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Direct use of dioxygen as an oxygen source: catalytic oxidative synthesis of amides.

The first transition-metal-catalyzed direct oxidative synthesis of amides by using dioxygen as an oxygen source has been developed under mild conditions, in which DBU was used as the key additive. The present methodology, which utilizes dioxygen as an oxidant and oxygen source and cheap copper salts... Full description

Journal Title: Chemical communications (Cambridge England), January 7, 2012, Vol.48(2), pp.305-307
Main Author: Wei, Wei
Other Authors: Hu, Xiao-Yu , Yan, Xiao-Wei , Zhang, Qiang , Cheng, Ming , Ji, Jian-Xin
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1364-548X ; DOI: 1364-548X ; DOI: 10.1039/c1cc14640h
Link: http://search.proquest.com/docview/908010017/?pq-origsite=primo
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recordid: proquest908010017
title: Direct use of dioxygen as an oxygen source: catalytic oxidative synthesis of amides.
format: Article
creator:
  • Wei, Wei
  • Hu, Xiao-Yu
  • Yan, Xiao-Wei
  • Zhang, Qiang
  • Cheng, Ming
  • Ji, Jian-Xin
subjects:
  • Amides–Chemical Synthesis
  • Catalysis–Chemistry
  • Copper–Chemistry
  • Oxidants–Chemistry
  • Oxidation-Reduction–Chemistry
  • Oxygen–Chemistry
  • Amides
  • Oxidants
  • Copper
  • Oxygen
ispartof: Chemical communications (Cambridge, England), January 7, 2012, Vol.48(2), pp.305-307
description: The first transition-metal-catalyzed direct oxidative synthesis of amides by using dioxygen as an oxygen source has been developed under mild conditions, in which DBU was used as the key additive. The present methodology, which utilizes dioxygen as an oxidant and oxygen source and cheap copper salts as catalysts, opens up an interesting and attractive avenue for the synthesis of amide functionality.
language: eng
source:
identifier: E-ISSN: 1364-548X ; DOI: 1364-548X ; DOI: 10.1039/c1cc14640h
fulltext: fulltext
issn:
  • 1364548X
  • 1364-548X
url: Link


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descriptionThe first transition-metal-catalyzed direct oxidative synthesis of amides by using dioxygen as an oxygen source has been developed under mild conditions, in which DBU was used as the key additive. The present methodology, which utilizes dioxygen as an oxidant and oxygen source and cheap copper salts as catalysts, opens up an interesting and attractive avenue for the synthesis of amide functionality.
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