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Theory-guided experiments on the mechanistic elucidation of the reduction of dinuclear zinc, manganese, and cadmium complexes.

Two MnMn‐bonded dimanganese complexes , as well as the tetracadmium complex shown in the picture, were obtained by reduction of [M 2 {μ‐κ 2 ‐Me 2 Si(NDipp) 2 } 2 ] (M=Mn, Cd; Dipp=2,6‐ i Pr 2 C 6 H 3 ). Their structures are consistent with those of calculated intermediates in the reduction of [Zn 2... Full description

Journal Title: Angewandte Chemie (International ed. in English) August 8, 2011, Vol.50(33), pp.7611-7615
Main Author: Lu, Duan-Yen
Other Authors: Yu, Jen-Shiang K , Kuo, Ting-Shen , Lee, Gene-Hsiang , Wang, Yu , Tsai, Yi-Chou
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1521-3773 ; DOI: 10.1002/anie.201102296
Link: http://search.proquest.com/docview/881473533/?pq-origsite=primo
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title: Theory-guided experiments on the mechanistic elucidation of the reduction of dinuclear zinc, manganese, and cadmium complexes.
format: Article
creator:
  • Lu, Duan-Yen
  • Yu, Jen-Shiang K
  • Kuo, Ting-Shen
  • Lee, Gene-Hsiang
  • Wang, Yu
  • Tsai, Yi-Chou
subjects:
  • Cadmium–Chemistry
  • Crystallography, X-Ray–Chemistry
  • Manganese–Chemical Synthesis
  • Models, Molecular–Chemistry
  • Molecular Structure–Chemistry
  • Organometallic Compounds–Chemistry
  • Oxidation-Reduction–Chemistry
  • Quantum Theory–Chemistry
  • Stereoisomerism–Chemistry
  • Zinc–Chemistry
  • Organometallic Compounds
  • Cadmium
  • Manganese
  • Zinc
ispartof: Angewandte Chemie (International ed. in English), August 8, 2011, Vol.50(33), pp.7611-7615
description: Two MnMn‐bonded dimanganese complexes , as well as the tetracadmium complex shown in the picture, were obtained by reduction of [M 2 {μ‐κ 2 ‐Me 2 Si(NDipp) 2 } 2 ] (M=Mn, Cd; Dipp=2,6‐ i Pr 2 C 6 H 3 ). Their structures are consistent with those of calculated intermediates in the reduction of [Zn 2 {μ‐κ 2 ‐Me 2 Si(NDipp) 2 } 2 ].
language: eng
source:
identifier: E-ISSN: 1521-3773 ; DOI: 10.1002/anie.201102296
fulltext: fulltext
issn:
  • 15213773
  • 1521-3773
url: Link


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titleTheory-guided experiments on the mechanistic elucidation of the reduction of dinuclear zinc, manganese, and cadmium complexes.
creatorLu, Duan-Yen ; Yu, Jen-Shiang K ; Kuo, Ting-Shen ; Lee, Gene-Hsiang ; Wang, Yu ; Tsai, Yi-Chou
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ispartofAngewandte Chemie (International ed. in English), August 8, 2011, Vol.50(33), pp.7611-7615
identifierE-ISSN: 1521-3773 ; DOI: 10.1002/anie.201102296
subjectCadmium–Chemistry ; Crystallography, X-Ray–Chemistry ; Manganese–Chemical Synthesis ; Models, Molecular–Chemistry ; Molecular Structure–Chemistry ; Organometallic Compounds–Chemistry ; Oxidation-Reduction–Chemistry ; Quantum Theory–Chemistry ; Stereoisomerism–Chemistry ; Zinc–Chemistry ; Organometallic Compounds ; Cadmium ; Manganese ; Zinc
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descriptionTwo MnMn‐bonded dimanganese complexes , as well as the tetracadmium complex shown in the picture, were obtained by reduction of [M 2 {μ‐κ 2 ‐Me 2 Si(NDipp) 2 } 2 ] (M=Mn, Cd; Dipp=2,6‐ i Pr 2 C 6 H 3 ). Their structures are consistent with those of calculated intermediates in the reduction of [Zn 2 {μ‐κ 2 ‐Me 2 Si(NDipp) 2 } 2 ].
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titleTheory-guided experiments on the mechanistic elucidation of the reduction of dinuclear zinc, manganese, and cadmium complexes.
authorLu, Duan-Yen ; Yu, Jen-Shiang K ; Kuo, Ting-Shen ; Lee, Gene-Hsiang ; Wang, Yu ; Tsai, Yi-Chou
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