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Catalytic Asymmetric Homologation of [alpha]-Ketoesters with [alpha]-Diazoesters: Synthesis of Succinate Derivatives with Chiral Quaternary Centers

Y not? In the presence of the L/Y(OTf) sub(3) catalyst, the first catalytic asymmetric homologation of [alpha]-ketoesters with [alpha]-alkyl-[alpha]-diazoesters through either a 1,2-aryl or 1,2-alkyl shift was accomplished. Highly functionalized succinate derivatives containing...

Journal Title: Angewandte Chemie (International Edition) Oct 2013, Vol.52(41), pp.10883-10886
Main Author: Li, Wei
Other Authors: Liu, Xiaohua , Tan, Fei , Hao, Xiaoyu , Zheng, Jianfeng , Lin, Lili , Feng, Xiaoming
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 1433-7851 ; E-ISSN: 1521-3773 ; DOI: 10.1002/anie.201305478
Link: http://search.proquest.com/docview/1701036929/?pq-origsite=primo
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title: Catalytic Asymmetric Homologation of [alpha]-Ketoesters with [alpha]-Diazoesters: Synthesis of Succinate Derivatives with Chiral Quaternary Centers
format: Article
creator:
  • Li, Wei
  • Liu, Xiaohua
  • Tan, Fei
  • Hao, Xiaoyu
  • Zheng, Jianfeng
  • Lin, Lili
  • Feng, Xiaoming
subjects:
  • Derivatives
  • Homology
  • Asymmetry
  • Catalysts
  • Synthesis
  • Catalysis
  • Analysis (MD)
  • Chemical Analysis (Ep)
  • Chemical Analysis (Ed)
  • Chemical Analysis (EC)
  • Asymmetric Catalysis
  • Diazo Compounds
  • Homogeneous Catalysis
  • Synthetic Methods
  • Yttrium
ispartof: Angewandte Chemie (International Edition), Oct 2013, Vol.52(41), pp.10883-10886
description: Y not? In the presence of the L/Y(OTf) sub(3) catalyst, the first catalytic asymmetric homologation of [alpha]-ketoesters with [alpha]-alkyl-[alpha]-diazoesters through either a 1,2-aryl or 1,2-alkyl shift was accomplished. Highly functionalized succinate derivatives containing...
language: eng
source:
identifier: ISSN: 1433-7851 ; E-ISSN: 1521-3773 ; DOI: 10.1002/anie.201305478
fulltext: fulltext
issn:
  • 14337851
  • 1433-7851
  • 15213773
  • 1521-3773
url: Link


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titleCatalytic Asymmetric Homologation of [alpha]-Ketoesters with [alpha]-Diazoesters: Synthesis of Succinate Derivatives with Chiral Quaternary Centers
creatorLi, Wei ; Liu, Xiaohua ; Tan, Fei ; Hao, Xiaoyu ; Zheng, Jianfeng ; Lin, Lili ; Feng, Xiaoming
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subjectDerivatives ; Homology ; Asymmetry ; Catalysts ; Synthesis ; Catalysis ; Analysis (MD) ; Chemical Analysis (Ep) ; Chemical Analysis (Ed) ; Chemical Analysis (EC) ; Asymmetric Catalysis ; Diazo Compounds ; Homogeneous Catalysis ; Synthetic Methods ; Yttrium
descriptionY not? In the presence of the L/Y(OTf) sub(3) catalyst, the first catalytic asymmetric homologation of [alpha]-ketoesters with [alpha]-alkyl-[alpha]-diazoesters through either a 1,2-aryl or 1,2-alkyl shift was accomplished. Highly functionalized succinate derivatives containing...
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titleCatalytic Asymmetric Homologation of [alpha]-Ketoesters with [alpha]-Diazoesters: Synthesis of Succinate Derivatives with Chiral Quaternary Centers
descriptionY not? In the presence of the L/Y(OTf) sub(3) catalyst, the first catalytic asymmetric homologation of [alpha]-ketoesters with [alpha]-alkyl-[alpha]-diazoesters through either a 1,2-aryl or 1,2-alkyl shift was accomplished. Highly functionalized succinate derivatives containing...
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titleCatalytic Asymmetric Homologation of [alpha]-Ketoesters with [alpha]-Diazoesters: Synthesis of Succinate Derivatives with Chiral Quaternary Centers
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abstractY not? In the presence of the L/Y(OTf) sub(3) catalyst, the first catalytic asymmetric homologation of [alpha]-ketoesters with [alpha]-alkyl-[alpha]-diazoesters through either a 1,2-aryl or 1,2-alkyl shift was accomplished. Highly functionalized succinate derivatives containing...
doi10.1002/anie.201305478
urlhttp://search.proquest.com/docview/1701036929/
date2013-10-04