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De novo synthesis of multisubstituted aryl amines using alkene cross metathesis.

The olefin cross-metathesis reaction allows rapid access to 1,5-dicarbonyl intermediates which, upon treatment with a primary or secondary amine, allow the synthesis of a range of multisubstituted carbocyclic aryl amines. This de novo arene synthesis yields nonclassical substitution patterns in a re... Full description

Journal Title: Organic letters April 4, 2014, Vol.16(7), pp.1920-1923
Main Author: Tatton, Matthew R
Other Authors: Simpson, Iain , Donohoe, Timothy J
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1523-7052 ; DOI: 10.1021/ol500441q
Link: http://search.proquest.com/docview/1513051598/?pq-origsite=primo
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recordid: proquest1513051598
title: De novo synthesis of multisubstituted aryl amines using alkene cross metathesis.
format: Article
creator:
  • Tatton, Matthew R
  • Simpson, Iain
  • Donohoe, Timothy J
subjects:
  • Alkenes–Chemistry
  • Amines–Chemical Synthesis
  • Catalysis–Chemistry
  • Molecular Structure–Chemistry
  • Stereoisomerism–Chemistry
  • Alkenes
  • Amines
ispartof: Organic letters, April 4, 2014, Vol.16(7), pp.1920-1923
description: The olefin cross-metathesis reaction allows rapid access to 1,5-dicarbonyl intermediates which, upon treatment with a primary or secondary amine, allow the synthesis of a range of multisubstituted carbocyclic aryl amines. This de novo arene synthesis yields nonclassical substitution patterns in a regioselective and predictable approach that is compatible with several functional groups.
language: eng
source:
identifier: E-ISSN: 1523-7052 ; DOI: 10.1021/ol500441q
fulltext: fulltext
issn:
  • 15237052
  • 1523-7052
url: Link


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titleDe novo synthesis of multisubstituted aryl amines using alkene cross metathesis.
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identifierE-ISSN: 1523-7052 ; DOI: 10.1021/ol500441q
subjectAlkenes–Chemistry ; Amines–Chemical Synthesis ; Catalysis–Chemistry ; Molecular Structure–Chemistry ; Stereoisomerism–Chemistry ; Alkenes ; Amines
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descriptionThe olefin cross-metathesis reaction allows rapid access to 1,5-dicarbonyl intermediates which, upon treatment with a primary or secondary amine, allow the synthesis of a range of multisubstituted carbocyclic aryl amines. This de novo arene synthesis yields nonclassical substitution patterns in a regioselective and predictable approach that is compatible with several functional groups.
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