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Temperature and Pressure Dependence of the Reaction S + CS (+M) → CS2 (+M).

Experimental data for the unimolecular decomposition of CS2 from the literature are analyzed by unimolecular rate theory with the goal of obtaining rate constants for the reverse reaction S + CS (+M) → CS2 (+M) over wide temperature and pressure ranges. The results constitute an important input for... Full description

Journal Title: The journal of physical chemistry. A July 16, 2015, Vol.119(28), pp.7277-7281
Main Author: Glarborg, Peter
Other Authors: Marshall, Paul , Troe, Jürgen
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1520-5215 ; DOI: 10.1021/jp5121492
Link: http://search.proquest.com/docview/1697211079/?pq-origsite=primo
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recordid: proquest1697211079
title: Temperature and Pressure Dependence of the Reaction S + CS (+M) → CS2 (+M).
format: Article
creator:
  • Glarborg, Peter
  • Marshall, Paul
  • Troe, Jürgen
subjects:
  • Carbon Disulfide–Chemistry
  • Kinetics–Chemistry
  • Models, Chemical–Chemistry
  • Pressure–Chemistry
  • Sulfur–Chemistry
  • Temperature–Chemistry
  • Sulfur
  • Carbon Disulfide
ispartof: The journal of physical chemistry. A, July 16, 2015, Vol.119(28), pp.7277-7281
description: Experimental data for the unimolecular decomposition of CS2 from the literature are analyzed by unimolecular rate theory with the goal of obtaining rate constants for the reverse reaction S + CS (+M) → CS2 (+M) over wide temperature and pressure ranges. The results constitute an important input for the kinetic modeling of CS2 oxidation. CS2 dissociation proceeds as a spin-forbidden process whose detailed properties are still not well understood. The role of the singlet-triplet transition involved is discussed.
language: eng
source:
identifier: E-ISSN: 1520-5215 ; DOI: 10.1021/jp5121492
fulltext: fulltext
issn:
  • 15205215
  • 1520-5215
url: Link


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titleTemperature and Pressure Dependence of the Reaction S + CS (+M) → CS2 (+M).
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descriptionExperimental data for the unimolecular decomposition of CS2 from the literature are analyzed by unimolecular rate theory with the goal of obtaining rate constants for the reverse reaction S + CS (+M) → CS2 (+M) over wide temperature and pressure ranges. The results constitute an important input for the kinetic modeling of CS2 oxidation. CS2 dissociation proceeds as a spin-forbidden process whose detailed properties are still not well understood. The role of the singlet-triplet transition involved is discussed.
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