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Copper-Catalyzed Three-Component Oxytrifluoromethylation of Alkenes with Sodium Trifluoromethanesulfinate and Hydroxamic Acid

Radical paths: The title reaction of olefins with NaSO2 CF3 and N-hydroxy-N-phenylacetamide at room temperature is described for the first time. This reaction provides a practical and convenient route to a series of trifluoromethylated alcohols bearing a wide range of functional groups.

Journal Title: Angewandte Chemie Dec 23, 2013, Vol.52(52), pp.14177-80
Main Author: Jiang, Xin-Yi
Other Authors: Qing, Feng-Ling
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 14337851 ; E-ISSN: 15213773 ; DOI: 10.1002/anie.201307595
Link: http://search.proquest.com/docview/1468942225/?pq-origsite=primo
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title: Copper-Catalyzed Three-Component Oxytrifluoromethylation of Alkenes with Sodium Trifluoromethanesulfinate and Hydroxamic Acid
format: Article
creator:
  • Jiang, Xin-Yi
  • Qing, Feng-Ling
subjects:
  • Alkenes–Chemistry
  • Catalysis–Chemistry
  • Copper–Chemistry
  • Hydroxamic Acids–Chemistry
  • Oxidation-Reduction–Chemistry
  • Stereoisomerism–Chemistry
  • Alkenes
  • Hydroxamic Acids
  • Copper
ispartof: Angewandte Chemie, Dec 23, 2013, Vol.52(52), pp.14177-80
description: Radical paths: The title reaction of olefins with NaSO2 CF3 and N-hydroxy-N-phenylacetamide at room temperature is described for the first time. This reaction provides a practical and convenient route to a series of trifluoromethylated alcohols bearing a wide range of functional groups.
language: eng
source:
identifier: ISSN: 14337851 ; E-ISSN: 15213773 ; DOI: 10.1002/anie.201307595
fulltext: fulltext
issn:
  • 14337851
  • 1433-7851
  • 15213773
  • 1521-3773
url: Link


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descriptionRadical paths: The title reaction of olefins with NaSO2 CF3 and N-hydroxy-N-phenylacetamide at room temperature is described for the first time. This reaction provides a practical and convenient route to a series of trifluoromethylated alcohols bearing a wide range of functional groups.
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titleCopper-Catalyzed Three-Component Oxytrifluoromethylation of Alkenes with Sodium Trifluoromethanesulfinate and Hydroxamic Acid
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abstractRadical paths: The title reaction of olefins with NaSO2 CF3 and N-hydroxy-N-phenylacetamide at room temperature is described for the first time. This reaction provides a practical and convenient route to a series of trifluoromethylated alcohols bearing a wide range of functional groups.
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pubWiley Subscription Services, Inc.
doi10.1002/anie.201307595
urlhttp://search.proquest.com/docview/1468942225/
date2013-12-23