406174940/?pq-origsite=primo
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title: Selective C(sp2)-C(sp) bond cleavage: the nitrogenation of alkynes to amides.
format: Article
creator:
  • Qin, Chong
  • Feng, Peng
  • Ou, Yang
  • Shen, Tao
  • Wang, Teng
  • Jiao, Ning
subjects:
  • Alkynes–Chemistry
  • Amides–Chemistry
  • Catalysis–Chemistry
  • Cyclization–Chemistry
  • Molecular Structure–Chemistry
  • Nitrogen–Chemistry
  • Oxidants–Chemistry
  • Oxidation-Reduction–Chemistry
  • Stereoisomerism–Chemistry
  • Alkynes
  • Amides
  • Oxidants
  • Nitrogen
  • Cc Bond Cleavage
  • Alkynes
  • Amides
  • Gold
  • Rearrangement
ispartof: Angewandte Chemie (International ed. in English), July 22, 2013, Vol.52(30), pp.7850-7854
description: Breakthrough: A novel catalyzed direct highly selective C sp 2 --C sub(sp) bond functionalization of alkynes to amides has been developed. Nitrogenation is achieved by the highly selective C sp 2 --C sub(sp) bond cleavage of aryl-substituted alkynes. The oxidant-free and mild conditions and wide substrate scope make this method very practical.
language: eng
source:
identifier: E-ISSN: 1521-3773 ; DOI: 10.1002/anie.201303376
fulltext: fulltext
issn:
  • 15213773
  • 1521-3773
url: Link


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titleSelective C(sp2)-C(sp) bond cleavage: the nitrogenation of alkynes to amides.
creatorQin, Chong ; Feng, Peng ; Ou, Yang ; Shen, Tao ; Wang, Teng ; Jiao, Ning
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identifierE-ISSN: 1521-3773 ; DOI: 10.1002/anie.201303376
subjectAlkynes–Chemistry ; Amides–Chemistry ; Catalysis–Chemistry ; Cyclization–Chemistry ; Molecular Structure–Chemistry ; Nitrogen–Chemistry ; Oxidants–Chemistry ; Oxidation-Reduction–Chemistry ; Stereoisomerism–Chemistry ; Alkynes ; Amides ; Oxidants ; Nitrogen ; Cc Bond Cleavage ; Alkynes ; Amides ; Gold ; Rearrangement
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descriptionBreakthrough: A novel catalyzed direct highly selective C sp 2 --C sub(sp) bond functionalization of alkynes to amides has been developed. Nitrogenation is achieved by the highly selective C sp 2 --C sub(sp) bond cleavage of aryl-substituted alkynes. The oxidant-free and mild conditions and wide substrate scope make this method very practical.
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titleSelective C(sp2)-C(sp) bond cleavage: the nitrogenation of alkynes to amides.
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