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Benzo[f]benzo[5,6]indolo[3,2-b]indole: a stable unsubstituted 4nπ-electron acene with an antiaromatic 1,4-diazapentalene core.

A stable unsubstituted 4nπ-electron acene with an antiaromatic 1,4-diazapentalene core was prepared via an unprecedented mild oxidation. Further investigation showed that the stability of such acenes was dependent on the fusion patterns of the peripheryl benzene rings to the centre core.

Journal Title: Chemical communications (Cambridge England), March 28, 2014, Vol.50(25), pp.3324-3327
Main Author: Qiu, Li
Other Authors: Zhuang, Xuhui , Zhao, Na , Wang, Xiao , An, Zengjian , Lan, Zhenggang , Wan, Xiaobo
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1364-548X ; DOI: 1364-548X ; DOI: 10.1039/c3cc49418g
Link: http://search.proquest.com/docview/1503554678/?pq-origsite=primo
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recordid: proquest1503554678
title: Benzo[f]benzo[5,6]indolo[3,2-b]indole: a stable unsubstituted 4nπ-electron acene with an antiaromatic 1,4-diazapentalene core.
format: Article
creator:
  • Qiu, Li
  • Zhuang, Xuhui
  • Zhao, Na
  • Wang, Xiao
  • An, Zengjian
  • Lan, Zhenggang
  • Wan, Xiaobo
subjects:
  • Electrons–Chemistry
  • Indoles–Chemistry
  • Molecular Structure–Chemistry
  • Oxidation-Reduction–Chemistry
  • Indoles
ispartof: Chemical communications (Cambridge, England), March 28, 2014, Vol.50(25), pp.3324-3327
description: A stable unsubstituted 4nπ-electron acene with an antiaromatic 1,4-diazapentalene core was prepared via an unprecedented mild oxidation. Further investigation showed that the stability of such acenes was dependent on the fusion patterns of the peripheryl benzene rings to the centre core.
language: eng
source:
identifier: E-ISSN: 1364-548X ; DOI: 1364-548X ; DOI: 10.1039/c3cc49418g
fulltext: fulltext
issn:
  • 1364548X
  • 1364-548X
url: Link


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descriptionA stable unsubstituted 4nπ-electron acene with an antiaromatic 1,4-diazapentalene core was prepared via an unprecedented mild oxidation. Further investigation showed that the stability of such acenes was dependent on the fusion patterns of the peripheryl benzene rings to the centre core.
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