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Efficient imidation of C(sp3)-H bonds adjacent to oxygen atoms of aryl ethers under metal-free conditions.

An intermolecular oxidative C-N formation reaction of aryl ethers with pharmacological saccharins was realized under metal-free conditions for the first time. The understanding of the intrinsic characteristics between C(sp super(3))-H and C(sp super(2))-O bonds of aryl ethers and their potential for... Full description

Journal Title: Chemical communications (Cambridge England), November 4, 2014, Vol.50(85), pp.12880-12883
Main Author: Sun, Kai
Other Authors: Wang, Xin , Li, Gang , Zhu, Zhonghong , Jiang, Yongqing , Xiao, Beibei
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1364-548X ; DOI: 1364-548X ; DOI: 10.1039/c4cc06003b
Link: http://search.proquest.com/docview/1567051313/?pq-origsite=primo
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title: Efficient imidation of C(sp3)-H bonds adjacent to oxygen atoms of aryl ethers under metal-free conditions.
format: Article
creator:
  • Sun, Kai
  • Wang, Xin
  • Li, Gang
  • Zhu, Zhonghong
  • Jiang, Yongqing
  • Xiao, Beibei
subjects:
  • Ethers–Chemistry
  • Hydrocarbons, Aromatic–Chemistry
  • Hydrogen Bonding–Chemistry
  • Imides–Chemistry
  • Oxidation-Reduction–Chemistry
  • Oxygen–Chemistry
  • Ethers
  • Hydrocarbons, Aromatic
  • Imides
  • Oxygen
ispartof: Chemical communications (Cambridge, England), November 4, 2014, Vol.50(85), pp.12880-12883
description: An intermolecular oxidative C-N formation reaction of aryl ethers with pharmacological saccharins was realized under metal-free conditions for the first time. The understanding of the intrinsic characteristics between C(sp super(3))-H and C(sp super(2))-O bonds of aryl ethers and their potential for application might promote more research interest in this area.
language: eng
source:
identifier: E-ISSN: 1364-548X ; DOI: 1364-548X ; DOI: 10.1039/c4cc06003b
fulltext: fulltext
issn:
  • 1364548X
  • 1364-548X
url: Link


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titleEfficient imidation of C(sp3)-H bonds adjacent to oxygen atoms of aryl ethers under metal-free conditions.
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descriptionAn intermolecular oxidative C-N formation reaction of aryl ethers with pharmacological saccharins was realized under metal-free conditions for the first time. The understanding of the intrinsic characteristics between C(sp super(3))-H and C(sp super(2))-O bonds of aryl ethers and their potential for application might promote more research interest in this area.
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