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Oxidative Heck desymmetrisation of 2,2-disubstituted cyclopentene-1,3-diones.

Oxidative Heck couplings have been successfully developed for 2,2-disubstituted cyclopentene-1,3-diones. The direct coupling onto the 2,2-disubstituted cyclopentene-1,3-dione core provides a novel expedient way of enantioselectively desymmetrising all-carbon quaternary centres.

Journal Title: Chemical communications (Cambridge England), March 7, 2015, Vol.51(19), pp.4089-4092
Main Author: Walker, S E
Other Authors: Lamb, C J C , Beattie, N A , Nikodemiak, P , Lee, A-L
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1364-548X ; DOI: 1364-548X ; DOI: 10.1039/c5cc00407a
Link: http://search.proquest.com/docview/1657328043/?pq-origsite=primo
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recordid: proquest1657328043
title: Oxidative Heck desymmetrisation of 2,2-disubstituted cyclopentene-1,3-diones.
format: Article
creator:
  • Walker, S E
  • Lamb, C J C
  • Beattie, N A
  • Nikodemiak, P
  • Lee, A-L
subjects:
  • Cyclopentanes–Chemistry
  • Ketones–Chemistry
  • Oxidation-Reduction–Chemistry
  • Stereoisomerism–Chemistry
  • Cyclopentanes
  • Ketones
ispartof: Chemical communications (Cambridge, England), March 7, 2015, Vol.51(19), pp.4089-4092
description: Oxidative Heck couplings have been successfully developed for 2,2-disubstituted cyclopentene-1,3-diones. The direct coupling onto the 2,2-disubstituted cyclopentene-1,3-dione core provides a novel expedient way of enantioselectively desymmetrising all-carbon quaternary centres.
language: eng
source:
identifier: E-ISSN: 1364-548X ; DOI: 1364-548X ; DOI: 10.1039/c5cc00407a
fulltext: fulltext
issn:
  • 1364548X
  • 1364-548X
url: Link


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titleOxidative Heck desymmetrisation of 2,2-disubstituted cyclopentene-1,3-diones.
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descriptionOxidative Heck couplings have been successfully developed for 2,2-disubstituted cyclopentene-1,3-diones. The direct coupling onto the 2,2-disubstituted cyclopentene-1,3-dione core provides a novel expedient way of enantioselectively desymmetrising all-carbon quaternary centres.
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