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Porous metal carboxylate boron imidazolate frameworks.

Metal-organic frameworks (MOFs) have attracted considerable interest because of their intriguing structures and potential applications. Of particular importance is the design and synthesis of MOFs with novel composition and topology, because properties and applications of such materials depend on th... Full description

Journal Title: Angewandte Chemie (International ed. in English) July 19, 2010, Vol.49(31), pp.5362-5366
Main Author: Zheng, Shoutian
Other Authors: Wu, Tao , Zhang, Jian , Chow, Mina , Nieto, Ruben A , Feng, Pingyun , Bu, Xianhui
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1521-3773 ; DOI: 10.1002/anie.201001675
Link: http://search.proquest.com/docview/749006518/?pq-origsite=primo
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recordid: proquest749006518
title: Porous metal carboxylate boron imidazolate frameworks.
format: Article
creator:
  • Zheng, Shoutian
  • Wu, Tao
  • Zhang, Jian
  • Chow, Mina
  • Nieto, Ruben A
  • Feng, Pingyun
  • Bu, Xianhui
subjects:
  • Boron Compounds–Chemistry
  • Carboxylic Acids–Chemistry
  • Imidazoles–Chemistry
  • Metals–Chemistry
  • Models, Molecular–Chemistry
  • Organometallic Compounds–Chemistry
  • Porosity–Chemistry
  • Boron Compounds
  • Carboxylic Acids
  • Imidazoles
  • Metals
  • Organometallic Compounds
ispartof: Angewandte Chemie (International ed. in English), July 19, 2010, Vol.49(31), pp.5362-5366
description: Metal-organic frameworks (MOFs) have attracted considerable interest because of their intriguing structures and potential applications. Of particular importance is the design and synthesis of MOFs with novel composition and topology, because properties and applications of such materials depend on their composition and topology. Among MOFs, metal-carboxylate frameworks (MCFs) constitute one of the most important subclasses. A new family of porous materials with tunable gas sorption properties has been prepared by integrating metal carboxylates and boron imidazolates under hydro- or solvothermal conditions. One hydrothermally synthesized phase exhibits very high volumetric CO2 storage capacity of 81 L L-1 (273 K, 1 atm).
language: eng
source:
identifier: E-ISSN: 1521-3773 ; DOI: 10.1002/anie.201001675
fulltext: fulltext
issn:
  • 15213773
  • 1521-3773
url: Link


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titlePorous metal carboxylate boron imidazolate frameworks.
creatorZheng, Shoutian ; Wu, Tao ; Zhang, Jian ; Chow, Mina ; Nieto, Ruben A ; Feng, Pingyun ; Bu, Xianhui
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identifierE-ISSN: 1521-3773 ; DOI: 10.1002/anie.201001675
subjectBoron Compounds–Chemistry ; Carboxylic Acids–Chemistry ; Imidazoles–Chemistry ; Metals–Chemistry ; Models, Molecular–Chemistry ; Organometallic Compounds–Chemistry ; Porosity–Chemistry ; Boron Compounds ; Carboxylic Acids ; Imidazoles ; Metals ; Organometallic Compounds
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descriptionMetal-organic frameworks (MOFs) have attracted considerable interest because of their intriguing structures and potential applications. Of particular importance is the design and synthesis of MOFs with novel composition and topology, because properties and applications of such materials depend on their composition and topology. Among MOFs, metal-carboxylate frameworks (MCFs) constitute one of the most important subclasses. A new family of porous materials with tunable gas sorption properties has been prepared by integrating metal carboxylates and boron imidazolates under hydro- or solvothermal conditions. One hydrothermally synthesized phase exhibits very high volumetric CO2 storage capacity of 81 L L-1 (273 K, 1 atm).
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