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Modulation of the Coordination Environment around the Magnetic Easy Axis Leads to Significant Magnetic Relaxations in a Series of 3d-4f Schiff Complexes.

A series of Salen-type Zn­(II)–Dy­(III) complexes [L1Zn­(II)­ClDy­(III)­(acac)2]­·H2O (1), [L1Zn­(II)­BrDy­(III)­(acac)2]­·H2O (2), [L1Zn­(II)­(H2O)­Dy­(III)­(acac)2]­·CH2Cl2·PF6 (3), [L2Zn­(II)­(H2O)­Dy­(III)­(acac)2]­·PF6 (4), and Co­(III)–Dy­(III) complexes [L1Co­(III)­Br2Dy­(III)­(acac)2]·CH2Cl2... Full description

Journal Title: Inorganic chemistry July 16, 2018, Vol.57(14), pp.8065-8077
Main Author: Yang, Jing-Wei
Other Authors: Tian, Yong-Mei , Tao, Jin , Chen, Peng , Li, Hong-Feng , Zhang, Yi-Quan , Yan, Peng-Fei , Sun, Wen-Bin
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1520-510X ; DOI: 10.1021/acs.inorgchem.8b00056
Link: http://search.proquest.com/docview/2063715834/?pq-origsite=primo
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title: Modulation of the Coordination Environment around the Magnetic Easy Axis Leads to Significant Magnetic Relaxations in a Series of 3d-4f Schiff Complexes.
format: Article
creator:
  • Yang, Jing-Wei
  • Tian, Yong-Mei
  • Tao, Jin
  • Chen, Peng
  • Li, Hong-Feng
  • Zhang, Yi-Quan
  • Yan, Peng-Fei
  • Sun, Wen-Bin
subjects:
  • Chemistry
ispartof: Inorganic chemistry, July 16, 2018, Vol.57(14), pp.8065-8077
description: A series of Salen-type Zn­(II)–Dy­(III) complexes [L1Zn­(II)­ClDy­(III)­(acac)2]­·H2O (1), [L1Zn­(II)­BrDy­(III)­(acac)2]­·H2O (2), [L1Zn­(II)­(H2O)­Dy­(III)­(acac)2]­·CH2Cl2·PF6 (3), [L2Zn­(II)­(H2O)­Dy­(III)­(acac)2]­·PF6 (4), and Co­(III)–Dy­(III) complexes [L1Co­(III)­Br2Dy­(III)­(acac)2]·CH2Cl2 (5), [L2Co­(III)­Cl2Dy­(III)­(acac)­Cl­(MeO)] (6), [L2Co­(III)­Cl2Dy­(III)­(acac)­Cl­(H2O)] (7), and [L2Co­(III)­Cl2Dy­(III)­(NO3)2­(MeO)] (8) heterobinuclear single-molecule magnets (SMMs) were synthesized and magnetically characterized. These complexes were constructed by incorporating diamagnetic Zn­(II) and Co­(III) ions with acetylacetone (acac) and compartmental Schiff-base ligands (H2L1 = N,N′-bis­(2-oxy-3-methoxybenzylidene)-1,2-phenylenediamine; H2L2 = N,N′-bis­(2-oxy-3-methoxybenzylidene)-1,2-diaminocyclohexane). In the Zn­(II)–Dy­(III) (1–4) system, the coordination environments of the Dy­(III) ions are nearly identical, but the apical coordination atom to the Zn­(II) ion...
language: eng
source:
identifier: E-ISSN: 1520-510X ; DOI: 10.1021/acs.inorgchem.8b00056
fulltext: fulltext
issn:
  • 1520510X
  • 1520-510X
url: Link


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titleModulation of the Coordination Environment around the Magnetic Easy Axis Leads to Significant Magnetic Relaxations in a Series of 3d-4f Schiff Complexes.
creatorYang, Jing-Wei ; Tian, Yong-Mei ; Tao, Jin ; Chen, Peng ; Li, Hong-Feng ; Zhang, Yi-Quan ; Yan, Peng-Fei ; Sun, Wen-Bin
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ispartofInorganic chemistry, July 16, 2018, Vol.57(14), pp.8065-8077
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descriptionA series of Salen-type Zn­(II)–Dy­(III) complexes [L1Zn­(II)­ClDy­(III)­(acac)2]­·H2O (1), [L1Zn­(II)­BrDy­(III)­(acac)2]­·H2O (2), [L1Zn­(II)­(H2O)­Dy­(III)­(acac)2]­·CH2Cl2·PF6 (3), [L2Zn­(II)­(H2O)­Dy­(III)­(acac)2]­·PF6 (4), and Co­(III)–Dy­(III) complexes [L1Co­(III)­Br2Dy­(III)­(acac)2]·CH2Cl2 (5), [L2Co­(III)­Cl2Dy­(III)­(acac)­Cl­(MeO)] (6), [L2Co­(III)­Cl2Dy­(III)­(acac)­Cl­(H2O)] (7), and [L2Co­(III)­Cl2Dy­(III)­(NO3)2­(MeO)] (8) heterobinuclear single-molecule magnets (SMMs) were synthesized and magnetically characterized. These complexes were constructed by incorporating diamagnetic Zn­(II) and Co­(III) ions with acetylacetone (acac) and compartmental Schiff-base ligands (H2L1 = N,N′-bis­(2-oxy-3-methoxybenzylidene)-1,2-phenylenediamine; H2L2 = N,N′-bis­(2-oxy-3-methoxybenzylidene)-1,2-diaminocyclohexane). In the Zn­(II)–Dy­(III) (1–4) system, the coordination environments of the Dy­(III) ions are nearly identical, but the apical coordination atom to the Zn­(II) ion...
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