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2-Pyridyl Sulfoxide: A Versatile and Removable Directing Group for the Pd super(II)-Catalyzed Direct C--H Olefination of Arenes

Removable and versatile: The 2-pyridylsulfinyl group has proved to be an efficient directing group in the Pd super(II)-catalyzed aryl ortho C--H olefination. This catalyst system enables the sequential double olefination to give asymmetrically di-ortho-functionalized arenes. The sulfinyl directing g... Full description

Journal Title: Chemistry: A European Journal March 2011, Vol.17(13), pp.3567-3570
Main Author: Garcia-Rubia, Alfonso
Other Authors: Fernandez-Ibanez, Mangeles , Gomezarrayas, Ramon , Carretero, Juan
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 0947-6539 ; E-ISSN: 1521-3765 ; DOI: 10.1002/chem.201003633
Link: http://search.proquest.com/docview/1800488061/?pq-origsite=primo
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title: 2-Pyridyl Sulfoxide: A Versatile and Removable Directing Group for the Pd super(II)-Catalyzed Direct C--H Olefination of Arenes
format: Article
creator:
  • Garcia-Rubia, Alfonso
  • Fernandez-Ibanez, Mangeles
  • Gomezarrayas, Ramon
  • Carretero, Juan
subjects:
  • Aromatic Compounds
  • Thiols
  • Asymmetry
  • Catalysts
  • Analysis (MD)
  • Chemical Analysis (Ep)
  • Chemical Analysis (Ed)
  • Chemical Analysis (EC)
ispartof: Chemistry: A European Journal, March 2011, Vol.17(13), pp.3567-3570
description: Removable and versatile: The 2-pyridylsulfinyl group has proved to be an efficient directing group in the Pd super(II)-catalyzed aryl ortho C--H olefination. This catalyst system enables the sequential double olefination to give asymmetrically di-ortho-functionalized arenes. The sulfinyl directing group can be easily cleaved, providing access to 1,3-disubstituted arenes, or transformed into a thiol group.
language: eng
source:
identifier: ISSN: 0947-6539 ; E-ISSN: 1521-3765 ; DOI: 10.1002/chem.201003633
fulltext: fulltext
issn:
  • 09476539
  • 0947-6539
  • 15213765
  • 1521-3765
url: Link


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creatorGarcia-Rubia, Alfonso ; Fernandez-Ibanez, Mangeles ; Gomezarrayas, Ramon ; Carretero, Juan
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subjectAromatic Compounds ; Thiols ; Asymmetry ; Catalysts ; Analysis (MD) ; Chemical Analysis (Ep) ; Chemical Analysis (Ed) ; Chemical Analysis (EC)
descriptionRemovable and versatile: The 2-pyridylsulfinyl group has proved to be an efficient directing group in the Pd super(II)-catalyzed aryl ortho C--H olefination. This catalyst system enables the sequential double olefination to give asymmetrically di-ortho-functionalized arenes. The sulfinyl directing group can be easily cleaved, providing access to 1,3-disubstituted arenes, or transformed into a thiol group.
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descriptionRemovable and versatile: The 2-pyridylsulfinyl group has proved to be an efficient directing group in the Pd super(II)-catalyzed aryl ortho C--H olefination. This catalyst system enables the sequential double olefination to give asymmetrically di-ortho-functionalized arenes. The sulfinyl directing group can be easily cleaved, providing access to 1,3-disubstituted arenes, or transformed into a thiol group.
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abstractRemovable and versatile: The 2-pyridylsulfinyl group has proved to be an efficient directing group in the Pd super(II)-catalyzed aryl ortho C--H olefination. This catalyst system enables the sequential double olefination to give asymmetrically di-ortho-functionalized arenes. The sulfinyl directing group can be easily cleaved, providing access to 1,3-disubstituted arenes, or transformed into a thiol group.
doi10.1002/chem.201003633
urlhttp://search.proquest.com/docview/1800488061/
date2011-03-21