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Cu and Au Metal-Organic Frameworks Bridge the Gap between Homogeneous and Heterogeneous Catalysts for Alkene Cyclopropanation Reactions

The copper and gold metal-organic frameworks (MOFs) [Cu3(BTC)2(H2O)3]n, [Cu3(BTC)2] (BTC=benzene-1,3,5-tricarboxylate), and IRMOF-3-SI-Au are active and reusable solid catalysts for the cyclopropanation of alkenes with high chemo- and diastereoselectivities. This type of material gives better result... Full description

Journal Title: Chemistry: A European Journal August 2010, Vol.16(32), pp.9789-9795
Main Author: Corma, Avelino
Other Authors: Iglesias, Marta , Llabresixamena, Francescx , Sanchez, Felix
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 0947-6539 ; E-ISSN: 1521-3765 ; DOI: 10.1002/chem.201000278
Link: http://search.proquest.com/docview/1777991415/?pq-origsite=primo
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title: Cu and Au Metal-Organic Frameworks Bridge the Gap between Homogeneous and Heterogeneous Catalysts for Alkene Cyclopropanation Reactions
format: Article
creator:
  • Corma, Avelino
  • Iglesias, Marta
  • Llabresixamena, Francescx
  • Sanchez, Felix
subjects:
  • Alkenes
  • Gold
  • Olefins
  • Copper
  • Catalysts
  • Reusable
  • Metalorganic Compounds
  • Metal-Organic Frameworks
  • Catalysis
  • Analysis (MD)
  • Chemical Analysis (Ep)
  • Chemical Analysis (Ed)
  • Chemical Analysis (EC)
ispartof: Chemistry: A European Journal, August 2010, Vol.16(32), pp.9789-9795
description: The copper and gold metal-organic frameworks (MOFs) [Cu3(BTC)2(H2O)3]n, [Cu3(BTC)2] (BTC=benzene-1,3,5-tricarboxylate), and IRMOF-3-SI-Au are active and reusable solid catalysts for the cyclopropanation of alkenes with high chemo- and diastereoselectivities. This type of material gives better results than previous solid catalysts while working together with the homogeneous catalysts. These MOFs can help to bridge the gap between homogeneous and heterogeneous catalysis.
language: eng
source:
identifier: ISSN: 0947-6539 ; E-ISSN: 1521-3765 ; DOI: 10.1002/chem.201000278
fulltext: fulltext
issn:
  • 09476539
  • 0947-6539
  • 15213765
  • 1521-3765
url: Link


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titleCu and Au Metal-Organic Frameworks Bridge the Gap between Homogeneous and Heterogeneous Catalysts for Alkene Cyclopropanation Reactions
creatorCorma, Avelino ; Iglesias, Marta ; Llabresixamena, Francescx ; Sanchez, Felix
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subjectAlkenes ; Gold ; Olefins ; Copper ; Catalysts ; Reusable ; Metalorganic Compounds ; Metal-Organic Frameworks ; Catalysis ; Analysis (MD) ; Chemical Analysis (Ep) ; Chemical Analysis (Ed) ; Chemical Analysis (EC)
descriptionThe copper and gold metal-organic frameworks (MOFs) [Cu3(BTC)2(H2O)3]n, [Cu3(BTC)2] (BTC=benzene-1,3,5-tricarboxylate), and IRMOF-3-SI-Au are active and reusable solid catalysts for the cyclopropanation of alkenes with high chemo- and diastereoselectivities. This type of material gives better results than previous solid catalysts while working together with the homogeneous catalysts. These MOFs can help to bridge the gap between homogeneous and heterogeneous catalysis.
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descriptionThe copper and gold metal-organic frameworks (MOFs) [Cu3(BTC)2(H2O)3]n, [Cu3(BTC)2] (BTC=benzene-1,3,5-tricarboxylate), and IRMOF-3-SI-Au are active and reusable solid catalysts for the cyclopropanation of alkenes with high chemo- and diastereoselectivities. This type of material gives better results than previous solid catalysts while working together with the homogeneous catalysts. These MOFs can help to bridge the gap between homogeneous and heterogeneous catalysis.
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abstractThe copper and gold metal-organic frameworks (MOFs) [Cu3(BTC)2(H2O)3]n, [Cu3(BTC)2] (BTC=benzene-1,3,5-tricarboxylate), and IRMOF-3-SI-Au are active and reusable solid catalysts for the cyclopropanation of alkenes with high chemo- and diastereoselectivities. This type of material gives better results than previous solid catalysts while working together with the homogeneous catalysts. These MOFs can help to bridge the gap between homogeneous and heterogeneous catalysis.
doi10.1002/chem.201000278
urlhttp://search.proquest.com/docview/1777991415/
date2010-08-23