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Electrophile-directed diastereoselective alkylation of prochiral enediolates.

The article describes a new approach for constructing quaternary [alpha]-hydroxy carboxylic derivatives. This method has used electrophile-directed diastereoselective alkylation of prochiral enolates with chiral primary and secondary protected iodohydrins.

Journal Title: Journal of the American Chemical Society October 24, 2007, Vol.129(42), pp.12600-12601
Main Author: Marsden, Stephen P
Other Authors: Newton, Rebecca
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 0002-7863
Link: http://search.proquest.com/docview/68401005/?pq-origsite=primo
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recordid: proquest68401005
title: Electrophile-directed diastereoselective alkylation of prochiral enediolates.
format: Article
creator:
  • Marsden, Stephen P
  • Newton, Rebecca
subjects:
  • Alkylation–Chemistry
  • Amides–Methods
  • Chemistry–Methods
  • Chemistry, Organic–Methods
  • Crystallography, X-Ray–Chemistry
  • Dimerization–Chemistry
  • Esters–Chemistry
  • Lactones–Chemistry
  • Models, Chemical–Chemistry
  • Molecular Conformation–Chemistry
  • Oxygen–Chemistry
  • Stereoisomerism–Chemistry
  • Time Factors–Chemistry
  • Amides
  • Esters
  • Lactones
  • Cinatrin B
  • Oxygen
ispartof: Journal of the American Chemical Society, October 24, 2007, Vol.129(42), pp.12600-12601
description: The article describes a new approach for constructing quaternary [alpha]-hydroxy carboxylic derivatives. This method has used electrophile-directed diastereoselective alkylation of prochiral enolates with chiral primary and secondary protected iodohydrins.
language: eng
source:
identifier: ISSN: 0002-7863
fulltext: fulltext
issn:
  • 00027863
  • 0002-7863
url: Link


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subjectAlkylation–Chemistry ; Amides–Methods ; Chemistry–Methods ; Chemistry, Organic–Methods ; Crystallography, X-Ray–Chemistry ; Dimerization–Chemistry ; Esters–Chemistry ; Lactones–Chemistry ; Models, Chemical–Chemistry ; Molecular Conformation–Chemistry ; Oxygen–Chemistry ; Stereoisomerism–Chemistry ; Time Factors–Chemistry ; Amides ; Esters ; Lactones ; Cinatrin B ; Oxygen
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descriptionThe article describes a new approach for constructing quaternary [alpha]-hydroxy carboxylic derivatives. This method has used electrophile-directed diastereoselective alkylation of prochiral enolates with chiral primary and secondary protected iodohydrins.
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