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Copper-catalyzed trifluoromethylation of unactivated olefins.

In conclusion, we have developed an allylic trifluoromethylation of unactivated terminal olefins. This method allows for the preparation of allyl-CF3 products that were previously difficult to access in a straightforward and efficient manner. The mild conditions for this transformation enable the tr... Full description

Journal Title: Angewandte Chemie (International ed. in English) September 19, 2011, Vol.50(39), pp.9120-9123
Main Author: Parsons, Andrew T
Other Authors: Buchwald, Stephen L
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1521-3773 ; DOI: 1521-3773 ; DOI: 10.1002/anie.201104053
Link: http://search.proquest.com/docview/890678359/?pq-origsite=primo
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recordid: proquest890678359
title: Copper-catalyzed trifluoromethylation of unactivated olefins.
format: Article
creator:
  • Parsons, Andrew T
  • Buchwald, Stephen L
subjects:
  • Alkenes–Chemistry
  • Amination–Chemistry
  • Catalysis–Chemistry
  • Copper–Chemistry
  • Fluorine–Chemistry
  • Oxidation-Reduction–Chemistry
  • Stereoisomerism–Chemistry
  • Alkenes
  • Fluorine
  • Copper
ispartof: Angewandte Chemie (International ed. in English), September 19, 2011, Vol.50(39), pp.9120-9123
description: In conclusion, we have developed an allylic trifluoromethylation of unactivated terminal olefins. This method allows for the preparation of allyl-CF3 products that were previously difficult to access in a straightforward and efficient manner. The mild conditions for this transformation enable the trifluoromethylation of a range of substrates that bear numerous functional groups. A preliminary analysis suggests that the reaction mechanism is complex and multiple pathways leading to the desired allyl-CF3 products may be operating. Future efforts will focus on examining the mechanistic details more extensively on the way to expanding the generality and increasing the efficiency of this transformation.
language: eng
source:
identifier: E-ISSN: 1521-3773 ; DOI: 1521-3773 ; DOI: 10.1002/anie.201104053
fulltext: fulltext
issn:
  • 15213773
  • 1521-3773
url: Link


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descriptionIn conclusion, we have developed an allylic trifluoromethylation of unactivated terminal olefins. This method allows for the preparation of allyl-CF3 products that were previously difficult to access in a straightforward and efficient manner. The mild conditions for this transformation enable the trifluoromethylation of a range of substrates that bear numerous functional groups. A preliminary analysis suggests that the reaction mechanism is complex and multiple pathways leading to the desired allyl-CF3 products may be operating. Future efforts will focus on examining the mechanistic details more extensively on the way to expanding the generality and increasing the efficiency of this transformation.
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