schliessen

Filtern

 

Bibliotheken

Synthesis of monocarbenepalladium(0) complexes and their catalytic behavior in cross-coupling reactions of aryldiazonium salts.

The first monocarbenepalladium(0) complexes with benzoquinone and naphthoquinone as additional ligands have been prepared. As demonstrated by NMR spectroscopy and X‐ray analysis, the complexes show a unique coordination mode giving quinone‐bridged dimers. The monocarbenepalladium(0) complexes allow... Full description

Journal Title: Chemistry (Weinheim an der Bergstrasse Germany), September 2, 2002, Vol.8(17), pp.3901-3906
Main Author: Selvakumar, Kumaravel
Other Authors: Zapf, Alexander , Spannenberg, Anke , Beller, Matthias
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 0947-6539
Link: http://search.proquest.com/docview/72134906/?pq-origsite=primo
Zum Text:
SendSend as email Add to Book BagAdd to Book Bag
Staff View
recordid: proquest72134906
title: Synthesis of monocarbenepalladium(0) complexes and their catalytic behavior in cross-coupling reactions of aryldiazonium salts.
format: Article
creator:
  • Selvakumar, Kumaravel
  • Zapf, Alexander
  • Spannenberg, Anke
  • Beller, Matthias
subjects:
  • Carbenes
  • Heck Reaction
  • Homogeneous Catalysis
  • Palladium
  • Suzuki Reaction
  • Chemistry
ispartof: Chemistry (Weinheim an der Bergstrasse, Germany), September 2, 2002, Vol.8(17), pp.3901-3906
description: The first monocarbenepalladium(0) complexes with benzoquinone and naphthoquinone as additional ligands have been prepared. As demonstrated by NMR spectroscopy and X‐ray analysis, the complexes show a unique coordination mode giving quinone‐bridged dimers. The monocarbenepalladium(0) complexes allow efficient cross‐coupling reactions of aryldiazonium salts with olefins (Heck reaction) and arylboronic acids (Suzuki reaction). Monocarbenepalladium(0)quinone complexes, such as 1, have been prepared and tested for the first time in Heck and Suzuki reactions of aryldiazonium salts.
language: eng
source:
identifier: ISSN: 0947-6539
fulltext: fulltext
issn:
  • 09476539
  • 0947-6539
url: Link


@attributes
ID1764705308
RANK0.07
NO1
SEARCH_ENGINEprimo_central_multiple_fe
SEARCH_ENGINE_TYPEPrimo Central Search Engine
LOCALfalse
PrimoNMBib
record
control
sourcerecordid72134906
sourceidproquest
recordidTN_proquest72134906
sourcesystemPC
pqid72134906
display
typearticle
titleSynthesis of monocarbenepalladium(0) complexes and their catalytic behavior in cross-coupling reactions of aryldiazonium salts.
creatorSelvakumar, Kumaravel ; Zapf, Alexander ; Spannenberg, Anke ; Beller, Matthias
contributorSelvakumar, Kumaravel (correspondence author) ; Selvakumar, Kumaravel (record owner)
ispartofChemistry (Weinheim an der Bergstrasse, Germany), September 2, 2002, Vol.8(17), pp.3901-3906
identifierISSN: 0947-6539
languageeng
source
subjectCarbenes ; Heck Reaction ; Homogeneous Catalysis ; Palladium ; Suzuki Reaction ; Chemistry;
descriptionThe first monocarbenepalladium(0) complexes with benzoquinone and naphthoquinone as additional ligands have been prepared. As demonstrated by NMR spectroscopy and X‐ray analysis, the complexes show a unique coordination mode giving quinone‐bridged dimers. The monocarbenepalladium(0) complexes allow efficient cross‐coupling reactions of aryldiazonium salts with olefins (Heck reaction) and arylboronic acids (Suzuki reaction). Monocarbenepalladium(0)quinone complexes, such as 1, have been prepared and tested for the first time in Heck and Suzuki reactions of aryldiazonium salts.
version4
lds50peer_reviewed
links
openurl$$Topenurl_article
openurlfulltext$$Topenurlfull_article
backlink$$Uhttp://search.proquest.com/docview/72134906/?pq-origsite=primo$$EView_record_in_ProQuest_(subscribers_only)
search
creatorcontrib
0Selvakumar, Kumaravel
1Zapf, Alexander
2Spannenberg, Anke
3Beller, Matthias
titleSynthesis of monocarbenepalladium(0) complexes and their catalytic behavior in cross-coupling reactions of aryldiazonium salts.
general
0English
1MEDLINE (ProQuest)
2ProQuest Biological Science Collection
3ProQuest Natural Science Collection
4ProQuest SciTech Collection
5Biological Science Database
6Natural Science Collection
7SciTech Premium Collection
8Health Research Premium Collection
9Health Research Premium Collection (Alumni edition)
10Biological Science Index (ProQuest)
sourceidproquest
recordidproquest72134906
issn
009476539
10947-6539
rsrctypearticle
creationdate2002
addtitleChemistry (Weinheim an der Bergstrasse, Germany)
searchscope
01007527
11007944
21009130
310000004
410000038
510000050
610000120
710000159
810000238
910000253
1010000260
1110000270
1210000271
1310000302
1410000350
15proquest
scope
01007527
11007944
21009130
310000004
410000038
510000050
610000120
710000159
810000238
910000253
1010000260
1110000270
1210000271
1310000302
1410000350
15proquest
lsr43
01007527false
11007944false
21009130false
310000004false
410000038false
510000050false
610000120false
710000159false
810000238false
910000253false
1010000260false
1110000270false
1210000271false
1310000302false
1410000350false
contributorSelvakumar, Kumaravel
startdate20020902
enddate20020902
citationpf 3901 pt 3906 vol 8 issue 17
lsr30VSR-Enriched:[pqid, doi, eissn, subject, description]
sort
titleSynthesis of monocarbenepalladium(0) complexes and their catalytic behavior in cross-coupling reactions of aryldiazonium salts.
authorSelvakumar, Kumaravel ; Zapf, Alexander ; Spannenberg, Anke ; Beller, Matthias
creationdate20020902
lso0120020902
facets
frbrgroupid7605275525339312882
frbrtype5
newrecords20181218
languageeng
creationdate2002
collection
0MEDLINE (ProQuest)
1ProQuest Biological Science Collection
2ProQuest Natural Science Collection
3ProQuest SciTech Collection
4Biological Science Database
5Natural Science Collection
6SciTech Premium Collection
7Health Research Premium Collection
8Health Research Premium Collection (Alumni edition)
9Biological Science Index (ProQuest)
prefilterarticles
rsrctypearticles
creatorcontrib
0Selvakumar, Kumaravel
1Zapf, Alexander
2Spannenberg, Anke
3Beller, Matthias
jtitleChemistry (Weinheim an der Bergstrasse, Germany)
toplevelpeer_reviewed
delivery
delcategoryRemote Search Resource
fulltextfulltext
addata
aulast
0Selvakumar
1Zapf
2Spannenberg
3Beller
aufirst
0Kumaravel
1Alexander
2Anke
3Matthias
au
0Selvakumar, Kumaravel
1Zapf, Alexander
2Spannenberg, Anke
3Beller, Matthias
addauSelvakumar, Kumaravel
atitleSynthesis of monocarbenepalladium(0) complexes and their catalytic behavior in cross-coupling reactions of aryldiazonium salts.
jtitleChemistry (Weinheim an der Bergstrasse, Germany)
risdate20020902
volume8
issue17
spage3901
epage3906
pages3901-3906
issn0947-6539
formatjournal
genrearticle
ristypeJOUR
urlhttp://search.proquest.com/docview/72134906/
doi10.1002/1521-3765(20020902)8:17<3901::AID-CHEM3901>3.0.CO;2-E
eissn15213765
date2002-09-02