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Copper catalyzed arylation/C-C bond activation: an approach toward alpha-aryl ketones.

An efficient arylation/C-C activation process is described and [beta]-diketones with aryl halides (aryl iodides and aryl bromides) have undergone reaction in the presence of Cu(I) or Cu(II) salts in DMSO by using [K.sub.3]P[O.sub.4].3[H.sub.2]O without ligands. This novel method is used for preparin... Full description

Journal Title: Journal of the American Chemical Society June 23, 2010, Vol.132(24), pp.8273-8275
Main Author: He, Chuan
Other Authors: Guo, Sheng , Huang, Li , Lei, Aiwen
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1520-5126 ; DOI: 10.1021/ja1033777
Link: http://search.proquest.com/docview/733347221/?pq-origsite=primo
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recordid: proquest733347221
title: Copper catalyzed arylation/C-C bond activation: an approach toward alpha-aryl ketones.
format: Article
creator:
  • He, Chuan
  • Guo, Sheng
  • Huang, Li
  • Lei, Aiwen
subjects:
  • Arylation -- Analysis
  • Catalysis -- Analysis
  • Copper (Metal) -- Atomic Properties
  • Copper (Metal) -- Chemical Properties
  • Dimethyl Sulfoxide -- Chemical Properties
  • Ketones -- Chemical Properties
ispartof: Journal of the American Chemical Society, June 23, 2010, Vol.132(24), pp.8273-8275
description: An efficient arylation/C-C activation process is described and [beta]-diketones with aryl halides (aryl iodides and aryl bromides) have undergone reaction in the presence of Cu(I) or Cu(II) salts in DMSO by using [K.sub.3]P[O.sub.4].3[H.sub.2]O without ligands. This novel method is used for preparing various [alpha]-aryl ketones.
language: eng
source:
identifier: E-ISSN: 1520-5126 ; DOI: 10.1021/ja1033777
fulltext: fulltext
issn:
  • 15205126
  • 1520-5126
url: Link


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titleCopper catalyzed arylation/C-C bond activation: an approach toward alpha-aryl ketones.
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descriptionAn efficient arylation/C-C activation process is described and [beta]-diketones with aryl halides (aryl iodides and aryl bromides) have undergone reaction in the presence of Cu(I) or Cu(II) salts in DMSO by using [K.sub.3]P[O.sub.4].3[H.sub.2]O without ligands. This novel method is used for preparing various [alpha]-aryl ketones.
subjectArylation -- Analysis ; Catalysis -- Analysis ; Copper (Metal) -- Atomic Properties ; Copper (Metal) -- Chemical Properties ; Dimethyl Sulfoxide -- Chemical Properties ; Ketones -- Chemical Properties;
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