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A directly linked ferrocene-naphthalenediimide conjugate: precise control of stacking structures of π-systems by redox stimuli.

A ferrocene derivative having directly connected naphthalenediimide moieties has been synthesized. The stacking-destacking structures of the naphthalenediimides can be switched in response to redox stimuli by associating with the pivoting motion of ferrocene. The conformation and the electronic stru... Full description

Journal Title: Angewandte Chemie (International ed. in English) August 26, 2013, Vol.52(35), pp.9167-9171
Main Author: Takai, Atsuro
Other Authors: Yasuda, Takeshi , Ishizuka, Tomoya , Kojima, Takahiko , Takeuchi, Masayuki
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1521-3773 ; DOI: 1521-3773 ; DOI: 10.1002/anie.201302587
Link: http://search.proquest.com/docview/1427744335/?pq-origsite=primo
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title: A directly linked ferrocene-naphthalenediimide conjugate: precise control of stacking structures of π-systems by redox stimuli.
format: Article
creator:
  • Takai, Atsuro
  • Yasuda, Takeshi
  • Ishizuka, Tomoya
  • Kojima, Takahiko
  • Takeuchi, Masayuki
subjects:
  • Ferrous Compounds–Chemistry
  • Imides–Chemistry
  • Metallocenes–Chemistry
  • Models, Molecular–Chemistry
  • Molecular Structure–Chemistry
  • Naphthalenes–Chemistry
  • Oxidation-Reduction–Chemistry
  • Ferrous Compounds
  • Imides
  • Metallocenes
  • Naphthalenes
  • Naphthalenediimide
  • Ferrocene
  • Donor-Acceptor Systems
  • Electronic Structure
  • Materials Science
  • Stacking Interactions
  • Π Interactions
ispartof: Angewandte Chemie (International ed. in English), August 26, 2013, Vol.52(35), pp.9167-9171
description: A ferrocene derivative having directly connected naphthalenediimide moieties has been synthesized. The stacking-destacking structures of the naphthalenediimides can be switched in response to redox stimuli by associating with the pivoting motion of ferrocene. The conformation and the electronic structure of naphthalenediimides are elucidated quantitatively in each electron-transfer state. The composite exhibited n-type semiconducting behavior.
language: eng
source:
identifier: E-ISSN: 1521-3773 ; DOI: 1521-3773 ; DOI: 10.1002/anie.201302587
fulltext: fulltext
issn:
  • 15213773
  • 1521-3773
url: Link


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titleA directly linked ferrocene-naphthalenediimide conjugate: precise control of stacking structures of π-systems by redox stimuli.
creatorTakai, Atsuro ; Yasuda, Takeshi ; Ishizuka, Tomoya ; Kojima, Takahiko ; Takeuchi, Masayuki
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subjectFerrous Compounds–Chemistry ; Imides–Chemistry ; Metallocenes–Chemistry ; Models, Molecular–Chemistry ; Molecular Structure–Chemistry ; Naphthalenes–Chemistry ; Oxidation-Reduction–Chemistry ; Ferrous Compounds ; Imides ; Metallocenes ; Naphthalenes ; Naphthalenediimide ; Ferrocene ; Donor-Acceptor Systems ; Electronic Structure ; Materials Science ; Stacking Interactions ; Π Interactions
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descriptionA ferrocene derivative having directly connected naphthalenediimide moieties has been synthesized. The stacking-destacking structures of the naphthalenediimides can be switched in response to redox stimuli by associating with the pivoting motion of ferrocene. The conformation and the electronic structure of naphthalenediimides are elucidated quantitatively in each electron-transfer state. The composite exhibited n-type semiconducting behavior.
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titleA directly linked ferrocene-naphthalenediimide conjugate: precise control of stacking structures of π-systems by redox stimuli.
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