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Asymmetric Synthesis of 2,3-Dihydropyrroles by Ring-Opening/Cyclization of Cyclopropyl Ketones Using Primary Amines

The asymmetric ring-opening/cyclization of cyclopropyl ketones with primary amine nucleophiles was catalyzed by a chiral N,N'-dioxide/scandium(III) complex through a kinetic resolution process. A broad range of cyclopropyl...

Journal Title: Angewandte Chemie (International Edition) Jan 2015, Vol.54(1), pp.227-230
Main Author: Xia, Yong
Other Authors: Liu, Xiaohua , Zheng, Haifeng , Lin, Lili , Feng, Xiaoming
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 1433-7851 ; E-ISSN: 1521-3773 ; DOI: 10.1002/anie.201407880
Link: http://search.proquest.com/docview/1701001877/?pq-origsite=primo
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recordid: proquest1701001877
title: Asymmetric Synthesis of 2,3-Dihydropyrroles by Ring-Opening/Cyclization of Cyclopropyl Ketones Using Primary Amines
format: Article
creator:
  • Xia, Yong
  • Liu, Xiaohua
  • Zheng, Haifeng
  • Lin, Lili
  • Feng, Xiaoming
subjects:
  • Reaction Kinetics
  • Nucleophiles
  • Ketones
  • Asymmetry
  • Organic Compounds
  • Synthesis
  • Amines
  • Analysis (MD)
  • Chemical Analysis (Ep)
  • Chemical Analysis (Ed)
  • Chemical Analysis (EC)
ispartof: Angewandte Chemie (International Edition), Jan 2015, Vol.54(1), pp.227-230
description: The asymmetric ring-opening/cyclization of cyclopropyl ketones with primary amine nucleophiles was catalyzed by a chiral N,N'-dioxide/scandium(III) complex through a kinetic resolution process. A broad range of cyclopropyl...
language: eng
source:
identifier: ISSN: 1433-7851 ; E-ISSN: 1521-3773 ; DOI: 10.1002/anie.201407880
fulltext: fulltext
issn:
  • 14337851
  • 1433-7851
  • 15213773
  • 1521-3773
url: Link


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subjectReaction Kinetics ; Nucleophiles ; Ketones ; Asymmetry ; Organic Compounds ; Synthesis ; Amines ; Analysis (MD) ; Chemical Analysis (Ep) ; Chemical Analysis (Ed) ; Chemical Analysis (EC)
descriptionThe asymmetric ring-opening/cyclization of cyclopropyl ketones with primary amine nucleophiles was catalyzed by a chiral N,N'-dioxide/scandium(III) complex through a kinetic resolution process. A broad range of cyclopropyl...
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abstractThe asymmetric ring-opening/cyclization of cyclopropyl ketones with primary amine nucleophiles was catalyzed by a chiral N,N'-dioxide/scandium(III) complex through a kinetic resolution process. A broad range of cyclopropyl...
doi10.1002/anie.201407880
urlhttp://search.proquest.com/docview/1701001877/
date2015-01-02