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Oxygen evolution from BF3/MnO4-.

MnO(4)(-) is activated by BF(3) to undergo intramolecular coupling of two oxo ligands to generate O(2). DFT calculations suggest that there should be a spin intercrossing between the singlet and triplet potential energy surfaces on going from the active intermediate [MnO(2)(OBF(3))(2)](-) to the O··... Full description

Journal Title: Chemical communications (Cambridge England), April 14, 2011, Vol.47(14), pp.4159-4161
Main Author: Yiu, Shek-Man
Other Authors: Man, Wai-Lun , Wang, Xin , Lam, William W Y , Ng, Siu-Mui , Kwong, Hoi-Ki , Lau, Kai-Chung , Lau, Tai-Chu
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1364-548X ; DOI: 10.1039/c1cc00019e
Link: http://search.proquest.com/docview/858282880/?pq-origsite=primo
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recordid: proquest858282880
title: Oxygen evolution from BF3/MnO4-.
format: Article
creator:
  • Yiu, Shek-Man
  • Man, Wai-Lun
  • Wang, Xin
  • Lam, William W Y
  • Ng, Siu-Mui
  • Kwong, Hoi-Ki
  • Lau, Kai-Chung
  • Lau, Tai-Chu
subjects:
  • Acetonitriles–Chemistry
  • Borates–Chemistry
  • Kinetics–Chemistry
  • Manganese Compounds–Chemistry
  • Oxidation-Reduction–Chemistry
  • Oxides–Chemistry
  • Oxygen–Chemistry
  • Thermodynamics–Chemistry
  • Acetonitriles
  • Borates
  • Manganese Compounds
  • Oxides
  • Manganese Oxide
  • Fluoroboric Acid
  • Oxygen
ispartof: Chemical communications (Cambridge, England), April 14, 2011, Vol.47(14), pp.4159-4161
description: MnO(4)(-) is activated by BF(3) to undergo intramolecular coupling of two oxo ligands to generate O(2). DFT calculations suggest that there should be a spin intercrossing between the singlet and triplet potential energy surfaces on going from the active intermediate [MnO(2)(OBF(3))(2)](-) to the O···O coupling transition state.
language: eng
source:
identifier: E-ISSN: 1364-548X ; DOI: 10.1039/c1cc00019e
fulltext: fulltext
issn:
  • 1364548X
  • 1364-548X
url: Link


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titleOxygen evolution from BF3/MnO4-.
creatorYiu, Shek-Man ; Man, Wai-Lun ; Wang, Xin ; Lam, William W Y ; Ng, Siu-Mui ; Kwong, Hoi-Ki ; Lau, Kai-Chung ; Lau, Tai-Chu
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ispartofChemical communications (Cambridge, England), April 14, 2011, Vol.47(14), pp.4159-4161
identifierE-ISSN: 1364-548X ; DOI: 10.1039/c1cc00019e
subjectAcetonitriles–Chemistry ; Borates–Chemistry ; Kinetics–Chemistry ; Manganese Compounds–Chemistry ; Oxidation-Reduction–Chemistry ; Oxides–Chemistry ; Oxygen–Chemistry ; Thermodynamics–Chemistry ; Acetonitriles ; Borates ; Manganese Compounds ; Oxides ; Manganese Oxide ; Fluoroboric Acid ; Oxygen
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descriptionMnO(4)(-) is activated by BF(3) to undergo intramolecular coupling of two oxo ligands to generate O(2). DFT calculations suggest that there should be a spin intercrossing between the singlet and triplet potential energy surfaces on going from the active intermediate [MnO(2)(OBF(3))(2)](-) to the O···O coupling transition state.
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titleOxygen evolution from BF3/MnO4-.
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