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Organoaluminum-Mediated Direct Cross-Coupling Reactions

We present a direct cross-coupling reaction between arylaluminum compounds (ArAlMe sub(2)LiCl) and organic halides RX (R=aryl, alkenyl, alkynyl; X=I, Br, and Cl) without any external catalyst. The reaction takes place smoothly, simply upon heating, thereby enabling the efficient and chemo-/stereosel... Full description

Journal Title: Angewandte Chemie (International Edition) Apr 2015, Vol.54(15), pp.4665-4668
Main Author: Minami, Hiroki
Other Authors: Saito, Tatsuo , Wang, Chao , Uchiyama, Masanobu
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 1433-7851 ; E-ISSN: 1521-3773 ; DOI: 10.1002/anie.201412249
Link: http://search.proquest.com/docview/1701023285/?pq-origsite=primo
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title: Organoaluminum-Mediated Direct Cross-Coupling Reactions
format: Article
creator:
  • Minami, Hiroki
  • Saito, Tatsuo
  • Wang, Chao
  • Uchiyama, Masanobu
subjects:
  • Joining
  • Heating
  • Formations
  • Compatibility
  • Aluminum
  • Olefins
  • Catalysts
  • Halides
  • Functional Groups
  • Analysis (MD)
  • Chemical Analysis (Ep)
  • Chemical Analysis (Ed)
  • Chemical Analysis (EC)
  • Alloy/Material Development (AI)
ispartof: Angewandte Chemie (International Edition), Apr 2015, Vol.54(15), pp.4665-4668
description: We present a direct cross-coupling reaction between arylaluminum compounds (ArAlMe sub(2)LiCl) and organic halides RX (R=aryl, alkenyl, alkynyl; X=I, Br, and Cl) without any external catalyst. The reaction takes place smoothly, simply upon heating, thereby enabling the efficient and chemo-/stereoselective formation of biaryl, alkene, and alkyne coupling products with broad functional group compatibility. All in Al: Simply heating an arylaluminum (ArAlMe sub(2)LiCl) and an organic halide RX (R=aryl, alkenyl, alkynyl; X=I, Br, Cl) without any external catalyst results in a smooth and direct cross-coupling reaction taking place. This approach enables the efficient, chemo-/stereoselective formation of coupling products with broad functional group compatibility.
language: eng
source:
identifier: ISSN: 1433-7851 ; E-ISSN: 1521-3773 ; DOI: 10.1002/anie.201412249
fulltext: fulltext
issn:
  • 14337851
  • 1433-7851
  • 15213773
  • 1521-3773
url: Link


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subjectJoining ; Heating ; Formations ; Compatibility ; Aluminum ; Olefins ; Catalysts ; Halides ; Functional Groups ; Analysis (MD) ; Chemical Analysis (Ep) ; Chemical Analysis (Ed) ; Chemical Analysis (EC) ; Alloy/Material Development (AI)
descriptionWe present a direct cross-coupling reaction between arylaluminum compounds (ArAlMe sub(2)LiCl) and organic halides RX (R=aryl, alkenyl, alkynyl; X=I, Br, and Cl) without any external catalyst. The reaction takes place smoothly, simply upon heating, thereby enabling the efficient and chemo-/stereoselective formation of biaryl, alkene, and alkyne coupling products with broad functional group compatibility. All in Al: Simply heating an arylaluminum (ArAlMe sub(2)LiCl) and an organic halide RX (R=aryl, alkenyl, alkynyl; X=I, Br, Cl) without any external catalyst results in a smooth and direct cross-coupling reaction taking place. This approach enables the efficient, chemo-/stereoselective formation of coupling products with broad functional group compatibility.
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abstractWe present a direct cross-coupling reaction between arylaluminum compounds (ArAlMe sub(2)LiCl) and organic halides RX (R=aryl, alkenyl, alkynyl; X=I, Br, and Cl) without any external catalyst. The reaction takes place smoothly, simply upon heating, thereby enabling the efficient and chemo-/stereoselective formation of biaryl, alkene, and alkyne coupling products with broad functional group compatibility. All in Al: Simply heating an arylaluminum (ArAlMe sub(2)LiCl) and an organic halide RX (R=aryl, alkenyl, alkynyl; X=I, Br, Cl) without any external catalyst results in a smooth and direct cross-coupling reaction taking place. This approach enables the efficient, chemo-/stereoselective formation of coupling products with broad functional group compatibility.
doi10.1002/anie.201412249
urlhttp://search.proquest.com/docview/1701023285/
date2015-04-07