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First Pre-Functionalised Polymeric Aromatic Framework from Mononitrotetrakis(iodophenyl)methane and its Applications

Starting from mononitrotetrakis(iodophenyl)methane as monomer, we report the preparation of the first pre-functionalised porous aromatic frameworks (PAFs) and their application as supports for organometallic catalysts. Neutral coordinate imino-pyridine Schiff base (PAF-NPy) or chiral bis-amino (PAF-... Full description

Journal Title: Chemistry: A European Journal April 2014, Vol.20(17), pp.5111-5120
Main Author: Verde-Sesto, Ester
Other Authors: Pintado-Sierra, Mercedes , Corma, Avelino , Maya, Eva , Delacampa, Jose , Iglesias, Marta , Sanchez, Felix
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 0947-6539 ; E-ISSN: 1521-3765 ; DOI: 10.1002/chem.201304163
Link: http://search.proquest.com/docview/1778009039/?pq-origsite=primo
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title: First Pre-Functionalised Polymeric Aromatic Framework from Mononitrotetrakis(iodophenyl)methane and its Applications
format: Article
creator:
  • Verde-Sesto, Ester
  • Pintado-Sierra, Mercedes
  • Corma, Avelino
  • Maya, Eva
  • Delacampa, Jose
  • Iglesias, Marta
  • Sanchez, Felix
subjects:
  • Monomers
  • Recycled
  • Catalysts
  • Selectivity
  • Schiff Bases
  • Metalorganic Compounds
  • Ligands
  • Catalysis
  • Analysis (MD)
  • Chemical Analysis (Ep)
  • Chemical Analysis (Ed)
  • Chemical Analysis (EC)
  • Cyclopropanation
  • Heterogeneous Catalysts
  • Porous Aromatic Frameworks
  • Recyclability
  • Supported Catalysts
ispartof: Chemistry: A European Journal, April 2014, Vol.20(17), pp.5111-5120
description: Starting from mononitrotetrakis(iodophenyl)methane as monomer, we report the preparation of the first pre-functionalised porous aromatic frameworks (PAFs) and their application as supports for organometallic catalysts. Neutral coordinate imino-pyridine Schiff base (PAF-NPy) or chiral bis-amino (PAF-NPro) ligands were obtained by post-synthetic treatment of PAF-NH sub(2) and treated with copper(I) or rhodium(I) to yield the corresponding supported transition-metal catalysts. The as-prepared PAF-NN-M catalysts exhibited activity and selectivity similar to that of the corresponding homogeneous catalysts and were easily removed from reaction media and recycled without loss of activity or selectivity. New copper catalysts: The preparation of pre-functionalised porous aromatic frameworks (PAFs) and their application as supports for organometallic catalysts (see figure) is reported for the first time.
language: eng
source:
identifier: ISSN: 0947-6539 ; E-ISSN: 1521-3765 ; DOI: 10.1002/chem.201304163
fulltext: fulltext
issn:
  • 09476539
  • 0947-6539
  • 15213765
  • 1521-3765
url: Link


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titleFirst Pre-Functionalised Polymeric Aromatic Framework from Mononitrotetrakis(iodophenyl)methane and its Applications
creatorVerde-Sesto, Ester ; Pintado-Sierra, Mercedes ; Corma, Avelino ; Maya, Eva ; Delacampa, Jose ; Iglesias, Marta ; Sanchez, Felix
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subjectMonomers ; Recycled ; Catalysts ; Selectivity ; Schiff Bases ; Metalorganic Compounds ; Ligands ; Catalysis ; Analysis (MD) ; Chemical Analysis (Ep) ; Chemical Analysis (Ed) ; Chemical Analysis (EC) ; Cyclopropanation ; Heterogeneous Catalysts ; Porous Aromatic Frameworks ; Recyclability ; Supported Catalysts
descriptionStarting from mononitrotetrakis(iodophenyl)methane as monomer, we report the preparation of the first pre-functionalised porous aromatic frameworks (PAFs) and their application as supports for organometallic catalysts. Neutral coordinate imino-pyridine Schiff base (PAF-NPy) or chiral bis-amino (PAF-NPro) ligands were obtained by post-synthetic treatment of PAF-NH sub(2) and treated with copper(I) or rhodium(I) to yield the corresponding supported transition-metal catalysts. The as-prepared PAF-NN-M catalysts exhibited activity and selectivity similar to that of the corresponding homogeneous catalysts and were easily removed from reaction media and recycled without loss of activity or selectivity. New copper catalysts: The preparation of pre-functionalised porous aromatic frameworks (PAFs) and their application as supports for organometallic catalysts (see figure) is reported for the first time.
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titleFirst Pre-Functionalised Polymeric Aromatic Framework from Mononitrotetrakis(iodophenyl)methane and its Applications
descriptionStarting from mononitrotetrakis(iodophenyl)methane as monomer, we report the preparation of the first pre-functionalised porous aromatic frameworks (PAFs) and their application as supports for organometallic catalysts. Neutral coordinate imino-pyridine Schiff base (PAF-NPy) or chiral bis-amino (PAF-NPro) ligands were obtained by post-synthetic treatment of PAF-NH sub(2) and treated with copper(I) or rhodium(I) to yield the corresponding supported transition-metal catalysts. The as-prepared PAF-NN-M catalysts exhibited activity and selectivity similar to that of the corresponding homogeneous catalysts and were easily removed from reaction media and recycled without loss of activity or selectivity. New copper catalysts: The preparation of pre-functionalised porous aromatic frameworks (PAFs) and their application as supports for organometallic catalysts (see figure) is reported for the first time.
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titleFirst Pre-Functionalised Polymeric Aromatic Framework from Mononitrotetrakis(iodophenyl)methane and its Applications
authorVerde-Sesto, Ester ; Pintado-Sierra, Mercedes ; Corma, Avelino ; Maya, Eva ; Delacampa, Jose ; Iglesias, Marta ; Sanchez, Felix
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abstractStarting from mononitrotetrakis(iodophenyl)methane as monomer, we report the preparation of the first pre-functionalised porous aromatic frameworks (PAFs) and their application as supports for organometallic catalysts. Neutral coordinate imino-pyridine Schiff base (PAF-NPy) or chiral bis-amino (PAF-NPro) ligands were obtained by post-synthetic treatment of PAF-NH sub(2) and treated with copper(I) or rhodium(I) to yield the corresponding supported transition-metal catalysts. The as-prepared PAF-NN-M catalysts exhibited activity and selectivity similar to that of the corresponding homogeneous catalysts and were easily removed from reaction media and recycled without loss of activity or selectivity. New copper catalysts: The preparation of pre-functionalised porous aromatic frameworks (PAFs) and their application as supports for organometallic catalysts (see figure) is reported for the first time.
doi10.1002/chem.201304163
urlhttp://search.proquest.com/docview/1778009039/
date2014-04-22