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A One-step Strategy for Reinforced Poly(propylene carbonate) with Partial Crosslinking via Terpolymerization of CO2 and Propylene Oxide Using Triglycidyl Isocyanurate

  Partly crosslinked poly(propylene carbonate) (pc-PPC) is directly prepared by terpolymerization of CO2 and propylene oxide using multifunctional triglycidyl isocyanurate (TGIC). It is thermoplastic and exhibits significantly enhanced properties with the 5% weight-loss degradation temperature of 27... Full description

Journal Title: Chemistry Letters 2013, Vol.42(7), p.714
Main Author: Feng, Jiu-Ying
Other Authors: Gao, Li-Jun , Chen, Bing , Wu, Xiao-Jun , Luo, Qiao-Li , Wu, Cai-Yan , Zheng, Chun-Xia , Lin, Liang-Zhu , Deng, Shu-Lin , Huang, Xiao-Min
Format: Electronic Article Electronic Article
Language: English
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ID: ISSN: 03667022 ; E-ISSN: 13480715
Link: http://search.proquest.com/docview/1478036421/?pq-origsite=primo
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title: A One-step Strategy for Reinforced Poly(propylene carbonate) with Partial Crosslinking via Terpolymerization of CO2 and Propylene Oxide Using Triglycidyl Isocyanurate
format: Article
creator:
  • Feng, Jiu-Ying
  • Gao, Li-Jun
  • Chen, Bing
  • Wu, Xiao-Jun
  • Luo, Qiao-Li
  • Wu, Cai-Yan
  • Zheng, Chun-Xia
  • Lin, Liang-Zhu
  • Deng, Shu-Lin
  • Huang, Xiao-Min
subjects:
  • Terpolymerization
  • Tgic
  • Elongation
  • Crosslinking
  • Triglycidyl Isocyanurate
  • Carbonates
  • Strategy
  • Carbon Dioxide
  • Propylene Oxide
  • Chemical and Electrochemical Properties (Ep)
  • Chemical and Electrochemical Properties (Ed)
  • Chemical and Electrochemical Properties (EC)
ispartof: Chemistry Letters, 2013, Vol.42(7), p.714
description:   Partly crosslinked poly(propylene carbonate) (pc-PPC) is directly prepared by terpolymerization of CO2 and propylene oxide using multifunctional triglycidyl isocyanurate (TGIC). It is thermoplastic and exhibits significantly enhanced properties with the 5% weight-loss degradation temperature of 271 °C and the tensile strength of 37.4 MPa, along with good toughness with elongation at break of 446%. These findings may develop a facile and effective way to ensure that PPC can be melt-processed without decomposition and used as a structural material.
language: eng
source:
identifier: ISSN: 03667022 ; E-ISSN: 13480715
fulltext: fulltext
issn:
  • 03667022
  • 0366-7022
  • 13480715
  • 1348-0715
url: Link


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titleA One-step Strategy for Reinforced Poly(propylene carbonate) with Partial Crosslinking via Terpolymerization of CO2 and Propylene Oxide Using Triglycidyl Isocyanurate
creatorFeng, Jiu-Ying ; Gao, Li-Jun ; Chen, Bing ; Wu, Xiao-Jun ; Luo, Qiao-Li ; Wu, Cai-Yan ; Zheng, Chun-Xia ; Lin, Liang-Zhu ; Deng, Shu-Lin ; Huang, Xiao-Min
ispartofChemistry Letters, 2013, Vol.42(7), p.714
identifierISSN: 03667022 ; E-ISSN: 13480715
description  Partly crosslinked poly(propylene carbonate) (pc-PPC) is directly prepared by terpolymerization of CO2 and propylene oxide using multifunctional triglycidyl isocyanurate (TGIC). It is thermoplastic and exhibits significantly enhanced properties with the 5% weight-loss degradation temperature of 271 °C and the tensile strength of 37.4 MPa, along with good toughness with elongation at break of 446%. These findings may develop a facile and effective way to ensure that PPC can be melt-processed without decomposition and used as a structural material.
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subjectTerpolymerization ; Tgic ; Elongation ; Crosslinking ; Triglycidyl Isocyanurate ; Carbonates ; Strategy ; Carbon Dioxide ; Propylene Oxide ; Chemical and Electrochemical Properties (Ep) ; Chemical and Electrochemical Properties (Ed) ; Chemical and Electrochemical Properties (EC);
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titleA One-step Strategy for Reinforced Poly(propylene carbonate) with Partial Crosslinking via Terpolymerization of CO2 and Propylene Oxide Using Triglycidyl Isocyanurate
description  Partly crosslinked poly(propylene carbonate) (pc-PPC) is directly prepared by terpolymerization of CO2 and propylene oxide using multifunctional triglycidyl isocyanurate (TGIC). It is thermoplastic and exhibits significantly enhanced properties with the 5% weight-loss degradation temperature of 271 °C and the tensile strength of 37.4 MPa, along with good toughness with elongation at break of 446%. These findings may develop a facile and effective way to ensure that PPC can be melt-processed without decomposition and used as a structural material.
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atitleA One-step Strategy for Reinforced Poly(propylene carbonate) with Partial Crosslinking via Terpolymerization of CO2 and Propylene Oxide Using Triglycidyl Isocyanurate
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abstract  Partly crosslinked poly(propylene carbonate) (pc-PPC) is directly prepared by terpolymerization of CO2 and propylene oxide using multifunctional triglycidyl isocyanurate (TGIC). It is thermoplastic and exhibits significantly enhanced properties with the 5% weight-loss degradation temperature of 271 °C and the tensile strength of 37.4 MPa, along with good toughness with elongation at break of 446%. These findings may develop a facile and effective way to ensure that PPC can be melt-processed without decomposition and used as a structural material.
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pubChemical Society of Japan
urlhttp://search.proquest.com/docview/1478036421/
pages714-716
doi10.1246/cl.130165
date2013-07-01