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A Noncrystallization Approach toward Uniform Thylakoids-like 2D "Nano-coins" and Their Grana-like 3D Suprastructures.

Two-dimensional (2D) circular shape nanostructures (e.g., "nano-coins") are ubiquitously present in thylakoids and grana within chloroplasts of plant cells in nature. The design and fabrication of 2D nano-coins with controlled sizes and thicknesses yet remain challenging tasks. Herein, we present a... Full description

Journal Title: Journal of the American Chemical Society April 26, 2017, Vol.139(16), pp.5883-5889
Main Author: Lin, Zhiwei
Other Authors: Sun, Jian , Zhou, Yangbin , Wang, Yu , Xu, Hui , Yang, Xing , Su, Hao , Cui, Honggang , Aida, Takuzo , Zhang, Wei , Cheng, Stephen Z D
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1520-5126 ; DOI: 10.1021/jacs.7b01275
Link: http://search.proquest.com/docview/1885954885/?pq-origsite=primo
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title: A Noncrystallization Approach toward Uniform Thylakoids-like 2D "Nano-coins" and Their Grana-like 3D Suprastructures.
format: Article
creator:
  • Lin, Zhiwei
  • Sun, Jian
  • Zhou, Yangbin
  • Wang, Yu
  • Xu, Hui
  • Yang, Xing
  • Su, Hao
  • Cui, Honggang
  • Aida, Takuzo
  • Zhang, Wei
  • Cheng, Stephen Z D
subjects:
  • Colloids–Chemistry
  • Crystallization–Chemical Synthesis
  • Hydrogen-Ion Concentration–Chemistry
  • Macromolecular Substances–Chemistry
  • Molecular Structure–Chemistry
  • Nanostructures–Chemistry
  • Particle Size–Chemistry
  • Solvents–Chemistry
  • Surface Properties–Chemistry
  • Thylakoids–Chemistry
  • Colloids
  • Macromolecular Substances
  • Solvents
ispartof: Journal of the American Chemical Society, April 26, 2017, Vol.139(16), pp.5883-5889
description: Two-dimensional (2D) circular shape nanostructures (e.g., "nano-coins") are ubiquitously present in thylakoids and grana within chloroplasts of plant cells in nature. The design and fabrication of 2D nano-coins with controlled sizes and thicknesses yet remain challenging tasks. Herein, we present a noncrystallization approach to achieve 2D nano-coins from assemblies of a set of zwitterionic giant surfactants. Distinguished from traditional crystallization approaches where the 2D nanostructures with specific crystallographic symmetries are fabricated, the noncrystallization assembly of giant surfactants results in 2D nano-coins that are derived from the separation of assembled 3D multiple lamellar cylindrical colloids with uniform diameters. The diameters and thicknesses of these nano-coins can be readily tailored by varying the molecular length of giant surfactants' tails. The formation of 2D nano-coins or 3D cylindrical colloid suprastructures is controlled by tuning the pH value of added...
language: eng
source:
identifier: E-ISSN: 1520-5126 ; DOI: 10.1021/jacs.7b01275
fulltext: fulltext
issn:
  • 15205126
  • 1520-5126
url: Link


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titleA Noncrystallization Approach toward Uniform Thylakoids-like 2D "Nano-coins" and Their Grana-like 3D Suprastructures.
creatorLin, Zhiwei ; Sun, Jian ; Zhou, Yangbin ; Wang, Yu ; Xu, Hui ; Yang, Xing ; Su, Hao ; Cui, Honggang ; Aida, Takuzo ; Zhang, Wei ; Cheng, Stephen Z D
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identifierE-ISSN: 1520-5126 ; DOI: 10.1021/jacs.7b01275
subjectColloids–Chemistry ; Crystallization–Chemical Synthesis ; Hydrogen-Ion Concentration–Chemistry ; Macromolecular Substances–Chemistry ; Molecular Structure–Chemistry ; Nanostructures–Chemistry ; Particle Size–Chemistry ; Solvents–Chemistry ; Surface Properties–Chemistry ; Thylakoids–Chemistry ; Colloids ; Macromolecular Substances ; Solvents
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descriptionTwo-dimensional (2D) circular shape nanostructures (e.g., "nano-coins") are ubiquitously present in thylakoids and grana within chloroplasts of plant cells in nature. The design and fabrication of 2D nano-coins with controlled sizes and thicknesses yet remain challenging tasks. Herein, we present a noncrystallization approach to achieve 2D nano-coins from assemblies of a set of zwitterionic giant surfactants. Distinguished from traditional crystallization approaches where the 2D nanostructures with specific crystallographic symmetries are fabricated, the noncrystallization assembly of giant surfactants results in 2D nano-coins that are derived from the separation of assembled 3D multiple lamellar cylindrical colloids with uniform diameters. The diameters and thicknesses of these nano-coins can be readily tailored by varying the molecular length of giant surfactants' tails. The formation of 2D nano-coins or 3D cylindrical colloid suprastructures is controlled by tuning the pH value of added...
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