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Kinetic Resolution of Racemic Mandelic Acid Esters by N,N'-Dioxide-Scandi um-Complex-Catalyzed Enantiomer-Selective Acylation

A simple and efficient acylative kinetic resolution of racemic mandelic acid esters was accomplished with a chiral N,N'-dioxide-scandiu m(III) complex under mild and base-free reaction conditions. A variety of mandelic acid esters performed well in the reaction, obtaining...

Journal Title: Chemistry: A European Journal November 2014, Vol.20(48), pp.15884-15890
Main Author: Zhang, Yuheng
Other Authors: Liu, Xiaohua , Zhou, Lin , Wu, Wangbin , Huang, Tianyu , Liao, Yuting , Lin, Lili , Feng, Xiaoming
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 0947-6539 ; E-ISSN: 1521-3765 ; DOI: 10.1002/chem.201403242
Link: http://search.proquest.com/docview/1786181672/?pq-origsite=primo
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title: Kinetic Resolution of Racemic Mandelic Acid Esters by N,N'-Dioxide-Scandi um-Complex-Catalyzed Enantiomer-Selective Acylation
format: Article
creator:
  • Zhang, Yuheng
  • Liu, Xiaohua
  • Zhou, Lin
  • Wu, Wangbin
  • Huang, Tianyu
  • Liao, Yuting
  • Lin, Lili
  • Feng, Xiaoming
subjects:
  • Reaction Kinetics
  • Mathematical Models
  • Recognition
  • Catalysts
  • Esters
  • Selectivity
  • Materials Selection
  • Catalysis
  • Analysis (MD)
  • Chemical Analysis (Ep)
  • Chemical Analysis (Ed)
  • Chemical Analysis (EC)
ispartof: Chemistry: A European Journal, November 2014, Vol.20(48), pp.15884-15890
description: A simple and efficient acylative kinetic resolution of racemic mandelic acid esters was accomplished with a chiral N,N'-dioxide-scandiu m(III) complex under mild and base-free reaction conditions. A variety of mandelic acid esters performed well in the reaction, obtaining...
language: eng
source:
identifier: ISSN: 0947-6539 ; E-ISSN: 1521-3765 ; DOI: 10.1002/chem.201403242
fulltext: fulltext
issn:
  • 09476539
  • 0947-6539
  • 15213765
  • 1521-3765
url: Link


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titleKinetic Resolution of Racemic Mandelic Acid Esters by N,N'-Dioxide-Scandi um-Complex-Catalyzed Enantiomer-Selective Acylation
creatorZhang, Yuheng ; Liu, Xiaohua ; Zhou, Lin ; Wu, Wangbin ; Huang, Tianyu ; Liao, Yuting ; Lin, Lili ; Feng, Xiaoming
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subjectReaction Kinetics ; Mathematical Models ; Recognition ; Catalysts ; Esters ; Selectivity ; Materials Selection ; Catalysis ; Analysis (MD) ; Chemical Analysis (Ep) ; Chemical Analysis (Ed) ; Chemical Analysis (EC)
descriptionA simple and efficient acylative kinetic resolution of racemic mandelic acid esters was accomplished with a chiral N,N'-dioxide-scandiu m(III) complex under mild and base-free reaction conditions. A variety of mandelic acid esters performed well in the reaction, obtaining...
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abstractA simple and efficient acylative kinetic resolution of racemic mandelic acid esters was accomplished with a chiral N,N'-dioxide-scandiu m(III) complex under mild and base-free reaction conditions. A variety of mandelic acid esters performed well in the reaction, obtaining...
doi10.1002/chem.201403242
urlhttp://search.proquest.com/docview/1786181672/
date2014-11-24