schliessen

Filtern

 

Bibliotheken

Derivitization of pristine graphene for bulk heterojunction polymeric photovoltaic devices

In this communication, we report a simple method for a covalent band-forming reaction to change the hybridization of carbon atoms from sp super(2) to sp super(3), to introduce a band gap in pristine graphene. Graphene with well-defined functionality was synthesized, and the resulting material was so... Full description

Journal Title: Journal of Materials Chemistry Jul 2012, Vol.22(33), pp.16723-16727
Main Author: Ye, Lei
Other Authors: Xiao, Ting , Zhao, Ni , Xu, Haihua , Xiao, Yubin , Xu, Jianbin , Xiong, Yuzi , Xu, Weijian
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 0959-9428 ; E-ISSN: 1364-5501 ; DOI: 10.1039/c2jm32729e
Link: http://search.proquest.com/docview/1671380413/?pq-origsite=primo
Zum Text:
SendSend as email Add to Book BagAdd to Book Bag
Staff View
recordid: proquest1671380413
title: Derivitization of pristine graphene for bulk heterojunction polymeric photovoltaic devices
format: Article
creator:
  • Ye, Lei
  • Xiao, Ting
  • Zhao, Ni
  • Xu, Haihua
  • Xiao, Yubin
  • Xu, Jianbin
  • Xiong, Yuzi
  • Xu, Weijian
subjects:
  • Covalence
  • Carbon
  • Graphene
  • Solar Cells
  • Devices
  • Solvents
  • Esters
  • Photovoltaic Cells
  • Thin Films, Surfaces, and Interfaces (So)
  • Chemical and Electrochemical Properties (MD)
  • Chemical and Electrochemical Properties (Ep)
  • Chemical and Electrochemical Properties (Ed)
  • Chemical and Electrochemical Properties (EC)
ispartof: Journal of Materials Chemistry, Jul 2012, Vol.22(33), pp.16723-16727
description: In this communication, we report a simple method for a covalent band-forming reaction to change the hybridization of carbon atoms from sp super(2) to sp super(3), to introduce a band gap in pristine graphene. Graphene with well-defined functionality was synthesized, and the resulting material was soluble in organic solvent. The LUMO of functionalized graphene was below the LUMO of poly(3-hexylthiophene) (P3HT) and close to that of [6,6]-phenyl C sub(61)-butyric acid methyl ester (PCBM), indicating its suitability as an electron acceptor for organic photovoltaic (OPV) applications. We further show the P3HT/functionalized graphene composite as the active layer in a solar cell, with device efficiency of 1.1%.
language: eng
source:
identifier: ISSN: 0959-9428 ; E-ISSN: 1364-5501 ; DOI: 10.1039/c2jm32729e
fulltext: fulltext
issn:
  • 09599428
  • 0959-9428
  • 13645501
  • 1364-5501
url: Link


@attributes
ID551733312
RANK0.06999999
NO1
SEARCH_ENGINEprimo_central_multiple_fe
SEARCH_ENGINE_TYPEPrimo Central Search Engine
LOCALfalse
PrimoNMBib
record
control
sourcerecordid1671380413
sourceidproquest
recordidTN_proquest1671380413
sourcesystemPC
pqid1671380413
display
typearticle
titleDerivitization of pristine graphene for bulk heterojunction polymeric photovoltaic devices
creatorYe, Lei ; Xiao, Ting ; Zhao, Ni ; Xu, Haihua ; Xiao, Yubin ; Xu, Jianbin ; Xiong, Yuzi ; Xu, Weijian
contributorYe, Lei (correspondence author)
ispartofJournal of Materials Chemistry, Jul 2012, Vol.22(33), pp.16723-16727
identifier
subjectCovalence ; Carbon ; Graphene ; Solar Cells ; Devices ; Solvents ; Esters ; Photovoltaic Cells ; Thin Films, Surfaces, and Interfaces (So) ; Chemical and Electrochemical Properties (MD) ; Chemical and Electrochemical Properties (Ep) ; Chemical and Electrochemical Properties (Ed) ; Chemical and Electrochemical Properties (EC)
descriptionIn this communication, we report a simple method for a covalent band-forming reaction to change the hybridization of carbon atoms from sp super(2) to sp super(3), to introduce a band gap in pristine graphene. Graphene with well-defined functionality was synthesized, and the resulting material was soluble in organic solvent. The LUMO of functionalized graphene was below the LUMO of poly(3-hexylthiophene) (P3HT) and close to that of [6,6]-phenyl C sub(61)-butyric acid methyl ester (PCBM), indicating its suitability as an electron acceptor for organic photovoltaic (OPV) applications. We further show the P3HT/functionalized graphene composite as the active layer in a solar cell, with device efficiency of 1.1%.
languageeng
source
version2
lds50peer_reviewed
links
openurl$$Topenurl_article
openurlfulltext$$Topenurlfull_article
backlink$$Uhttp://search.proquest.com/docview/1671380413/?pq-origsite=primo$$EView_record_in_ProQuest_(subscribers_only)
search
creatorcontrib
0Ye, Lei
1Xiao, Ting
2Zhao, Ni
3Xu, Haihua
4Xiao, Yubin
5Xu, Jianbin
6Xiong, Yuzi
7Xu, Weijian
titleDerivitization of pristine graphene for bulk heterojunction polymeric photovoltaic devices
descriptionIn this communication, we report a simple method for a covalent band-forming reaction to change the hybridization of carbon atoms from sp super(2) to sp super(3), to introduce a band gap in pristine graphene. Graphene with well-defined functionality was synthesized, and the resulting material was soluble in organic solvent. The LUMO of functionalized graphene was below the LUMO of poly(3-hexylthiophene) (P3HT) and close to that of [6,6]-phenyl C sub(61)-butyric acid methyl ester (PCBM), indicating its suitability as an electron acceptor for organic photovoltaic (OPV) applications. We further show the P3HT/functionalized graphene composite as the active layer in a solar cell, with device efficiency of 1.1%.
subject
0Covalence
1Carbon
2Graphene
3Solar Cells
4Devices
5Solvents
6Esters
7Photovoltaic Cells
8Thin Films, Surfaces, and Interfaces (So)
9Chemical and Electrochemical Properties (MD)
10Chemical and Electrochemical Properties (Ep)
11Chemical and Electrochemical Properties (Ed)
12Chemical and Electrochemical Properties (EC)
1331
1434
15C4
general
0English
110.1039/c2jm32729e
2Engineered Materials Abstracts
3Solid State and Superconductivity Abstracts
4METADEX
5Advanced Technologies Database with Aerospace
6Materials Research Database
7Technology Research Database
8ProQuest Advanced Technologies & Aerospace Collection
9ProQuest Materials Science Collection
10ProQuest Technology Collection
11ProQuest SciTech Collection
12Advanced Technologies & Aerospace Database
13Materials Science & Engineering Database
14SciTech Premium Collection
15Technology Collection
sourceidproquest
recordidproquest1671380413
issn
009599428
10959-9428
213645501
31364-5501
rsrctypearticle
creationdate2012
addtitleJournal of Materials Chemistry
searchscope
01007393
11007481
21007528
31007944
410000012
510000014
610000015
710000022
810000045
910000049
1010000053
1110000120
1210000195
1310000201
1410000203
1510000209
1610000233
1710000250
1810000260
1910000265
20proquest
scope
01007393
11007481
21007528
31007944
410000012
510000014
610000015
710000022
810000045
910000049
1010000053
1110000120
1210000195
1310000201
1410000203
1510000209
1610000233
1710000250
1810000260
1910000265
20proquest
lsr43
01007393false
11007481false
21007528false
31007944false
410000012false
510000014false
610000015false
710000022false
810000045false
910000049false
1010000053false
1110000120false
1210000195false
1310000201false
1410000203false
1510000209false
1610000233false
1710000250false
1810000260false
1910000265false
contributorYe, Lei
startdate20120701
enddate20120701
citationpf 16723 pt 16727 vol 22 issue 33
lsr30VSR-Enriched:[pqid]
sort
titleDerivitization of pristine graphene for bulk heterojunction polymeric photovoltaic devices
authorYe, Lei ; Xiao, Ting ; Zhao, Ni ; Xu, Haihua ; Xiao, Yubin ; Xu, Jianbin ; Xiong, Yuzi ; Xu, Weijian
creationdate20120701
lso0120120701
facets
frbrgroupid5030863395124026308
frbrtype5
languageeng
creationdate2012
topic
0Covalence
1Carbon
2Graphene
3Solar Cells
4Devices
5Solvents
6Esters
7Photovoltaic Cells
8Thin Films, Surfaces, and Interfaces (So)
9Chemical and Electrochemical Properties (MD)
10Chemical and Electrochemical Properties (Ep)
11Chemical and Electrochemical Properties (Ed)
12Chemical and Electrochemical Properties (EC)
collection
0Engineered Materials Abstracts
1Solid State and Superconductivity Abstracts
2METADEX
3Advanced Technologies Database with Aerospace
4Materials Research Database
5Technology Research Database
6ProQuest Advanced Technologies & Aerospace Collection
7ProQuest Materials Science Collection
8ProQuest Technology Collection
9ProQuest SciTech Collection
10Advanced Technologies & Aerospace Database
11Materials Science & Engineering Database
12SciTech Premium Collection
13Technology Collection
prefilterarticles
rsrctypearticles
creatorcontrib
0Ye, Lei
1Xiao, Ting
2Zhao, Ni
3Xu, Haihua
4Xiao, Yubin
5Xu, Jianbin
6Xiong, Yuzi
7Xu, Weijian
jtitleJournal of Materials Chemistry
toplevelpeer_reviewed
delivery
delcategoryRemote Search Resource
fulltextfulltext
addata
aulast
0Ye
1Xiao
2Zhao
3Xu
4Xiong
aufirst
0Lei
1Ting
2Ni
3Haihua
4Yubin
5Jianbin
6Yuzi
7Weijian
au
0Ye, Lei
1Xiao, Ting
2Zhao, Ni
3Xu, Haihua
4Xiao, Yubin
5Xu, Jianbin
6Xiong, Yuzi
7Xu, Weijian
addauYe, Lei
atitleDerivitization of pristine graphene for bulk heterojunction polymeric photovoltaic devices
jtitleJournal of Materials Chemistry
risdate20120701
volume22
issue33
spage16723
epage16727
pages16723-16727
issn0959-9428
eissn1364-5501
formatjournal
genrearticle
ristypeJOUR
abstractIn this communication, we report a simple method for a covalent band-forming reaction to change the hybridization of carbon atoms from sp super(2) to sp super(3), to introduce a band gap in pristine graphene. Graphene with well-defined functionality was synthesized, and the resulting material was soluble in organic solvent. The LUMO of functionalized graphene was below the LUMO of poly(3-hexylthiophene) (P3HT) and close to that of [6,6]-phenyl C sub(61)-butyric acid methyl ester (PCBM), indicating its suitability as an electron acceptor for organic photovoltaic (OPV) applications. We further show the P3HT/functionalized graphene composite as the active layer in a solar cell, with device efficiency of 1.1%.
doi10.1039/c2jm32729e
urlhttp://search.proquest.com/docview/1671380413/
date2012-07-01